CHEMISTRY >CUSTOM<
14th Edition
ISBN: 9781259137815
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 11, Problem 92QP
What is a phase diagram? What useful information can be obtained from studying a phase diagram?
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Chapter 11 Solutions
CHEMISTRY >CUSTOM<
Ch. 11.1 - Prob. 1PPACh. 11.1 - Prob. 1PPBCh. 11.1 - Prob. 1PPCCh. 11.1 - Prob. 1CPCh. 11.1 - Prob. 2CPCh. 11.2 - Prob. 1PPACh. 11.2 - Prob. 1PPBCh. 11.2 - Prob. 1PPCCh. 11.2 - Prob. 1CPCh. 11.2 - 11.2.2 Given the following information for ...
Ch. 11.2 - 11.2.3 Using the graph, estimate the vapor...Ch. 11.2 - Using the result from question 11.2.3 and another...Ch. 11.3 - Practice ProblemATTEMPT When silver crystallizes,...Ch. 11.3 - Practice Problem BUILD
The density of sodium metal...Ch. 11.3 - Practice Problem CONCEPTUALIZE The diagram shows...Ch. 11.3 - 11.3.1 Nickel has a face-centered cubic unit cell...Ch. 11.3 - Prob. 2CPCh. 11.4 - Prob. 1PPACh. 11.4 - Prob. 1PPBCh. 11.4 - Prob. 1PPCCh. 11.5 - Practice ProblemATTEMPT LiF has the same unit cell...Ch. 11.5 - Practice ProblemBUILD NiO also adopts the...Ch. 11.5 - Practice ProblemCONCEPTUALIZE Referring to the...Ch. 11.6 - Practice Problem ATTEMPT
Aluminum metal...Ch. 11.6 - Practice Problem BUILD
Copper crystallizes in a...Ch. 11.6 - Prob. 1PPCCh. 11.6 - 11.6.1 How much energy (in kJ) is required to...Ch. 11.6 - 11.6.2 How much energy (in kJ) is given off when...Ch. 11.7 - Practice ProblemATTEMPT Calculate the amount of...Ch. 11.7 - Practice ProblemBUILD Determine the final state...Ch. 11.7 - Prob. 1PPCCh. 11.7 - Prob. 1CPCh. 11.7 - Prob. 2CPCh. 11.8 - Prob. 1PPACh. 11.8 - Practice Problem BUILD
Sketch the phase diagram of...Ch. 11.8 - Prob. 1PPCCh. 11 - Which of the following would you expect to be more...Ch. 11 - 11.2
Which of the following would you expect to be...Ch. 11 - Prob. 3KSPCh. 11 - Prob. 4KSPCh. 11 - Give an example for each type of intermolecular...Ch. 11 - 11.2 Explain the term polarizability. What kind of...Ch. 11 - Prob. 3QPCh. 11 - Prob. 4QPCh. 11 - 11.5 What physical properties are determined by...Ch. 11 - Prob. 6QPCh. 11 - Describe the types of intermolecular forces that...Ch. 11 - Prob. 8QPCh. 11 - Prob. 9QPCh. 11 - The binary hydrogen compounds of the Group 4A...Ch. 11 - 11.11 List the types of intermolecular forces that...Ch. 11 - Prob. 12QPCh. 11 - Prob. 13QPCh. 11 - Arrange the following in order of increasing...Ch. 11 - Diethyl ether has a boiling point of 34 .5°C , and...Ch. 11 - 11.16 Which member of each of the following pairs...Ch. 11 - Prob. 17QPCh. 11 - Explain in terms of intermolecular forces why (a)...Ch. 11 - What kind of attractive forces must be overcome to...Ch. 11 - Prob. 20QPCh. 11 - Prob. 21QPCh. 11 - Explain why liquids, unlike gases, are virtually...Ch. 11 - 11.23 What is surface tension? What is the...Ch. 11 - Prob. 24QPCh. 11 - Prob. 25QPCh. 11 - 11.26 A glass can be filled slightly above the rim...Ch. 11 - 11.27 Draw diagrams showing the capillary action...Ch. 11 - Prob. 28QPCh. 11 - Why does the viscosity of a liquid decrease with...Ch. 11 - Why is ice less dense than water?Ch. 11 - 11.31 Outdoor water pipes have to be drained or...Ch. 11 - Prob. 32QPCh. 11 - Prob. 33QPCh. 11 - Prob. 34QPCh. 11 - Predict the viscosity of ethylene glycol relative...Ch. 11 - 11.36 Vapor pressure measurements at several...Ch. 11 - The vapor pressure of liquid X is lower than that...Ch. 11 - 11.38 Define the following terms: crystalline...Ch. 11 - Describe the geometries of the following cubic...Ch. 11 - Classify the solid states in terms of crystal...Ch. 11 - The melting points of the oxides of the...Ch. 11 - Define X-ray diffraction. What are the typical...Ch. 11 - 11.43 Write the Bragg equation. Define every term...Ch. 11 - 11.44 What is the coordination number of each...Ch. 11 - Calculate the number of spheres that would be...Ch. 11 - Metallic iron crystallizes in a cubic lattice. The...Ch. 11 - Barium metal crystallizes in a body-centered cubic...Ch. 11 - 11.48 Vanadium crystallizes in a body-centered...Ch. 