ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL
8th Edition
ISBN: 9780134595450
Author: Bruice
Publisher: PEARSON
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Chapter 11.2, Problem 3P
Interpretation Introduction

Interpretation:

The organometallic compound formed by excess reaction of methylmagnesium chloride with GaCl3.

Concept introduction:

  • Organometallic compound it can be defined as the compound which contain Carbon – Metal bond.
  • The carbon attached to the halogen in an alkyl halide is an electrophile, whereas the carbon attached to the metal in an organometallic compound is a nucleophile.
  • Transmetallation:

Transmetallation occurs when an organometallic compound is added to a metal halid whose metal is more electronegative (closer to the electronegative of carbon) than the metal in the organometallic compound.

  • Grignard reagent:

The compound that results when magnesium is inserted between the carbon atom and the halogen of an alkyl halide like RMgBr & RMgCl  is known as Grignard reagent.  They are also known as Organomagnesium compounds.

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Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Select to Edit Arrows H H Select to Add Arrows > H CFCI: Select to Edit Arrows H Select to Edit Arrows
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Chapter 11 Solutions

ORGANIC CHEMISTRY-W/S.G+SOLN.MANUAL

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