Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
10th Edition
ISBN: 9781305957510
Author: ZUMDAHL, Steven S.; Zumdahl, Susan A.; DeCoste, Donald J.
Publisher: Cengage Learning
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Chapter 11, Problem 7ALQ
Using the phase diagram for water and Raoult’s law, explain why salt is spread on the roads in winter (even when it is below freezing).
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Chapter 11 Solutions
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
Ch. 11 - Prob. 1RQCh. 11 - Using KF as an example, write equations that refer...Ch. 11 - Prob. 3RQCh. 11 - Prob. 4RQCh. 11 - Define the terms in Raoults law. Figure 10-9...Ch. 11 - In terms of Raoults law, distinguish between an...Ch. 11 - Vapor-pressure lowering is a colligative property,...Ch. 11 - What is osmotic pressure? How is osmotic pressure...Ch. 11 - Distinguish between a strong electrolyte, a weak...Ch. 11 - Prob. 10RQ
Ch. 11 - Prob. 1ALQCh. 11 - Once again, consider Fig. 10-9. Suppose instead of...Ch. 11 - Prob. 3ALQCh. 11 - Prob. 4ALQCh. 11 - You have read that adding a solute to a solvent...Ch. 11 - You drop an ice cube (made from pure water) into a...Ch. 11 - Using the phase diagram for water and Raoults law,...Ch. 11 - You and your friend are each drinking cola from...Ch. 11 - Prob. 9ALQCh. 11 - Prob. 10ALQCh. 11 - If a solution shows positive deviations from...Ch. 11 - Prob. 12ALQCh. 11 - Rubbing alcohol contains 585 g isopropanol...Ch. 11 - Prob. 14SRCh. 11 - Prob. 15SRCh. 11 - Prob. 16SRCh. 11 - Calculate the sodium ion concentration when 70.0...Ch. 11 - Write equations showing the ions present after the...Ch. 11 - Rationalize the temperature dependence of the...Ch. 11 - The weak electrolyte NH3(g) does not obey Henrys...Ch. 11 - The two beakers in the sealed container...Ch. 11 - The following plot shows the vapor pressure of...Ch. 11 - When pure methanol is mixed with water, the...Ch. 11 - Prob. 24QCh. 11 - For an acid or a base, when is the normality of a...Ch. 11 - Prob. 26QCh. 11 - Prob. 27QCh. 11 - Prob. 28QCh. 11 - Prob. 29QCh. 11 - Table sugar (C12H22O11) or urea [(NH2)2CO] can be...Ch. 11 - If two different aqueous solutions of proteins...Ch. 11 - An extremely important application of dialysis is...Ch. 11 - Explain the terms isotonic solution, crenation,...Ch. 11 - Prob. 34QCh. 11 - Prob. 35ECh. 11 - A typical IV used in hospitals is dextrose 5% in...Ch. 11 - Prob. 37ECh. 11 - Prob. 38ECh. 11 - Common commercial acids and bases are aqueous...Ch. 11 - In lab you need to prepare at least 100 mL of each...Ch. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Calculate the molarity and mole fraction of...Ch. 11 - Prob. 45ECh. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - a. Use the following data to calculate the...Ch. 11 - Although Al(OH)3 is insoluble in water, NaOH is...Ch. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - For each of the following pairs, predict which...Ch. 11 - Which ion in each of the following pairs would you...Ch. 11 - Rationalize the trend in water solubility for the...Ch. 11 - In flushing and cleaning columns used in liquid...Ch. 11 - The solubility of nitrogen in water is 8.21 104...Ch. 11 - Calculate the solubility of O2 in water at a...Ch. 11 - The vapor pressure of a solution containing 53.6 g...Ch. 11 - An aqueous solution containing glucose has a