The initial rate for a reaction is equal to the slope of the tangent line at t ≈ 0 in a plot of [A] versus time. From calculus, initial rate = − d [ A ] d t . Therefore. the differential rate law for a reaction is Rate = − d [ A ] d t = k [ A ] n . Assuming you have some calculus in your background, derive the zero-, first-, and second-order integrated rate laws using the differential rate law.
The initial rate for a reaction is equal to the slope of the tangent line at t ≈ 0 in a plot of [A] versus time. From calculus, initial rate = − d [ A ] d t . Therefore. the differential rate law for a reaction is Rate = − d [ A ] d t = k [ A ] n . Assuming you have some calculus in your background, derive the zero-, first-, and second-order integrated rate laws using the differential rate law.
Solution Summary: The author explains that the initial rate for a reaction is equal to the slope of the tangent line at tapprox 0. The zero-, first- and second-order integrated rate
The initial rate for a reaction is equal to the slope of the tangent line at t ≈ 0 in a plot of [A] versus time. From calculus, initial rate =
−
d
[
A
]
d
t
. Therefore. the differential rate law for a reaction is Rate =
−
d
[
A
]
d
t
=
k
[
A
]
n
.
Assuming you have some calculus in your background, derive the zero-, first-, and second-order integrated rate laws using the differential rate law.
Definition Definition Study of the speed of chemical reactions and other factors that affect the rate of reaction. It also extends toward the mechanism involved in the reaction.
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 11 Solutions
Bundle: Chemistry: An Atoms First Approach, 2nd, Loose-Leaf + OWLv2, 4 terms (24 months) Printed Access Card
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