The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated. Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy. To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

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Answer 1

Question

Chapter 11, Problem 9RQ

(a)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(b)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(c)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(d)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

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3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer

curved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism steps

Answer 2

Question

Chapter 11, Problem 9RQ

(a)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(b)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(c)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(d)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

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Answer 3

Question

Chapter 11, Problem 9RQ

(a)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(b)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(c)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(d)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

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Answer 4

Question

Chapter 11, Problem 9RQ

(a)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(b)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(c)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(d)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

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Answer 5

Chapter 11, Problem 9RQ

(a)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(b)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(c)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

(d)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 6

Chapter 11, Problem 9RQ

(a)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 7

Chapter 11, Problem 9RQ

(a)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 8

(b)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 9

(b)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 10

(c)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 11

(c)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 12

(d)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 13

(d)

Interpretation Introduction

Interpretation: The premise underlying the collision model and the effect on the rate by the given terms is to be stated. The potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction is to be stated. The effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic is to be stated.

Concept introduction: The change observed in the concentration of a reactant or a product per unit time is known as the rate of the particular reaction. The differential rate law provides the rate of a reaction at specific reaction concentrations. The minimum amount of energy that is required for a chemical reaction to take place is known as activation energy.

To determine: The premise underlying the collision model and the effect on the rate by the given terms; the potential energy versus reaction progress plot for an endothermic as well as an exothermic reaction and the effect on the rate of the forward reaction if the reaction is exothermic and if the reaction is endothermic.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 11 - Define reaction rate. Distinguish between the...Ch. 11 - Distinguish between the differential rate law and...Ch. 11 - One experimental procedure that can be used to...Ch. 11 - The initial rate for a reaction is equal to the...Ch. 11 - Prob. 5RQ Ch. 11 - Derive expressions for the half-life of zero-,...Ch. 11 - Prob. 7RQ Ch. 11 - Prob. 8RQ Ch. 11 - Prob. 9RQ Ch. 11 - Give the Arrhenius equation. Take the natural log...

Solution Summary: The author explains the premise underlying the collision model and the effect of ‘activation energy’ on the reaction rate.

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Chapter 11 Solutions