(a) Interpretation: The element that is least reactive in group 1 is to be stated. Concept Introduction: Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Question

Describe the principle of resonance and give a set of Lewis Structures to illustrate your explanation.

Answer 1

Question

Chapter 11, Problem 79QAP

Interpretation Introduction

(a)

Interpretation:

The element that is least reactive in group 1 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(b)

Interpretation:

The element that is least reactive in group 7 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(c)

Interpretation:

The element that is least reactive in group 2 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(d)

Interpretation:

The element that is least reactive in group 6 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

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Describe the principle of resonance and give a set of Lewis Structures to illustrate your explanation.

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It is not unexpected that the methoxyl substituent on a cyclohexane ring prefers to adopt the equatorial conformation. OMe H A G₂ = +0.6 kcal/mol OMe What is unexpected is that the closely related 2-methoxytetrahydropyran prefers the axial conformation: H H OMe OMe A Gp=-0.6 kcal/mol Methoxy: CH3O group Please be specific and clearly write the reason why this is observed. This effect that provides stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO interacting with anti-bonding MO...]

Answer 2

Question

Chapter 11, Problem 79QAP

Interpretation Introduction

(a)

Interpretation:

The element that is least reactive in group 1 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(b)

Interpretation:

The element that is least reactive in group 7 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(c)

Interpretation:

The element that is least reactive in group 2 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(d)

Interpretation:

The element that is least reactive in group 6 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

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Answer 3

Question

Chapter 11, Problem 79QAP

Interpretation Introduction

(a)

Interpretation:

The element that is least reactive in group 1 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(b)

Interpretation:

The element that is least reactive in group 7 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(c)

Interpretation:

The element that is least reactive in group 2 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(d)

Interpretation:

The element that is least reactive in group 6 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

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Answer 4

Question

Chapter 11, Problem 79QAP

Interpretation Introduction

(a)

Interpretation:

The element that is least reactive in group 1 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(b)

Interpretation:

The element that is least reactive in group 7 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(c)

Interpretation:

The element that is least reactive in group 2 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(d)

Interpretation:

The element that is least reactive in group 6 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

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Answer 5

Chapter 11, Problem 79QAP

Interpretation Introduction

(a)

Interpretation:

The element that is least reactive in group 1 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(b)

Interpretation:

The element that is least reactive in group 7 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(c)

Interpretation:

The element that is least reactive in group 2 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Interpretation Introduction

(d)

Interpretation:

The element that is least reactive in group 6 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 6

Chapter 11, Problem 79QAP

Interpretation Introduction

(a)

Interpretation:

The element that is least reactive in group 1 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 7

Chapter 11, Problem 79QAP

Interpretation Introduction

(a)

Interpretation:

The element that is least reactive in group 1 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The element that is least reactive in group 7 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The element that is least reactive in group 7 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The element that is least reactive in group 2 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The element that is least reactive in group 2 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The element that is least reactive in group 6 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The element that is least reactive in group 6 is to be stated.

Concept Introduction:

Reactivity of an element depends on its size, ionization energy, number of valence electrons in the atom. On going down the group, the reactivity of the elements increases in case of metals and decreases in case of nonmetals. This unusual trend is because of the reactivity difference in metals and nonmetals.

Answer 14

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