Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Question
Chapter 11, Problem 7PS
(a)
Interpretation Introduction
Interpretation:
From the following, identify which compound is expected to form intermolecular hydrogen bonding in the liquid state.
Concept Introduction:
Hydrogen bonding is the intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule.
Example of hydrogen bonding:
- The hydrogen atom must be directly bonded to a small atom with high electronegative atoms of nitrogen, oxygen and flurine.
- It can form with another molecule is (intermolecular bonding) or another part of the same molecule intramolecular hydrogen bonding.
(b).
Interpretation Introduction
Interpretation:
From the following, identify which compound is expected to form intermolecular hydrogen bonding in the liquid state.
Concept Introduction:
Hydrogen bonding is the intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule.
Example of hydrogen bonding:
- The hydrogen atom must be directly bonded to a small atom with high electronegative atoms of nitrogen, oxygen and flurine.
- It can form with another molecule is (intermolecular bonding) or another part of the same molecule intramolecular hydrogen bonding.
(c).
Interpretation Introduction
Interpretation:
From the following, identify which compound is expected to form intermolecular hydrogen bonding in the liquid state.
Concept Introduction:
Hydrogen bonding is the intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule.
Example of hydrogen bonding:
- The hydrogen atom must be directly bonded to a small atom with high electronegative atoms of nitrogen, oxygen and flurine.
- It can form with another molecule is (intermolecular bonding) or another part of the same molecule intramolecular hydrogen bonding.
(d).
Interpretation Introduction
Interpretation:
From the following, identify which compound is expected to form intermolecular hydrogen bonding in the liquid state.
Concept Introduction:
Hydrogen bonding is the intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule.
Example of hydrogen bonding:
- The hydrogen atom must be directly bonded to a small atom with high electronegative atoms of nitrogen, oxygen and flurine.
- It can form with another molecule is (intermolecular bonding) or another part of the same molecule intramolecular hydrogen bonding.
(e).
Interpretation Introduction
Interpretation:
From the following, identify which compound is expected to form intermolecular hydrogen bonding in the liquid state.
Concept Introduction:
Hydrogen bonding is the intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule.
Example of hydrogen bonding:
- The hydrogen atom must be directly bonded to a small atom with high electronegative atoms of nitrogen, oxygen and flurine.
- It can form with another molecule is (intermolecular bonding) or another part of the same molecule intramolecular hydrogen bonding.
(f).
Interpretation Introduction
Interpretation:
From the following, identify which compound is expected to form intermolecular hydrogen bonding in the liquid state.
Concept Introduction:
Hydrogen bonding is the intermolecular force in which a hydrogen atom that is bonded to a highly electronegative atom is attracted to an unshared pair of electrons of an electronegative atom in a nearby molecule.
Example of hydrogen bonding:
- The hydrogen atom must be directly bonded to a small atom with high electronegative atoms of nitrogen, oxygen and flurine.
- It can form with another molecule is (intermolecular bonding) or another part of the same molecule intramolecular hydrogen bonding.
Expert Solution & Answer
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Students have asked these similar questions
Which of the following compounds would be expected to form intermolecular hydrogen bonds in the liquid state?
(a) CH3OCH3 (dimethyl ether)
(b) CH4
(c) HF
(d) CH3CO2H (acetic acid)
(e) Br2
(f) CH3OH (methanol)
Which of these molecules exhibits only the London dispersion forces (LDF) of interactions?
(A) H2O
(B) CO2
(C) SO2
(D) N2O
Circle all the compounds which would be expected to form intermolecular hydrogen bonds in the liquid
state:
(a) CHOCH3
(b) CHA
(c) HF
(d) CH3CO2H
(e) Br2
(f) CH,OH
Chapter 11 Solutions
Chemistry & Chemical Reactivity
Ch. 11.2 - Which should have the more negative hydration...Ch. 11.3 - Using structural formulas, describe the hydrogen...Ch. 11.4 - Prob. 11.3CYUCh. 11.5 - Prob. 11.4CYUCh. 11.6 - The molar enthalpy of vaporization of methanol,...Ch. 11.6 - Prob. 11.6CYUCh. 11.6 - Prob. 1.1ACPCh. 11.6 - Prob. 1.2ACPCh. 11.6 - Prob. 2.1ACPCh. 11.6 - Prob. 2.2ACP
Ch. 11 - Prob. 1PSCh. 11 - Intermolecular forces: What type of forces must be...Ch. 11 - Prob. 3PSCh. 11 - Prob. 4PSCh. 11 - Considering intermolecular forces in the pure...Ch. 11 - Considering intermolecular forces in the pure...Ch. 11 - Prob. 7PSCh. 11 - Which of the following compounds would be expected...Ch. 11 - Prob. 9PSCh. 11 - When salts of Mg2+, Na+, and Cs+ are placed in...Ch. 11 - Prob. 11PSCh. 11 - The enthalpy of vaporization of liquid mercury is...Ch. 11 - Answer the following questions using Figure 11.12:...Ch. 11 - Answer the following questions using Figure 11.12:...Ch. 11 - Prob. 15PSCh. 11 - Refer to Figure 11.12 to answer these questions:...Ch. 11 - Which member of each of the following pairs of...Ch. 11 - Place the following four compounds in order of...Ch. 11 - Prob. 19PSCh. 11 - You are comparing three different substances, A,...Ch. 11 - Equilibrium vapor pressures of benzene, C6H6, at...Ch. 11 - Prob. 22PSCh. 11 - Can carbon monoxide (Tc = 132.9 K; Pc = 34.5 atm...Ch. 11 - Methane (CH4) cannot be liquefied at room...Ch. 11 - What is surface tension? Give an example...Ch. 11 - What factors affect the viscosity of a substance?...Ch. 11 - If a piece of filter paper (an absorbent paper...Ch. 11 - When water is placed in a buret it forms a concave...Ch. 11 - Prob. 29GQCh. 11 - What types of intermolecular forces are important...Ch. 11 - Which of the following salts, Li2SO4 or Cs2SO4, is...Ch. 11 - Prob. 32GQCh. 11 - Prob. 33GQCh. 11 - Prob. 34GQCh. 11 - Rank the following compounds in order of...Ch. 11 - Prob. 36GQCh. 11 - Prob. 37GQCh. 11 - The following data are the equilibrium vapor...Ch. 11 - Prob. 39ILCh. 11 - A hand boiler can be purchased in toy stores or at...Ch. 11 - Prob. 41ILCh. 11 - Prob. 42ILCh. 11 - Acetone, CH3COCH3, is a common laboratory solvent....Ch. 11 - Cooking oil floats on top of water. From this...Ch. 11 - Liquid ethylene glycol, HOCH2CH2OH, is one of the...Ch. 11 - Liquid methanol, CH3OH, is placed in a glass tube....Ch. 11 - Account for these facts: (a) Although ethanol...Ch. 11 - Prob. 48SCQCh. 11 - Prob. 49SCQCh. 11 - Prob. 50SCQCh. 11 - Prob. 51SCQCh. 11 - Prob. 52SCQCh. 11 - A fluorocarbon, CF4, has a critical temperature of...Ch. 11 - Prob. 55SCQCh. 11 - List four properties of liquids that are directly...Ch. 11 - List the following ions in order of hydration...Ch. 11 - Prob. 59SCQCh. 11 - An 8.82-g sample of Br2 is placed in an evacuated...Ch. 11 - Polarizability is defined as the extent to which...Ch. 11 - Prob. 62SCQCh. 11 - A pressure cooker (a kitchen appliance) is a pot...Ch. 11 - Vapor pressures of NH3() at several temperatures...Ch. 11 - Prob. 65SCQCh. 11 - Prob. 66SCQCh. 11 - Prob. 67SCQ
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