Indicate the most important type of intermolecular attraction responsible for solvation in each of the following solutions: (a) the solutions In Figure 11.7 (b) methanol, CH 3 OH, dissolved in ethanol, C 2 H 5 OH (C) methane, CH 4 , dissolved in benzene, C 6 H 6 (d) the polar halocarbon CF 2 C1 2 dissolved In the polar halocarbon CF 2 C1CFCI 2 (e) O 2 (1) in N 2(1) Figure 117 As potassium chloride (KCI) dissolves in water, the ions are hydrated. The polar water molecuIes are attracted by the charges on the K + and Cl - ions. Water molecules in front of and behind the ions are not shown.
Indicate the most important type of intermolecular attraction responsible for solvation in each of the following solutions: (a) the solutions In Figure 11.7 (b) methanol, CH 3 OH, dissolved in ethanol, C 2 H 5 OH (C) methane, CH 4 , dissolved in benzene, C 6 H 6 (d) the polar halocarbon CF 2 C1 2 dissolved In the polar halocarbon CF 2 C1CFCI 2 (e) O 2 (1) in N 2(1) Figure 117 As potassium chloride (KCI) dissolves in water, the ions are hydrated. The polar water molecuIes are attracted by the charges on the K + and Cl - ions. Water molecules in front of and behind the ions are not shown.
Indicate the most important type of intermolecular attraction responsible for solvation in each of the following solutions:
(a) the solutions In Figure 11.7
(b) methanol,
CH
3
OH,
dissolved in ethanol,
C
2
H
5
OH
(C) methane, CH4, dissolved in benzene,
C
6
H
6
(d) the polar halocarbon
CF
2
C1
2
dissolved In the polar halocarbon
CF
2
C1CFCI
2
(e)
O
2
(1)
in
N
2(1)
Figure 117 As potassium chloride (KCI) dissolves in water, the ions are hydrated. The polar water molecuIes are attracted by the charges on the K+ and Cl- ions. Water molecules in front of and behind the ions are not shown.
2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
Question
Which of the following predicts the theoretical yield of SO2(g) from the reaction?
Responses
1.2 g
Answer A: 1.2 grams
A
41 g
Answer B: 41 grams
B
77 g
Answer C: 77 grams
C
154 g
Answer D: 154 grams
D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
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