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Indicate the products obtained when acetophenone reacts with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.
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- In the 1880's, Acetanilide, sold under the name Antifebrin, was widely used as a pain reliever and fever reducer. However, it had many adverse side effects, including cyanosis as a result of methemoglobinemia. The toxic side effects were the result of a small portion of acetanilide being hydrolyzed to aniline. Acetanilide was discontinued and replaced with phenacetin. Later studies show that both acetanilide and phenacetin are metabolized to acetaminophen. This metabolite, which we know as Tylenol, is responsible for the analgesic and antipyretic properties. Part 1: Show a detailed arrow pushing mechanism of the acid catalyzed hydrolysis of acetanilide to aniline Part 2: Propose a synthesis of Acetaminophen from phenol NH NH NH Phenacetin inophen Acetanilide Attach File Browse Local Files Browse Content Collection17-70 What simple chemical test could you use to distinguish between the members of each pair of com pounds? Tell what you would do, what you would expect to observe, and how you would interpret your experimental observation. (a) Benzaldehyde and cyclohexanone (b) Acetaldehyde and acetone17-33 What simple chemical test could you use to distinguish between the members of each pair of com pounds? Tell what you would do, what you would expect to observe, and how you would interpret your experimental observation. (a) Pentanal and 2-pentanone (b) 2-Pentanone and 2-pentanol
- What is the name of the major product formed during the reaction between benzoyl chloride and phenol? benzyl ester O phenyl benzoate ○ cyclopentanoate ○ benzyl phenoate ○ benzenecarboxylic acidIdentify the reagents that can be used to covert benzene into each of the following compounds: Benzene sulfonic acid AcetophenoneWhat reactants are required for the synthesis of butanamide? Group of answer choices butanol and ammonia butanal and ammonia methylpropanoate and ammonia butanoic acid and ammonia butanone and ammonia
- Following are structural formulas for amphetamine and methamphetamine. H NH, CH3 (a) (b) Amphetamine (racemic) Methamphetamine (racemic) The major central nervous system effects of amphetamine and amphetamine-like drugs are locomotor stimulation, euphoria and excitement, stereotyped behavior, and anorexia. Show how each drug can be synthesized by reductive amination of an ap- propriate aldehyde or ketone and amine.1% 83- 80- 70- 60- 50- 40- 30 20- 10- -0- 4000 3622.47cm-1 3547.27cm-1 3430.08cm-1 3064.48cm-1 3500 3033.50cm-1 2999.56cm-1 2952.56cm-1 3000 2844.00cm-1 2500 1725.00cm-1 cm-1 2000 | 1601.55cm-1 1435.67cm-1 1500 966.45cm-1 1027.19cm-1 1071.40cm-1 1111.83cm-1 1000 500In the mid-1930s a substance was isolated from a fungus that is a parasite of ryes and other grasses. This alkaloid, lysergic acid, has been of great interest to chemists because of its strange, dramatic action on the human mind. Many derivatives of lysergic acid are known, some with medicinal applications. Perhaps the best known derivative of lysergic acid is the potent hallucinogen lysergic acid diethylamide (LSD): మగవా జి N-H LSD (CH25N;O) Like other alkaloids, LSD is a weak base, with Kp = 7.6 × 107. What is the pH of a 0.94 M solution of LSD? pH =
- A mixture of the compounds shown below is dissolved in cyclohexane. An aqueous solution of NaOH is added to the solution, and two layers are formed. Which compound(s) is(are) found in the aqueous layer? он HO Benzoic acid Beta-naphthol Naphthalene O Benzoic acid only O Beta-naphthol only O Naphthalene O Both Benzoic acid and beta-naphthol O Both beta-naphthol and naphthalenePhenacetin is an analgesic compound having molecular formula C10H13NO2. Once a common component in over-thecounter pain relievers such as APC (aspirin, phenacetin, caffeine), phenacetin is no longer used because of its liver toxicity. Deduce the structure of phenacetin from its 1H NMR and IR spectra.Which combination of starting compounds should be chosen to prepare pentyl propanoate pentanol and propanal pentanol and pentanoic acid pentanol and propanoic acid propanol and pentanoic acid
