CHEMISTRY >CUSTOM<
14th Edition
ISBN: 9781259137815
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 11, Problem 5QP
What physical properties are determined by the strength of intermolecular forces in solids and in liquids?
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Chapter 11 Solutions
CHEMISTRY >CUSTOM<
Ch. 11.1 - Prob. 1PPACh. 11.1 - Prob. 1PPBCh. 11.1 - Prob. 1PPCCh. 11.1 - Prob. 1CPCh. 11.1 - Prob. 2CPCh. 11.2 - Prob. 1PPACh. 11.2 - Prob. 1PPBCh. 11.2 - Prob. 1PPCCh. 11.2 - Prob. 1CPCh. 11.2 - 11.2.2 Given the following information for ...
Ch. 11.2 - 11.2.3 Using the graph, estimate the vapor...Ch. 11.2 - Using the result from question 11.2.3 and another...Ch. 11.3 - Practice ProblemATTEMPT When silver crystallizes,...Ch. 11.3 - Practice Problem BUILD
The density of sodium metal...Ch. 11.3 - Practice Problem CONCEPTUALIZE The diagram shows...Ch. 11.3 - 11.3.1 Nickel has a face-centered cubic unit cell...Ch. 11.3 - Prob. 2CPCh. 11.4 - Prob. 1PPACh. 11.4 - Prob. 1PPBCh. 11.4 - Prob. 1PPCCh. 11.5 - Practice ProblemATTEMPT LiF has the same unit cell...Ch. 11.5 - Practice ProblemBUILD NiO also adopts the...Ch. 11.5 - Practice ProblemCONCEPTUALIZE Referring to the...Ch. 11.6 - Practice Problem ATTEMPT
Aluminum metal...Ch. 11.6 - Practice Problem BUILD
Copper crystallizes in a...Ch. 11.6 - Prob. 1PPCCh. 11.6 - 11.6.1 How much energy (in kJ) is required to...Ch. 11.6 - 11.6.2 How much energy (in kJ) is given off when...Ch. 11.7 - Practice ProblemATTEMPT Calculate the amount of...Ch. 11.7 - Practice ProblemBUILD Determine the final state...Ch. 11.7 - Prob. 1PPCCh. 11.7 - Prob. 1CPCh. 11.7 - Prob. 2CPCh. 11.8 - Prob. 1PPACh. 11.8 - Practice Problem BUILD
Sketch the phase diagram of...Ch. 11.8 - Prob. 1PPCCh. 11 - Which of the following would you expect to be more...Ch. 11 - 11.2
Which of the following would you expect to be...Ch. 11 - Prob. 3KSPCh. 11 - Prob. 4KSPCh. 11 - Give an example for each type of intermolecular...Ch. 11 - 11.2 Explain the term polarizability. What kind of...Ch. 11 - Prob. 3QPCh. 11 - Prob. 4QPCh. 11 - 11.5 What physical properties are determined by...Ch. 11 - Prob. 6QPCh. 11 - Describe the types of intermolecular forces that...Ch. 11 - Prob. 8QPCh. 11 - Prob. 9QPCh. 11 - The binary hydrogen compounds of the Group 4A...Ch. 11 - 11.11 List the types of intermolecular forces that...Ch. 11 - Prob. 12QPCh. 11 - Prob. 13QPCh. 11 - Arrange the following in order of increasing...Ch. 11 - Diethyl ether has a boiling point of 34 .5°C , and...Ch. 11 - 11.16 Which member of each of the following pairs...Ch. 11 - Prob. 17QPCh. 11 - Explain in terms of intermolecular forces why (a)...Ch. 11 - What kind of attractive forces must be overcome to...Ch. 11 - Prob. 20QPCh. 11 - Prob. 21QPCh. 11 - Explain why liquids, unlike gases, are virtually...Ch. 11 - 11.23 What is surface tension? What is the...Ch. 11 - Prob. 24QPCh. 11 - Prob. 25QPCh. 11 - 11.26 A glass can be filled slightly above the rim...Ch. 11 - 11.27 Draw diagrams showing the capillary action...Ch. 11 - Prob. 28QPCh. 11 - Why does the viscosity of a liquid decrease with...Ch. 11 - Why is ice less dense than water?Ch. 11 - 11.31 Outdoor water pipes have to be drained or...Ch. 11 - Prob. 32QPCh. 11 - Prob. 33QPCh. 11 - Prob. 34QPCh. 11 - Predict the viscosity of ethylene glycol relative...Ch. 11 - 11.36 Vapor pressure measurements at several...Ch. 11 - The vapor pressure of liquid X is lower than that...Ch. 11 - 11.38 Define the following terms: crystalline...Ch. 11 - Describe the geometries of the following cubic...Ch. 11 - Classify the solid states in terms of crystal...Ch. 11 - The melting points of the oxides of the...Ch. 11 - Define X-ray diffraction. What are the typical...Ch. 11 - 11.43 Write the Bragg equation. Define every term...Ch. 11 - 11.44 What is the coordination number of each...Ch. 11 - Calculate the number of spheres that would be...Ch. 11 - Metallic iron crystallizes in a cubic lattice. The...Ch. 11 - Barium metal crystallizes in a body-centered cubic...Ch. 11 - 11.48 Vanadium crystallizes in a body-centered...Ch. 11 - Europium crystallizes in a body-centered cubic...Ch. 11 - 11.50 Crystalline silicon has a cubic structure....Ch. 11 - 11.51 A face-centered cubic cell contains 8 X...Ch. 11 - When X rays of wavelength 0.090 nm are diffracted...Ch. 11 - The distance between layers in an NaCl crystal is...Ch. 11 - Identify the unit cell of molecular iodine ( I 2 )...Ch. 11 - Shown here is a zinc oxide unit cell. What is the...Ch. 11 - Prob. 56QPCh. 11 - Prob. 57QPCh. 11 - A solid is hard, brittle, and electrically...Ch. 11 - A solid is soft and has a low melting point (below...Ch. 11 - Prob. 60QPCh. 11 - 11.61 Which of the following are molecular solids...Ch. 11 - Classify the solid state of the following...Ch. 11 - Prob. 63QPCh. 11 - Prob. 64QPCh. 11 - Define glass. What is the chief component of...Ch. 11 - 11.66 What is a phase change? Name all possible...Ch. 11 - What is the equilibrium vapor pressure of a...Ch. 11 - Use any one of the phase changes to explain what...Ch. 11 - 11.69 Define the following terms: (a) molar heat...Ch. 11 - How is the molar heat of sublimation related to...Ch. 11 - What can we learn about the intermolecular forces...Ch. 11 - The greater the molar heat of vaporization of a...Ch. 11 - Prob. 73QPCh. 11 - As a liquid is heated at constant pressure, its...Ch. 11 - What is critical temperature? What is the...Ch. 11 - Prob. 76QPCh. 11 - 11.77 How do the boiling points and melting points...Ch. 11 - Prob. 78QPCh. 11 - The vapor pressure of a liquid in a closed...Ch. 11 - Wet clothes dry more quickly on a hot, dry day...Ch. 11 - Which of the following phase transitions gives off...Ch. 11 - 11.82 A beaker of water is heated to boiling by a...Ch. 11 - Prob. 83QPCh. 11 - Calculate the amount of heat (in kJ) required to...Ch. 11 - Prob. 85QPCh. 11 - The molar heats of fusion and sublimation of...Ch. 11 - How is the rate of evaporation of a liquid...Ch. 11 - 11.88 The following compounds, listed with their...Ch. 11 - Prob. 89QPCh. 11 - A student hangs wet clothes outdoors on a winter...Ch. 11 - Explain why steam at 100°C causes more serious...Ch. 11 - What is a phase diagram? What useful information...Ch. 11 - 11.93 Explain how water’s phase diagram differs...Ch. 11 - The blades of ice skates are quite thin, so the...Ch. 11 - 11.95 A length of wire is placed on top of a block...Ch. 11 - Prob. 96QPCh. 11 - Prob. 97QPCh. 11 - 11.98 Name the kinds of attractive forces that...Ch. 11 - Prob. 99APCh. 11 - At –35°C , liquid HI has a higher vapor pressure...Ch. 11 - Prob. 101APCh. 11 - Prob. 102APCh. 11 - Prob. 103APCh. 11 - Prob. 104APCh. 11 - Prob. 105APCh. 11 - A CO 2 fire extinguisher is located on the outside...Ch. 11 - Prob. 107APCh. 11 - A flask of water is connected to a powerful vacuum...Ch. 11 - Prob. 109APCh. 11 - The interionic distances of several alkali halide...Ch. 11 - Which has a greater density, crystalline Si O 2 or...Ch. 11 - A student is given four solid samples labeled W,...Ch. 11 - Prob. 113APCh. 11 - Prob. 114APCh. 11 - X rays of wavelength 0.154 nm strike an aluminum...Ch. 11 - 11.116 The properties of gases, liquids, and...Ch. 11 - Prob. 117APCh. 11 - Prob. 118APCh. 11 - Prob. 119APCh. 11 - Prob. 120APCh. 11 - Prob. 121APCh. 11 - 11.122 The distance between and is 257 pm in...Ch. 11 - Prob. 123APCh. 11 - Prob. 124APCh. 11 - 11.125 Calculate the for the following processes...Ch. 11 - 11.126 Which liquid would you expect to have a...Ch. 11 - 11.127 A beaker of water is placed in a closed...Ch. 11 - Prob. 128APCh. 11 - Prob. 129APCh. 11 - Carbon and silicon belong to Group 4A of the...Ch. 11 - Prob. 131APCh. 11 - Prob. 132APCh. 11 - Prob. 133APCh. 11 - Prob. 134APCh. 11 - Prob. 135APCh. 11 - Prob. 136APCh. 11 - Prob. 137APCh. 11 - Prob. 138APCh. 11 - Prob. 139APCh. 11 - 11.140 Sketch the cooling curves of water from...Ch. 11 - Prob. 141APCh. 11 - Prob. 142APCh. 11 - A closed vessel of volume 9.6 L contains 2.0 g of...Ch. 11 - 11.144 The electrical conductance of copper metal...Ch. 11 - 11.145 Assuming ideal behavior, calculate the...Ch. 11 - Explain why drivers are advised to use motor oil...Ch. 11 - Which of the following compounds is most likely to...Ch. 11 - 11.148 A chemistry instructor performed the...Ch. 11 - Prob. 149APCh. 11 - Prob. 150APCh. 11 - The phase diagram of helium is shown. Helium is...Ch. 11 - 11.152 The phase diagram of sulfur is shown. (a)...Ch. 11 - Prob. 153APCh. 11 - Prob. 154APCh. 11 - Prob. 155APCh. 11 - Prob. 156APCh. 11 - Prob. 157APCh. 11 - Prob. 158APCh. 11 - 11.159 Why do citrus growers spray their trees...Ch. 11 - Prob. 2SEPPCh. 11 - 3. Each cubic unit cell (edge length a = 543 pm)...
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- Use the References to access important values if needed for this question. What is the IUPAC name of each of the the following? 0 CH3CHCNH₂ CH3 CH3CHCNHCH2CH3 CH3arrow_forwardYou have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you manipulated and exploited the acid-base chemistry of one or more of the compounds in your mixture to facilitate their separation into different phases. The key to understanding how liquid- liquid extractions work is by knowing which layer a compound is in, and in what protonation state. The following liquid-liquid extraction is different from the one you performed in Experiment 4, but it uses the same type of logic. Your task is to show how to separate apart Compound A and Compound B. . Complete the following flowchart of a liquid-liquid extraction. Handwritten work is encouraged. • Draw by hand (neatly) only the appropriate organic compound(s) in the boxes. . Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4 and 5. • Box 7a requires the solvent (name is fine). • Box 7b requires one inorganic compound. • You can neatly complete this assignment by hand and…arrow_forwardb) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;' The compound has the ff electronic transitions: 0%o* and no a* 1H NMR Spectrum (CDCl3, 400 MHz) 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppm 13C{H} NMR Spectrum (CDCl3, 100 MHz) Solvent 80 70 60 50 40 30 20 10 0 ppm ppm ¹H-13C me-HSQC Spectrum ppm (CDCl3, 400 MHz) 5 ¹H-¹H COSY Spectrum (CDCl3, 400 MHz) 0.5 10 3.5 3.0 2.5 2.0 1.5 1.0 10 15 20 20 25 30 30 -35 -1.0 1.5 -2.0 -2.5 3.0 -3.5 0.5 ppm 3.5 3.0 2.5 2.0 1.5 1.0 0.5 ppmarrow_forward
- Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forward
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