Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated. Concept Introduction: Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone. General structure of alkyne can be given as, Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group. R 1 group being Hydrogen: R 1 group being alkyl:

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11.5, Problem 11.20Q

(a)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Refer part (a).

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Which of the m/z values corresponds to the base peak in the mass spectrum shown? 100 80 A. 45 B. 44 C. 29 D. 15 Intensity 20 0 10 20 30 40 B- m/z -8 50 E. 30 Which of the m/z values correspond to the molecular ion for the compound shown? A. 18 B. 82 OH C. 100 D. 102 E. 103

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11.5, Problem 11.20Q

(a)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Refer part (a).

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11.5, Problem 11.20Q

(a)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Refer part (a).

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 11.5, Problem 11.20Q

(a)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Refer part (a).

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Answer 5

Chapter 11.5, Problem 11.20Q

(a)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

(b)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 11.5, Problem 11.20Q

(a)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

Answer 7

Chapter 11.5, Problem 11.20Q

(a)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Addition of water molecule to an unsaturated bond present in hydrocarbon is known as hydration. In hydration of alkyne, the product formed is an aldehyde or a ketone depending upon the group that is attached to the carbon atom that is present in the unsaturated bond. During hydration of alkyne an enol intermediate is formed which is unstable and it isomerizes to either an aldehyde or ketone.

General structure of alkyne can be given as,

Two cases are possible here. One is that the R group can be hydrogen atom and R group can be an alkyl group.

R1 group being Hydrogen:

R1 group being alkyl:

Answer 8

(b)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Refer part (a).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 11.2 - Name each of the following alkenes and alkynes...Ch. 11.2 - Prob. 11.2PP Ch. 11.2 - Prob. 11.1Q Ch. 11.2 - Prob. 11.2Q Ch. 11.3 - Prob. 11.3PP Ch. 11.3 - Prob. 11.4PP Ch. 11.3 - Prob. 11.5PP Ch. 11.3 - Prob. 11.3Q Ch. 11.3 - Prob. 11.4Q Ch. 11.3 - Prob. 11.5Q

Interpretation: Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated. Concept Introduction: Refer part (a).

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Chapter 11 Solutions

Interpretation:

Final product in hydration of the given alkyne is aldehyde or ketone has to be indicated.

Concept Introduction:

Refer part (a).