Chapter 11.3, Problem 10P

(a)

Interpretation Introduction

Interpretation:

A method has to be suggested to prepare the following compound using cyclohexene as starting material.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide using an Organoborane reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoborane compound:

An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl –Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon single bond.

(b)

Interpretation Introduction

Interpretation:

A method has to be suggested to prepare the following compound using cyclohexene as starting material.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoborane compound:

An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl –Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

A method has to be suggested to prepare the following compound using cyclohexene as starting material.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl–organoboron compound, an alkenyl –Organoboron compound, or an aryl–Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

A method has to be suggested to prepare the following compound using cyclohexene as starting material.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl–Organoboron compound: ${\text{R}}^{\text{'}}\text{B}{\left(\text{OR}\right)}_2$.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.