T he expected product obtained for the given conversion should be determined. Concept introduction: Suzuki reaction: A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent . Heck reaction: A reaction that breaks the double bond of sa alkene and then joins the fragments . Organoborane compound: An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R ' B ( OR ) 2 . Coupling reaction: A reaction that joins two groups with a carbon-carbon bond.

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Answer 1

Question

Chapter 11, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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7. Draw a curved arrow mechanism for the following reaction. HO cat. HCI OH in dioxane with 4A molecular sieves

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Answer 2

Question

Chapter 11, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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Answer 3

Question

Chapter 11, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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Answer 4

Question

Chapter 11, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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Answer 5

Chapter 11, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 6

Chapter 11, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 7

Chapter 11, Problem 37P

(a)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Orghanoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The expected product obtained for the given conversion should be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoborane compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 11.1 - Prob. 1P Ch. 11.2 - Which is more reactive an organolithium compound...Ch. 11.2 - Prob. 3P Ch. 11.3 - Muscalure is the sex attractant of the common...Ch. 11.3 - Prob. 7P Ch. 11.3 - Prob. 8P Ch. 11.3 - Prob. 9P Ch. 11.3 - Prob. 10P Ch. 11.4 - Prob. 13P Ch. 11.4 - Prob. 14P

Solution Summary: The author explains Suzuki reaction, which couples an aryl halide with an Organoboron reagent. Heck reaction breaks the double bond of sa alkene and joins the fragments.

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Chapter 11 Solutions