Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 11, Problem 73E
How do colloids differ from solutions with regard to dispersed particle size and homogeneity?
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
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m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
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1.3
183.0
197.0
100.0
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200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
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ō (ppm)
4
2
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ō (ppm)
LOD
D
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HAVENUMBERI -11
Chapter 11 Solutions
Chemistry Atoms First2e
Ch. 11 - How do solutions differ from compounds? From other...Ch. 11 - Which of the principal characteristics of...Ch. 11 - When KNO3 is dissolved in water, the resulting...Ch. 11 - Give an example of each of the following types of...Ch. 11 - Indicate the most important types of...Ch. 11 - Predict whether each of the following substances...Ch. 11 - Heat is released when some solutions form; heat is...Ch. 11 - Solutions of hydrogen in palladium may be formed...Ch. 11 - Explain why the ions Na+ and CI- are strongly...Ch. 11 - Explain why solutions of HBr in benzene (a...
Ch. 11 - Consider the solutions presented: (a) Which of the...Ch. 11 - Compare the processes that occur when methanol...Ch. 11 - What is the expected electrical conductivity of...Ch. 11 - Why are most solid ionic compounds electrically...Ch. 11 - Indicate the most important type of intermolecular...Ch. 11 - Suppose you are presented with a clear solution of...Ch. 11 - Supersaturated solutions of most solids in water...Ch. 11 - Suggest an explanation for the observations that...Ch. 11 - Calculate the percent by mass of KBr in a...Ch. 11 - Which of the following gases is expected to be...Ch. 11 - At 0 C and 1.00 atm, as much as 0.70 g of O2 can...Ch. 11 - Refer to Figure 11.10. (a) How did the...Ch. 11 - The Henrys law constant for CO2 is 3.4102 M/atm at...Ch. 11 - The Henrys law constant for O2 is 1.3103 M/ atm at...Ch. 11 - Assuming ideal solution behavior, how many liters...Ch. 11 - Which is are part of the macroscopic domain of...Ch. 11 - What is the microscopic explanation for the...Ch. 11 - Sketch a qualitative graph of the pressure versus...Ch. 11 - A solution of potassium nitrate, an electrolyte,...Ch. 11 - What are the mole fractions of H3PO4 and water in...Ch. 11 - What are the mole fractions of HNO3 and water in a...Ch. 11 - Calculate the mole fraction of each solute and...Ch. 11 - Calculate the mole fraction of each solute and...Ch. 11 - Calculate the mole fractions of methanol, CH3OH;...Ch. 11 - What is the difference between a 1 M solution and...Ch. 11 - What is the molality of phosphoric acid, H3PO4, in...Ch. 11 - What is the molality of nitric acid in a...Ch. 11 - Calculate the molality of each of the following...Ch. 11 - Calculate the molality of each of the following...Ch. 11 - The concentration of glucose, C6H12O6, in normal...Ch. 11 - A 13.0% solution of K2CO3 by mass has a density of...Ch. 11 - Why does 1 mol of sodium chloride depress the...Ch. 11 - Assuming ideal solution behavior what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is osmotic...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - A sample of an organic compound (a nonelectrolyte)...Ch. 11 - A 1.0 m solution of HCI in benzene has a freezing...Ch. 11 - A solution contains 5.00 g of urea, CO(NH2)2 , a...Ch. 11 - A 12.O-g sample of a nonelectrolyte is dissolved...Ch. 11 - Arrange the following solutions in order by their...Ch. 11 - Calculate the boiling point elevation of 0.100 kg...Ch. 11 - How could you prepare a 3.08m aqueous solution of...Ch. 11 - A sample of sulfur weighing 0.210 g was dissolved...Ch. 11 - In a significant experiment performed many years...Ch. 11 - Lysozyme is an enzyme that cleaves cell walls. A...Ch. 11 - The osmotic pressure of a solution containing 7.0...Ch. 11 - The osmotic pressure of human blood is 7.6 atm at...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - The sugar fructose contains 40.0% C, 6.7% H, and...Ch. 11 - The vapor pressure of methanol, CH3OH, is 94 torr...Ch. 11 - The triple point of air-free water is defined as...Ch. 11 - Meat can be classified as fresh (not frozen) even...Ch. 11 - An organic compound has a composition of 93.46% C...Ch. 11 - A sample of HgCI2 weighing 9.41 g is dissolved in...Ch. 11 - A salt is known to be an alkali metal fluoride. A...Ch. 11 - Identify the dispersed phase and the dispersion...Ch. 11 - Distinguish between dispersion methods and...Ch. 11 - How do colloids differ from solutions with regard...Ch. 11 - Explain the cleansing action of soap.Ch. 11 - How can it be demonstrated that colloidal...
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
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