EBK CHEMICAL PRINCIPLES
8th Edition
ISBN: 8220101425812
Author: DECOSTE
Publisher: Cengage Learning US
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Chapter 11, Problem 8DQ
Explain the following relationships:
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Chapter 11 Solutions
EBK CHEMICAL PRINCIPLES
Ch. 11 - Prob. 1DQCh. 11 - Prob. 2DQCh. 11 - You want to “plate out” nickel metal from a nickel...Ch. 11 - A copper penny can be dissolved in nitric acid but...Ch. 11 - Sketch a cell that forms iron metal from iron(II)...Ch. 11 - Which of the following is the best reducing agent:...Ch. 11 - You are told that metal A is a better reducing...Ch. 11 - Explain the following relationships: G and w, cell...Ch. 11 - Explain why cell potentials are not multiplied by...Ch. 11 - What is the difference between andWhen is equal to...
Ch. 11 - Prob. 11DQCh. 11 - Look up the reduction potential for Fe3+toFe2+ ....Ch. 11 - Prob. 13DQCh. 11 - Is the following statement true or false?...Ch. 11 - What is electrochemistry? What are redox...Ch. 11 - When magnesium metal is added to a beaker of...Ch. 11 - Prob. 17ECh. 11 - How can you construct a galvanic cell from two...Ch. 11 - Prob. 19ECh. 11 - Prob. 20ECh. 11 - Prob. 21ECh. 11 - Consider the following galvanic cells: For each...Ch. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - Answer the following questions using data from...Ch. 11 - Prob. 26ECh. 11 - Using data from Table 11.1, place the following in...Ch. 11 - Prob. 28ECh. 11 - Use the table of standard reduction potentials...Ch. 11 - Use the table of standard reduction potentials...Ch. 11 - Prob. 31ECh. 11 - A patent attorney has asked for your advice...Ch. 11 - The free energy change for a reaction G is an...Ch. 11 - The equation also can be applied to...Ch. 11 - Prob. 35ECh. 11 - Glucose is the major fuel for most living cells....Ch. 11 - Direct methanol fuel cells (DMFCs) have shown...Ch. 11 - The overall reaction and standard cell potential...Ch. 11 - Calculate the maximum amount of work that can...Ch. 11 - Prob. 40ECh. 11 - Prob. 41ECh. 11 - Chlorine dioxide (ClO2) , which is produced by...Ch. 11 - The amount of manganese in steel is determined...Ch. 11 - The overall reaction and equilibrium constant...Ch. 11 - Prob. 45ECh. 11 - Calculate for the reaction...Ch. 11 - A disproportionation reaction involves a substance...Ch. 11 - Calculate for the following half-reaction:...Ch. 11 - For the following half-reaction AlF63+3eAl+6F...Ch. 11 - Prob. 50ECh. 11 - The solubility product for CuI(s) is 1.11012....Ch. 11 - Explain the following statement: determines...Ch. 11 - Calculate the pH of the cathode compartment for...Ch. 11 - Consider the galvanic cell based on the...Ch. 11 - Prob. 55ECh. 11 - Consider the following galvanic cell at 25°C:...Ch. 11 - The black silver sulfide discoloration of...Ch. 11 - Consider the cell described below:...Ch. 11 - Consider the cell described below:...Ch. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - What are concentration cells? What is in a...Ch. 11 - A silver concentration cell is set up at 25°C as...Ch. 11 - Consider the concentration cell shown below....Ch. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - An electrochemical cell consists of a nickel metal...Ch. 11 - You have a concentration cell in which the cathode...Ch. 11 - Consider a galvanic cell at standard conditions...Ch. 11 - An electrochemical cell consists of a zinc metal...Ch. 11 - How long will it take to plate out each of the...Ch. 11 - What mass of each of the following substances can...Ch. 11 - It took 2.30 min with a current of 2.00 A to plate...Ch. 11 - The electrolysis of BiO+ produces pure bismuth....Ch. 11 - A single HallHeroult cell (as shown in Fig. 11.22)...Ch. 11 - A factory wants to produce 1.00103 kg barium...Ch. 11 - Why is the electrolysis of molten salts much...Ch. 11 - What reaction will take place at the cathode and...Ch. 11 - What reaction will take place at the cathode and...Ch. 11 - Prob. 81ECh. 11 - a. In the electrolysis of an aqueous solution of...Ch. 11 - A solution at 25°C contains 1.0 M...Ch. 11 - An aqueous solution of an unknown salt of...Ch. 11 - Consider the following half-reactions: A...Ch. 11 - An unknown metal M is electrolyzed. It took 74.1 s...Ch. 11 - Electrolysis of an alkaline earth metal chloride...Ch. 11 - Prob. 88ECh. 11 - What volume of F2 gas, at 25°C and 1.00 atm, is...Ch. 11 - Prob. 90ECh. 11 - In the electrolysis of a sodium chloride solution,...Ch. 11 - What volumes of H2(g)andO2(g) at STP are...Ch. 11 - Copper can be plated onto a spoon