Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 11, Problem 17E
Supersaturated solutions of most solids in water are prepared by cooling saturated solutions. Supersaturated solutions of most gases in water are prepared by heating saturated solutions. Explain the reasons for the difference in the two procedures.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
3. Refer to the data below to answer the following questions:
Isoelectric point
Amino Acid
Arginine
10.76
Glutamic Acid
3.22
Tryptophan
5.89
A. Define isoelectric point.
B. The most basic amino acid is
C. The most acidic amino acid is
sidizo zo
3. A gas mixture contains 50 mol% H2 and 50 mol% He.
1.00-L samples of this gas mixture are mixed with
variable volumes of O2 (at 0 °C and 1 atm). A spark is
introduced to allow the mixture to undergo complete
combustion. The final volume is measured at 0 °C and 1
atm. Which graph best depicts the final volume as a
function of the volume of added O2?
(A)
2.00
1.75
Final Volume, L
1.50
1.25
1.00
0.75
0.50
0.25
0.00
0.00
0.25
0.50
2.00
(B)
1.75
1.50
Final Volume, L
1.25
1.00
0.75
0.50-
0.25
0.00
0.75
1.00
0.00
0.25
Volume O₂ added, L
2
0.50
0.75
1.00
Volume O₂ added, L
2
2.00
2.00
(C)
(D)
1.75
1.75
1.50
1.50
Final Volume, L
1.25
1.00
0.75
0.50
Final Volume, L
1.25
1.00
0.75
0.50
0.25
0.25
0.00
0.00
0.00
0.25
0.50
0.75
1.00
0.00
0.25
Volume O₂ added, L
0.50
0.75
1.00
Volume O₂ added, L
2
Leucine is an essential amino acid with the systematic name 2-amino-3-methylpentanoic acid. It has pai
2.36 and pKa2 = 9.60.
H2N-C(R)H-COOH and R is -CH2-CH(CH3)2
A. Draw the condensed structure for leucine, and label all chirality centers with an asterisk.
B. How many possible stereoisomers of leucine are there?
C. Draw a Fischer projection of L-leucine and label the chirality center(s) as R or S.
D. What is the p/ of leucine?
E. Draw the structure of the predominant form of leucine at 10.00.
F.
Draw the structure of the predominant form of leucine at pH = 1.50.
G. Leucine is described as an essential amino acid. What does this mean?
H. Show the alkyl halide you would use to prepare leucine by the amidomalonate method.
=
Chapter 11 Solutions
Chemistry Atoms First2e
Ch. 11 - How do solutions differ from compounds? From other...Ch. 11 - Which of the principal characteristics of...Ch. 11 - When KNO3 is dissolved in water, the resulting...Ch. 11 - Give an example of each of the following types of...Ch. 11 - Indicate the most important types of...Ch. 11 - Predict whether each of the following substances...Ch. 11 - Heat is released when some solutions form; heat is...Ch. 11 - Solutions of hydrogen in palladium may be formed...Ch. 11 - Explain why the ions Na+ and CI- are strongly...Ch. 11 - Explain why solutions of HBr in benzene (a...
Ch. 11 - Consider the solutions presented: (a) Which of the...Ch. 11 - Compare the processes that occur when methanol...Ch. 11 - What is the expected electrical conductivity of...Ch. 11 - Why are most solid ionic compounds electrically...Ch. 11 - Indicate the most important type of intermolecular...Ch. 11 - Suppose you are presented with a clear solution of...Ch. 11 - Supersaturated solutions of most solids in water...Ch. 11 - Suggest an explanation for the observations that...Ch. 11 - Calculate the percent by mass of KBr in a...Ch. 11 - Which of the following gases is expected to be...Ch. 11 - At 0 C and 1.00 atm, as much as 0.70 g of O2 can...Ch. 11 - Refer to Figure 11.10. (a) How did the...Ch. 11 - The Henrys law constant for CO2 is 3.4102 M/atm at...Ch. 11 - The Henrys law constant for O2 is 1.3103 M/ atm at...Ch. 11 - Assuming ideal solution behavior, how many liters...Ch. 11 - Which is are part of the macroscopic domain of...Ch. 11 - What is the microscopic explanation for the...Ch. 11 - Sketch a qualitative graph of the pressure versus...Ch. 11 - A solution of potassium nitrate, an electrolyte,...Ch. 11 - What are the mole fractions of H3PO4 and water in...Ch. 11 - What are the mole fractions of HNO3 and water in a...Ch. 11 - Calculate the mole fraction of each solute and...Ch. 11 - Calculate the mole fraction of each solute and...Ch. 11 - Calculate the mole fractions of methanol, CH3OH;...Ch. 11 - What is the difference between a 1 M solution and...Ch. 11 - What is the molality of phosphoric acid, H3PO4, in...Ch. 11 - What is the molality of nitric acid in a...Ch. 11 - Calculate the molality of each of the following...Ch. 11 - Calculate the molality of each of the following...Ch. 11 - The concentration of glucose, C6H12O6, in normal...Ch. 11 - A 13.0% solution of K2CO3 by mass has a density of...Ch. 11 - Why does 1 mol of sodium chloride depress the...Ch. 11 - Assuming ideal solution behavior what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is osmotic...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - A sample of an organic compound (a nonelectrolyte)...Ch. 11 - A 1.0 m solution of HCI in benzene has a freezing...Ch. 11 - A solution contains 5.00 g of urea, CO(NH2)2 , a...Ch. 11 - A 12.O-g sample of a nonelectrolyte is dissolved...Ch. 11 - Arrange the following solutions in order by their...Ch. 11 - Calculate the boiling point elevation of 0.100 kg...Ch. 11 - How could you prepare a 3.08m aqueous solution of...Ch. 11 - A sample of sulfur weighing 0.210 g was dissolved...Ch. 11 - In a significant experiment performed many years...Ch. 11 - Lysozyme is an enzyme that cleaves cell walls. A...Ch. 11 - The osmotic pressure of a solution containing 7.0...Ch. 11 - The osmotic pressure of human blood is 7.6 atm at...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - Assuming ideal solution behavior, what is the...Ch. 11 - The sugar fructose contains 40.0% C, 6.7% H, and...Ch. 11 - The vapor pressure of methanol, CH3OH, is 94 torr...Ch. 11 - The triple point of air-free water is defined as...Ch. 11 - Meat can be classified as fresh (not frozen) even...Ch. 11 - An organic compound has a composition of 93.46% C...Ch. 11 - A sample of HgCI2 weighing 9.41 g is dissolved in...Ch. 11 - A salt is known to be an alkali metal fluoride. A...Ch. 11 - Identify the dispersed phase and the dispersion...Ch. 11 - Distinguish between dispersion methods and...Ch. 11 - How do colloids differ from solutions with regard...Ch. 11 - Explain the cleansing action of soap.Ch. 11 - How can it be demonstrated that colloidal...
Additional Science Textbook Solutions
Find more solutions based on key concepts
8. Studies of DNA support which of the following?
a. Members of the group called australopiths were the first t...
Campbell Biology: Concepts & Connections (9th Edition)
The central nervous system is responsible for: a. integrative functions. b. sensory functions. c. motor functio...
Human Anatomy & Physiology (2nd Edition)
The following variances were calculated for two traits in a herd of hogs. (a) Calculate broad-sense (H2) and na...
Concepts of Genetics (12th Edition)
For the generic equilibrium HA(aq) ⇌ H + (aq) + A- (aq), which of these statements is true?
The equilibrium con...
Chemistry: The Central Science (14th Edition)
Body, Heal Thyself The precision of mitotic cell division is essential for repairing damaged tissues like those...
Biology: Life on Earth with Physiology (11th Edition)
One isomer of methamphetamine is the addictive illegal drug known as crank. Another isomer is a medicine for si...
