Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)
Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)
8th Edition
ISBN: 9780134649771
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 11, Problem 27P

(a)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl–Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(a)

Expert Solution
Check Mark

Explanation of Solution

When a Iodobenzene is treated with alkene in presence of HeeK Reagent to form the correspondng the benzene product.

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  1

(b)

Interpretation Introduction

Interpretation:

The product of the given reaction has to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl–Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Expert Solution
Check Mark

Answer to Problem 27P

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  2

Explanation of Solution

When a Complex of benzene  is treated with  ethylene oxide  to form the correspondng the alcoholic benzene product.

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  3

(c)

Interpretation Introduction

Interpretation:

The expected product should be formed by the following reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Expert Solution
Check Mark

Answer to Problem 27P

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  4

Explanation of Solution

Chloro benzene is treated with alkyl substituted CuLi reagent to give the corresponding product.

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  5

(d)

Interpretation Introduction

Interpretation:

The expected product should be formed by the following reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Expert Solution
Check Mark

Answer to Problem 27P

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  6

Explanation of Solution

When a Iodobenzene is treated with Aldehyde in presence of HeeK Reagent to form the correspondng the dicyclobenzene product.

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  7

(e)

Interpretation Introduction

Interpretation:

The expected product should be formed by the following reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl – organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(e)

Expert Solution
Check Mark

Answer to Problem 27P

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  8

Explanation of Solution

When a bromo benzene treated with a brane complecx in presence of Heek reagent to give the corresponding product.

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  9

(f)

Interpretation Introduction

Interpretation:

The expected product should be formed by the following reaction.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl–organoboron compound, an alkenyl–Organoboron compound, or an aryl–Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(f)

Expert Solution
Check Mark

Answer to Problem 27P

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  10

Explanation of Solution

When an alkyne is treated with the Borane and Bromobenzene and the Heck reagent to form the corresponding product.

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition), Chapter 11, Problem 27P , additional homework tip  11

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Chapter 11 Solutions

Organic Chemistry Study Guide and Solutions Manual, Books a la Carte Edition (8th Edition)

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