11 - Europium crystallizes in a body-centered cubic...Ch. 11 - 11.50 Crystalline silicon has a cubic structure....Ch. 11 - 11.51 A face-centered cubic cell contains 8 X...Ch. 11 - When X rays of wavelength 0.090 nm are diffracted...Ch. 11 - The distance between layers in an NaCl crystal is...Ch. 11 - Identify the unit cell of molecular iodine ( I 2 )...Ch. 11 - Shown here is a zinc oxide unit cell. What is the...Ch. 11 - Prob. 56QPCh. 11 - Prob. 57QPCh. 11 - A solid is hard, brittle, and electrically...Ch. 11 - A solid is soft and has a low melting point (below...Ch. 11 - Prob. 60QPCh. 11 - 11.61 Which of the following are molecular solids...Ch. 11 - Classify the solid state of the following...Ch. 11 - Prob. 63QPCh. 11 - Prob. 64QPCh. 11 - Define glass. What is the chief component of...Ch. 11 - 11.66 What is a phase change? Name all possible...Ch. 11 - What is the equilibrium vapor pressure of a...Ch. 11 - Use any one of the phase changes to explain what...Ch. 11 - 11.69 Define the following terms: (a) molar heat...Ch. 11 - How is the molar heat of sublimation related to...Ch. 11 - What can we learn about the intermolecular forces...Ch. 11 - The greater the molar heat of vaporization of a...Ch. 11 - Prob. 73QPCh. 11 - As a liquid is heated at constant pressure, its...Ch. 11 - What is critical temperature? What is the...Ch. 11 - Prob. 76QPCh. 11 - 11.77 How do the boiling points and melting points...Ch. 11 - Prob. 78QPCh. 11 - The vapor pressure of a liquid in a closed...Ch. 11 - Wet clothes dry more quickly on a hot, dry day...Ch. 11 - Which of the following phase transitions gives off...Ch. 11 - 11.82 A beaker of water is heated to boiling by a...Ch. 11 - Prob. 83QPCh. 11 - Calculate the amount of heat (in kJ) required to...Ch. 11 - Prob. 85QPCh. 11 - The molar heats of fusion and sublimation of...Ch. 11 - How is the rate of evaporation of a liquid...Ch. 11 - 11.88 The following compounds, listed with their...Ch. 11 - Prob. 89QPCh. 11 - A student hangs wet clothes outdoors on a winter...Ch. 11 - Explain why steam at 100°C causes more serious...Ch. 11 - What is a phase diagram? What useful information...Ch. 11 - 11.93 Explain how water’s phase diagram differs...Ch. 11 - The blades of ice skates are quite thin, so the...Ch. 11 - 11.95 A length of wire is placed on top of a block...Ch. 11 - Prob. 96QPCh. 11 - Prob. 97QPCh. 11 - 11.98 Name the kinds of attractive forces that...Ch. 11 - Prob. 99APCh. 11 - At –35°C , liquid HI has a higher vapor pressure...Ch. 11 - Prob. 101APCh. 11 - Prob. 102APCh. 11 - Prob. 103APCh. 11 - Prob. 104APCh. 11 - Prob. 105APCh. 11 - A CO 2 fire extinguisher is located on the outside...Ch. 11 - Prob. 107APCh. 11 - A flask of water is connected to a powerful vacuum...Ch. 11 - Prob. 109APCh. 11 - The interionic distances of several alkali halide...Ch. 11 - Which has a greater density, crystalline Si O 2 or...Ch. 11 - A student is given four solid samples labeled W,...Ch. 11 - Prob. 113APCh. 11 - Prob. 114APCh. 11 - X rays of wavelength 0.154 nm strike an aluminum...Ch. 11 - 11.116 The properties of gases, liquids, and...Ch. 11 - Prob. 117APCh. 11 - Prob. 118APCh. 11 - Prob. 119APCh. 11 - Prob. 120APCh. 11 - Prob. 121APCh. 11 - 11.122 The distance between and is 257 pm in...Ch. 11 - Prob. 123APCh. 11 - Prob. 124APCh. 11 - 11.125 Calculate the for the following processes...Ch. 11 - 11.126 Which liquid would you expect to have a...Ch. 11 - 11.127 A beaker of water is placed in a closed...Ch. 11 - Prob. 128APCh. 11 - Prob. 129APCh. 11 - Carbon and silicon belong to Group 4A of the...Ch. 11 - Prob. 131APCh. 11 - Prob. 132APCh. 11 - Prob. 133APCh. 11 - Prob. 134APCh. 11 - Prob. 135APCh. 11 - Prob. 136APCh. 11 - Prob. 137APCh. 11 - Prob. 138APCh. 11 - Prob. 139APCh. 11 - 11.140 Sketch the cooling curves of water from...Ch. 11 - Prob. 141APCh. 11 - Prob. 142APCh. 11 - A closed vessel of volume 9.6 L contains 2.0 g of...Ch. 11 - 11.144 The electrical conductance of copper metal...Ch. 11 - 11.145 Assuming ideal behavior, calculate the...Ch. 11 - Explain why drivers are advised to use motor oil...Ch. 11 - Which of the following compounds is most likely to...Ch. 11 - 11.148 A chemistry instructor performed the...Ch. 11 - Prob. 149APCh. 11 - Prob. 150APCh. 11 - The phase diagram of helium is shown. Helium is...Ch. 11 - 11.152 The phase diagram of sulfur is shown. (a)...Ch. 11 - Prob. 153APCh. 11 - Prob. 154APCh. 11 - Prob. 155APCh. 11 - Prob. 156APCh. 11 - Prob. 157APCh. 11 - Prob. 158APCh. 11 - 11.159 Why do citrus growers spray their trees...Ch. 11 - Prob. 2SEPPCh. 