Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 11, Problem 41IL
(a)
Interpretation Introduction
Interpretation: The change happens when a can having
Concept Introduction:
Vapor pressure is nothing but the pressure of a vapor in contact with its liquid or solid form.
When a liquid and vapor are in equilibrium the pressure exerted by the vapor is called the equilibrium vapor pressure.
(b)
Interpretation Introduction
A molecular level sketch of the situation inside the can before heating and after heating has to be drawn.
Concept Introduction:
Vapor pressure is nothing but the pressure of a vapor in contact with its liquid or solid form.
When a liquid and vapor are in equilibrium the pressure exerted by the vapor is called the equilibrium vapor pressure.
If intermolecular force is small the vapor pressure of the substance is high and the boiling point will be low.
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a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here?
b. What is the purpose of the Na2SO4?
c. What equipment would you use to “concentrate [a solution] under reduced pressure”?
Chapter 11 Solutions
Chemistry & Chemical Reactivity
Ch. 11.2 - Which should have the more negative hydration...Ch. 11.3 - Using structural formulas, describe the hydrogen...Ch. 11.4 - Prob. 11.3CYUCh. 11.5 - Prob. 11.4CYUCh. 11.6 - The molar enthalpy of vaporization of methanol,...Ch. 11.6 - Prob. 11.6CYUCh. 11.6 - Prob. 1.1ACPCh. 11.6 - Prob. 1.2ACPCh. 11.6 - Prob. 2.1ACPCh. 11.6 - Prob. 2.2ACP
Ch. 11 - Prob. 1PSCh. 11 - Intermolecular forces: What type of forces must be...Ch. 11 - Prob. 3PSCh. 11 - Prob. 4PSCh. 11 - Considering intermolecular forces in the pure...Ch. 11 - Considering intermolecular forces in the pure...Ch. 11 - Prob. 7PSCh. 11 - Which of the following compounds would be expected...Ch. 11 - Prob. 9PSCh. 11 - When salts of Mg2+, Na+, and Cs+ are placed in...Ch. 11 - Prob. 11PSCh. 11 - The enthalpy of vaporization of liquid mercury is...Ch. 11 - Answer the following questions using Figure 11.12:...Ch. 11 - Answer the following questions using Figure 11.12:...Ch. 11 - Prob. 15PSCh. 11 - Refer to Figure 11.12 to answer these questions:...Ch. 11 - Which member of each of the following pairs of...Ch. 11 - Place the following four compounds in order of...Ch. 11 - Prob. 19PSCh. 11 - You are comparing three different substances, A,...Ch. 11 - Equilibrium vapor pressures of benzene, C6H6, at...Ch. 11 - Prob. 22PSCh. 11 - Can carbon monoxide (Tc = 132.9 K; Pc = 34.5 atm...Ch. 11 - Methane (CH4) cannot be liquefied at room...Ch. 11 - What is surface tension? Give an example...Ch. 11 - What factors affect the viscosity of a substance?...Ch. 11 - If a piece of filter paper (an absorbent paper...Ch. 11 - When water is placed in a buret it forms a concave...Ch. 11 - Prob. 29GQCh. 11 - What types of intermolecular forces are important...Ch. 11 - Which of the following salts, Li2SO4 or Cs2SO4, is...Ch. 11 - Prob. 32GQCh. 11 - Prob. 33GQCh. 11 - Prob. 34GQCh. 11 - Rank the following compounds in order of...Ch. 11 - Prob. 36GQCh. 11 - Prob. 37GQCh. 11 - The following data are the equilibrium vapor...Ch. 11 - Prob. 39ILCh. 11 - A hand boiler can be purchased in toy stores or at...Ch. 11 - Prob. 41ILCh. 11 - Prob. 42ILCh. 11 - Acetone, CH3COCH3, is a common laboratory solvent....Ch. 11 - Cooking oil floats on top of water. From this...Ch. 11 - Liquid ethylene glycol, HOCH2CH2OH, is one of the...Ch. 11 - Liquid methanol, CH3OH, is placed in a glass tube....Ch. 11 - Account for these facts: (a) Although ethanol...Ch. 11 - Prob. 48SCQCh. 11 - Prob. 49SCQCh. 11 - Prob. 50SCQCh. 11 - Prob. 51SCQCh. 11 - Prob. 52SCQCh. 11 - A fluorocarbon, CF4, has a critical temperature of...Ch. 11 - Prob. 55SCQCh. 11 - List four properties of liquids that are directly...Ch. 11 - List the following ions in order of hydration...Ch. 11 - Prob. 59SCQCh. 11 - An 8.82-g sample of Br2 is placed in an evacuated...Ch. 11 - Polarizability is defined as the extent to which...Ch. 11 - Prob. 62SCQCh. 11 - A pressure cooker (a kitchen appliance) is a pot...Ch. 11 - Vapor pressures of NH3() at several temperatures...Ch. 11 - Prob. 65SCQCh. 11 - Prob. 66SCQCh. 11 - Prob. 67SCQ
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