Campbell Essential Biology (7th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- a) Write out 6 completely different reactions of acetophenone (reagent, product). b) Write out 3 preparations of 1-methylcyclohexanol, using a different starting material for each one. You may use preps where you just change the functional group, and/or preps where you construct the carbon chain. c) Write out 3 preparations of 2-ethoxybenzoic acid, a different starting material for each one. You may use preps where you just change the functional group, and/or preps where you construct the carbon chain.arrow_forward12. CH3 OH OH H&C CH3 H₂C N OH H₂C CH3 H&C CH3 H₂C' CH3 H.C CH3OH H.C CH2CH3OH CH3CEN Which one of these 17 compounds is represented by this IR and this 'H NMR spectrum? IR Spectrum 3000 4000 3000 NMR Spectrum 2000 £500 RAVENUMBER 2000 1500 9 8 6 5 10 HP-00-290 ppm m 1000 500 1000 4 °arrow_forwardDraw the structure of (E,6R) 6-methoxy-4-hepten-2-one. Give the IUPAC name of this compound, including stereochemistry. Draw the most stable chair conformation of (cis) 1,3-isobutylcyclohexane. H HC=CCH₂ CH2CH3 EN(CH3)2 -CN(CH3)2arrow_forward
- 10. Write out the mechanism (intermediate/transition state) for this reaction; indicate stereochemistry in product. H3C CH₂OH CH3 SN1 Harrow_forwardWrite "most" under the member of each trio which is most stable. Write "least under the member of each trio which is least stable. b) Draw a Fischer projection of a pair of enantiomers with three chiral carbons. Which of these two would you expect to be more soluble in water? Why? 1-butanol 1-heptanol Which of these two would you expect to have the higher boiling point? Why? hexyl methyl ether 1-heptanolarrow_forwardWrite "most" under the most acidic compound. Write "least" under the least acidic compound. OH NO₂ OCH3 Br 9. Compound X, C50H84F2, reacts with excess H2/Pd to give a C50H88F2 compound. How many rings are in X? How many double bonds are in X? Show your work.arrow_forward
- 4. State whether these two are: a) the same molecule b) c) d) different compounds that are not isomers constitutional isomers diastereomers e) enantiomers CH3 CH₁₂ H OH HO H H OH HO H CH, CH₂ 5. a) How many stereocenters does this compound have? b) How many stereoisomers are possible for this compound? CH₂ OH CHCHarrow_forwardCalculating the pH at equivalence of a titration A chemist titrates 210.0 mL of a 0.1003 M hydrobromic acid (HBr) solution with 0.7550M KOH solution at 25 °C. Calculate the pH at equivalence. Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added. pH = ] ☑ o0o 18 Ararrow_forwardDo you do chemistry assignmentsarrow_forward
- Using the conditions of spontaneity to deduce the signs of AH and AS Use the observations about each chemical reaction in the table below to decide the sign (positive or negative) of the reaction enthalpy AH and reaction entropy AS. Note: if you have not been given enough information to decide a sign, select the "unknown" option. reaction observations conclusions A This reaction is always spontaneous, but proceeds slower at temperatures above 120. °C. ΔΗ is (pick one) AS is (pick one) ΔΗ is (pick one) B This reaction is spontaneous except above 117. °C. AS is (pick one) ΔΗ is (pick one) This reaction is slower below 20. °C than C above. AS is |(pick one) ? 18 Ar 1arrow_forwardCalculating the pH at equivalence of a titration Try Again Your answer is incorrect. 0/5 a A chemist titrates 70.0 mL of a 0.7089 M hydrocyanic acid (HCN) solution with 0.4574M KOH solution at 25 °C. Calculate the pH at equivalence. The pK of hydrocyanic acid is 9.21. Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added. pH = 11.43] G 00. 18 Ar B•arrow_forwardBiological Macromolecules Naming and drawing the products of aldose oxidation and reduction aw a Fischer projection of the molecule that would produce L-ribonic acid if it were subjected to mildly oxidizing reaction conditions. Click and drag to start drawing a structure. X AP ‡ 1/5 Naor Explanation Check McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Center Accessibilarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY