Concept explainers
a)
Interpretation:Reactions takes place at cathode and anode in
Concept introduction:Electrolysis is a method to transform electrical energy to chemical energy. Electrolytic cells transform electric energy into a chemical energy. In these cells, non-spontaneous reactions occur so energy is supplied for their occurrence. These cells have positive charged anode and negative cathode.
b)
Interpretation:Reactions takes place at cathode and anode in electrolysis of molten
Concept introduction:Electrolysis is a method to transform electrical energy to chemical energy. Electrolytic cells transform electric energy into a chemical energy. In these cells, non-spontaneous reactions occur so energy is supplied for their occurrence. These cells have positive charged anode and negative cathode.
c)
Interpretation:Reactions takes place at cathode and anode in electrolysis of molten
Concept introduction:Electrolysis is a method to transform electrical energy to chemical energy. Electrolytic cells transform electric energy into a chemical energy. In these cells, non-spontaneous reactions occur so energy is supplied for their occurrence. These cells have positive charged anode and negative cathode.
d)
Interpretation:Reactions takes place at cathode and anode in electrolysis of
Concept introduction:Electrolysis is a method to transform electrical energy to chemical energy. Electrolytic cells transform electric energy into a chemical energy. In these cells, non-spontaneous reactions occur so energy is supplied for their occurrence. These cells have positive charged anode and negative cathode.
e)
Interpretation:Reactions takes place at cathode and anode in electrolysis of
Concept introduction:Electrolysis is a method to transform electrical energy to chemical energy. Electrolytic cells transform electric energy into a chemical energy. In these cells, non-spontaneous reactions occur so energy is supplied for their occurrence. These cells have positive charged anode and negative cathode.
f)
Interpretation:Reactions takes place at cathode and anode in electrolysis of
Concept introduction:Electrolysis is a method to transform electrical energy to chemical energy. Electrolytic cells transform electric energy into a chemical energy. In these cells, non-spontaneous reactions occur so energy is supplied for their occurrence. These cells have positive charged anode and negative cathode.
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Chapter 11 Solutions
EBK CHEMICAL PRINCIPLES
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- A factory wants to produce 1.00 103 kg barium from the electrolysis of molten barium chloride. What current must be applied for 4.00 h to accomplish this?arrow_forwardThe metallurgy of aluminum involves electrolysis of Al2O3 dissolved in molten cryolite (Na3AlF6) at about 950 C. Aluminum metal is produced at the cathode. Predict the anode product and write equations for the reactions occurring at both electrodes.arrow_forwardA standard galvanic cell is constructed so that the overall cell reaction is 2A13++(aq)+3M(s)3M2+(aq)+2A1(s) Where M is an unknown metal. If G = 411 kJ for the overall cell reaction, identify the metal used to construct the standard cell.arrow_forward
- For the cell: Cr|Cr3+Co2+|Co E° is 0.46 V. The same cell was prepared in the laboratory at standard conditions. The voltage obtained was 0.40 V. A possible explanation for the difference is (a) the surface area of the chromium electrode was smaller than the cobalt electrode. (b) the mass of the chromium electrode was larger than the mass of the cobalt electrode. (c) the concentration of Cr(NO3)2 solution used was less than 1.0 M. (d) the concentration of Cr(NO3)2 solution used was less than 1.0 M. (e) the volume of Cr(NO3)2 solution used was larger than the volume of Cr(NO3)2 solution used.arrow_forwardConsider the electrolysis of water in the presence of very dilute H2SO4. What species is produced at the anode? Atthe cathode? What are the relative amounts of the speciesproduced at the two electrodes?arrow_forwardThe mass of three different metal electrodes, each from a different galvanic cell, were determined before and after the current generated by the oxidation-reduction reaction in each cell was allowed to flow for a few minutes. The first metal electrode, given the label A, was found to have increased in mass; the second metal electrode, given the label B, did not change in mass; and the third metal electrode, given the label C, was found to have lost mass. Make an educated guess as to which electrodes were active and which were inert electrodes, and which were anode(s) and which were the cathode(s).arrow_forward
- You have 1.0 M solutions of Al(NO3)3 and AgNO3 along with Al and Ag electrodes to construct a voltaic cell. The salt bridge contains a saturated solution of KCl. Complete the picture associated with this problem by a writing the symbols of the elements and ions in the appropriate areas (both solutions and electrodes). b identifying the anode and cathode. c indicating the direction of electron flow through the external circuit. d indicating the cell potential (assume standard conditions, with no current flowing). e writing the appropriate half-reaction under each of the containers. f indicating the direction of ion flow in the salt bridge. g identifying the species undergoing oxidation and reduction. h writing the balanced overall reaction for the cell.arrow_forwardChlorine, Cl2, is produced commercially by the electrolysis of aqueous sodium chloride. The anode reaction is 2Cl(aq)Cl2(g)+2e How long will it take to produce 2.00 kg of chlorine if the current is 5.00 102 A?arrow_forwardElectrochemical Cells II Consider this cell running under standard conditions: Ni(s)Ni2(aq)Cu+(aq)Cu(s) a Is this cell a voltaic or an electrolytic cell? How do you know? b Does current flow in this cell spontaneously? c What is the maximum cell potential for this cell? d Say the cell is connected to a voltmeter. Describe what you might see for an initial voltage and what voltage changes, if any, you would observe as time went by. e What is the free energy of this cell when it is first constructed? f Does the free energy of the cell change over time as the cell runs? If so, how does it change?arrow_forward
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