by placing the...Ch. 11 - Prob. 94AECh. 11 - Prob. 95AECh. 11 - Prob. 96AECh. 11 - Prob. 97AECh. 11 - Prob. 98AECh. 11 - Prob. 99AECh. 11 - Prob. 100AECh. 11 - Prob. 101AECh. 11 - Prob. 102AECh. 11 - Prob. 103AECh. 11 - Prob. 104AECh. 11 - In 1973 the wreckage of the Civil War ironclad...Ch. 11 - A standard galvanic cell is constructed so that...Ch. 11 - Prob. 107AECh. 11 - Prob. 108AECh. 11 - Prob. 109AECh. 11 - Prob. 110AECh. 11 - Prob. 111AECh. 11 - Prob. 112AECh. 11 - Prob. 113AECh. 11 - Consider a galvanic cell based on the following...Ch. 11 - Prob. 115AECh. 11 - Prob. 116AECh. 11 - Prob. 117AECh. 11 - Prob. 118AECh. 11 - Prob. 119CPCh. 11 - Prob. 120CPCh. 11 - A zinccopper battery is constructed as follows:...Ch. 11 - Prob. 122CPCh. 11 - Prob. 123CPCh. 11 - Prob. 124CPCh. 11 - Prob. 125CPCh. 11 - Prob. 126CPCh. 11 - Prob. 127CPCh. 11 - Prob. 128CPCh. 11 - Prob. 129CPCh. 11 - Prob. 130CPCh. 11 - Prob. 131CPCh. 11 - Prob. 132MPCh. 11 - Prob. 133MP
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- For each of the reactions, calculate E from the table of standard potentials, and state whether the reaction is spontaneous as written or spontaneous in the reverse direction under standard conditions. (a) Cu2+(aq)+Ni(s)Cu(s)+Ni2+(aq) (b) 2Ag(s)+Cl2(g)2AgCl(s) (c) Cl2(g)+2I(aq)2Cl(aq)+I2(s)arrow_forwardWhat is the standard cell potential you would obtain from a cell at 25C using an electrode in which Hg22+(aq) is in contact with mercury metal and an electrode in which an aluminum strip dips into a solution of Al3+(aq)?arrow_forwardCalculate the standard cell potential of the following cell at 25C. Sn(s)Sn2+(aq)I2(aq)I(aq)arrow_forward
- A voltaic cell is constructed in which one half-cell consists of a silver wire in an aqueous solution of AgNO3.The other half cell consists of an inert platinum wire in an aqueous solution containing Fe2+(aq) and Fe3+(aq). (a) Calculate the cell potential, assuming standard conditions. (b) Write the net ionic equation for the reaction occurring in the cell. (c) Which electrode is the anode and which is the cathode? (d) If [Ag+] is 0.10 M, and [Fe2+] and [Fe3+] are both 1.0 M, what is the cell potential? Is the net cell reaction still that used in part (a)? If not, what is the net reaction under the new conditions?arrow_forwardUse the data from the table of standard reduction potentials in Appendix H to calculate the standard potential of the cell based on each of the following reactions. In each case, state whether the reaction proceeds spontaneously as written or spontaneously in the reverse direction under standard-state conditions. (a) H2(g)+Cl2(g)2H+(aq)+2Cl(aq) (b) Al3+(aq)+3Cr2+(aq)Al(s)+3Cr3+(aq) (c) Fe2+(aq)+Ag+(aq)Fe3+(aq)+Ag(s)arrow_forwardAn aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forward
- Another type of battery is the alkaline zinc-mercury cell, in which the cell reaction is Zn(s) + HgO(s) Hg() + ZnO(s) E = + 1.35 V (a) What is the standard free energy change for this reaction? (b) The standard free energy change in a voltaic cell is the maximum electrical energy that the cell can produce. If the reaction in a zinc-mercury cell consumes 1.00 g mercury oxide, what is the standard free energy change? (c) For how many hours could a mercury cell produce a 10-mA current if the limiting reactant is 3.50 g mercury oxide?arrow_forwardThe mass of three different metal electrodes, each from a different galvanic cell, were determined before and after the current generated by the oxidation-reduction reaction in each cell was allowed to flow for a few minutes. The first metal electrode, given the label A, was found to have increased in mass; the second metal electrode, given the label B, did not change in mass; and the third metal electrode, given the label C, was found to have lost mass. Make an educated guess as to which electrodes were active and which were inert electrodes, and which were anode(s) and which were the cathode(s).arrow_forwardAt 298 K, the solubility product constant for PbC2O4 is 8.5 1010, and the standard reduction potential of the Pb2+(aq) to Pb(s) is 0.126 V. (a) Find the standard potential of the half-reaction PbC2O4(s)+2ePb(s)+C2O42(aq) (Hint: The desired half-reaction is the sum of the equations for the solubility product and the reduction of Pb2+. Find G for these two reactions and add them to find G for their sum. Convert the G to the potential of the desired half-reaction.) (b) Calculate the potential of the Pb/PbC2O4 electrode in a 0.025 M solution of Na2C2O4.arrow_forward
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