vapor...Ch. 11 - The normal boiling point of diethyl ether is...Ch. 11 - At a certain temperature, the vapor pressure of...Ch. 11 - Prob. 63ECh. 11 - A solution is prepared by mixing 0.0300 mole of...Ch. 11 - What is the composition of a methanol...Ch. 11 - Benzene and toluene form an ideal solution....Ch. 11 - Which of the following will have the lowest total...Ch. 11 - Prob. 68ECh. 11 - Match the vapor pressure diagrams with the...Ch. 11 - The vapor pressures of several solutions of...Ch. 11 - A solution is prepared by dissolving 27.0 g urea,...Ch. 11 - A 2.00-g sample of a large biomolecule was...Ch. 11 - What mass of glycerin (C3H8O3), a nonelectrolyte,...Ch. 11 - The freezing point of 1-butanol is 25.50C and Kf...Ch. 11 - Prob. 75ECh. 11 - What volume of ethylene glycol (C2H6O2), a...Ch. 11 - Reserpine is a natural product isolated from the...Ch. 11 - A solution contains 3.75 g of a nonvolatile pure...Ch. 11 - a. Calculate the freezing-point depression and...Ch. 11 - Erythrocytes are red blood cells containing...Ch. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Consider the following solutions: 0.010 m Na3PO4...Ch. 11 - From the following: pure water solution of...Ch. 11 - Prob. 87ECh. 11 - Prob. 88ECh. 11 - Prob. 89ECh. 11 - Consider the following representations of an ionic...Ch. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Use the following data for three aqueous solutions...Ch. 11 - The freezing-point depression of a 0.091-m...Ch. 11 - Prob. 95ECh. 11 - A 0.500-g sample of a compound is dissolved in...Ch. 11 - The solubility of benzoic acid (HC7H5O2), is 0.34...Ch. 11 - Prob. 99AECh. 11 - Prob. 100AECh. 11 - Prob. 101AECh. 11 - In Exercise 96 in Chapter 8, the pressure of CO2...Ch. 11 - Explain the following on the basis of the behavior...Ch. 11 - The term proof is defined as twice the percent by...Ch. 11 - Prob. 105AECh. 11 - Prob. 106AECh. 11 - A solution is made by mixing 50.0 g acetone...Ch. 11 - Prob. 108AECh. 11 - Thyroxine, an important hormone that controls the...Ch. 11 - Prob. 110AECh. 11 - An unknown compound contains only carbon,...Ch. 11 - Prob. 112AECh. 11 - Prob. 113AECh. 11 - Prob. 115AECh. 11 - Patients undergoing an upper gastrointestinal...Ch. 11 - Prob. 118CWPCh. 11 - The lattice energy of NaCl is 786 kJ/mol, and the...Ch. 11 - For each of the following pairs, predict which...Ch. 11 - The normal boiling point of methanol is 64.7C. A...Ch. 11 - A solution is prepared by mixing 1.000 mole of...Ch. 11 - Prob. 123CWPCh. 11 - A 4.7 102 mg sample of a protein is dissolved in...Ch. 11 - A solid consists of a mixture of NaNO3 and...Ch. 11 - The vapor pressure of pure benzene is 750.0 torr...Ch. 11 - Prob. 127CPCh. 11 - Plants that thrive in salt water must have...Ch. 11 - You make 20.0 g of a sucrose (C12H22O11) and NaCl...Ch. 11 - Prob. 130CPCh. 11 - The vapor in equilibrium with a pentane-hexane...Ch. 11 - A forensic chemist is given a white solid that is...Ch. 11 - A 1.60-g sample of a mixture of naphthalene...Ch. 11 - Prob. 134CPCh. 11 - Prob. 135CPCh. 11 - You have a solution of two volatile liquids, A and...Ch. 11 - In some regions of the southwest United States,...Ch. 11 - Specifications for lactated Ringers solution,...Ch. 11 - Creatinine, C4H7N3O, is a by-product of muscle...Ch. 11 - An aqueous solution containing 0.250 mole of Q, a...Ch. 11 - Anthraquinone contains only carbon, hydrogen, and...