11 - 3. Each cubic unit cell (edge length a = 543 pm)...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- List the different phase transitions that are possible and give examples of each.arrow_forwardThe phase diagram for water over a relative narrow pressure and temperature range is given in Figure 9.19. A phase diagram over a considerably wider range of temperature and pressure (kbar) is given nearby. This phase diagram illustrates the polymorphism of ice, the existence of a solid in more than one form. In this case, Roman numerals are used to designate each polymorphic form. For example, Ice I, ordinary ice, is the form that exists under ordinary pressures. The other forms exist only at higher pressures, in some cases extremely high pressure such as Ice VII and Ice VIII. Using the phase diagram, give the approximate P and T conditions at the triple point for Ice III, Ice V, and liquid water. Determine the approximate temperature and pressure for the triple point for Ices VI, VII, and VIII. What is anomalously different about the fusion curves for Ice VI and Ice VII compared to that of Ice I? What phases exist at 8 kbar and 20 °C? At a constant temperature of −10 °C, start at 3 kbar and increase the pressure to 7 kbar. Identify all the phase changes that occur sequentially as these conditions change. Explain why there is no triple point for the combination of Ice VII, Ice VIII, and liquid water.arrow_forwardConsider the iodine monochloride molecule, ICI. Because chlorine is more electronegative than iodine, this molecule is a dipole. How would you expect iodine monochloride molecules in the gaseous state to orient themselves with respect to each other as the sample is cooled and the molecules begin to aggregate? Sketch the orientation you would expect.arrow_forward
- Referring to Figure 9.7, state what phase(s) is (are) present at (a) 1 atm, 10C. (b) 3 mm Hg, 20C. (c) 1000 mm Hg, 75C.arrow_forwardWhy are steam burns so much worse than water burns even if the H2O is at the same temperature for both phases? Hint: Consider the heat of vaporization of water.arrow_forwardSome water is placed in a sealed glass container connected to a vacuum pump (a device used to pump gases from a container), and the pump is turned on. The water appears to boil and then freezes. Explain these changes using the phase diagram for water. What would happen to the ice if the vacuum pump was left on indefinitely?arrow_forward
- Referring to Figure 9.7, state what phase(s) is/are present at (a) 1 atm, 100C. (b) 0.5 atm, 100C.(c) 0.8 atm. 50C.arrow_forwardA special vessel (see Fig. 10.45) contains ice and supercooled water (both at 10C) connected by vapor space. Describe what happens to the amounts of ice and water as time passes.arrow_forwardAn amorphous solid can sometimes be converted to a crystalline solid by a process called annealing. Annealing consists of heating the substance to a temperature just below the melting point of the crystalline form and then cooling it slowly. Explain why this process helps produce a crystalline solid.arrow_forward
- Use Figure 11.7 to estimate the boiling point of carbon tetrachloride, CCl4, under an external pressure of 250 mmHg.arrow_forward8.48 Why must the vapor pressure of a substance be measured only after dynamic equilibrium is established?arrow_forwardExplain why the enthalpies of vaporization of the following substances increase in the order CH4NH3H2O, even though all three substances have approximately the same molar mass.arrow_forward
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