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- Sodium chloride (NaCl) is commonly used to melt ice on roads during the winter. Calcium chloride (CaCl2) is sometimes used for this purpose too. Let us compare the effectiveness of equal masses of these two compounds in lowering the freezing point of water, by calculating the freezing point depression of solutions containing 200. g of each salt in 1.00 kg of water. (An advantage of CaCl2 is that it acts more quickly because it is hygroscopic, that is. it absorbs moisture from the air to give a solution and begin the process. A disadvantage is that this compound is more costly.)arrow_forwardA sample of water contains 0.010 ppm lead ions, Pb2+. (a) Calculate the mass of lead ions per liter in this solution.(Assume the density of the water solution is 1.0 g/mL.) (b) Calculate the mass fraction of lead in ppb.arrow_forwardDistinguish between dispersion methods and condensation methods for preparing colloidal systems.arrow_forward
- The freezing point of 0.109 m aqueous formic acid is 0.210C. Formic acid, HCHO2, is partially dissociated according to the equation HCHO2(aq)H+(aq)+CHO2(aq) Calculate the percentage of HCHO2 molecules that are dissociated, assuming the equation for the freezing-point depression holds for the total concentration of molecules and ions in the solution.arrow_forwardFreezing point depression is one means of determining the molar mass of a compound. The freezing point depression constant of benzene is 5.12 C/m. a. When a 0.503 g sample of the white crystalline dimer is dissolved in 10.0 g benzene, the freezing point of benzene is decreased by 0542 C. Verify that the molar mass of the dimer is 475 g/mol when determined by freezing point depression. Assume no dissociation of the dimer occurs. b. The correct molar mass of the dimer is 487 g/mol. Explain why the dissociation equilibrium causes the freezing point depression calculation to yield a lower molar mass for the dimer.arrow_forwardA 1.00 mol/kg aqueous sulfuric acid solution, H2SO4,freezes at 4.04 C. Calculate i, the vant Hoff factor,for sulfuric acid in this solution.arrow_forward
- A 0.109 mol/kg aqueous solution of formic acid, HCOOH, freezes at −0.210 °C. Calculate the percent dissociation of formic acid.arrow_forwardConsider three test tubes. Tube A has pure water. Tube B has an aqueous 1.0 m solution of ethanol, C2H5OH. Tube C has an aqueous 1.0 m solution of NaCl. Which of the following statements are true? (Assume that for these solutions 1.0m=1.0M.) (a) The vapor pressure of the solvent over tube A is greater than the solvent pressure over tube B. (b) The freezing point of the solution in tube B is higher than the freezing point of the solution in tube A. (c) The freezing point of the solution in tube B is higher than the freezing point of the solution in tube C. (d) The boiling point of the solution in tube B is higher than the boiling point of the solution in tube C. (e) The osmotic pressure of the solution in tube B is greater than the osmotic pressure of the solution in tube C.arrow_forwardThe dispersed phase of a certain colloidal dispersion consists of spheres of diameter 1.0 102 nm. (a) What are the volume (V=43r2) and surface area (A = r2) of each sphere? (b) How many spheres are required to give a total volume of 1.0 cm3? What is the total surface area of these spheres in square meters?arrow_forward
- Calculate the molality of a solution made by dissolving 115.0 g ethylene glycol, HOCH2CH2OH, in 500. mL water. The density of water at this temperature is 0.978 g/mL. Calculate the molarity of the solution.arrow_forwardThe following table lists the concentrations of the principal ions in seawater: (a) Calculate the freezing point of seawater. (b) Calculate the osmotic pressure of seawater at 25 C. What is the minimum pressure needed to purify seawater by reverse osmosis?arrow_forwardRefer to Figure 13.10 ( Sec. 13-4b) to answer these questions. (a) Does a saturated solution occur when 65.0 g LiCl is present in 100 g H2O at 40 C? Explain your answer. (b) Consider a solution that contains 95.0 g LiCl in 100 g H2O at 40 C. Is the solution unsaturated, saturated, or supersaturated? Explain your answer. (c) Consider a solution that contains 50. g Li2SO4 in 200. g H2O at 50 C. Is this solution unsaturated, saturated, or supersaturated? Explain your answer. Figure 13.10 Solubility of ionic compounds versus temperature.arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY