The respective reactant (methyl substituted piperidine) and respective product (diene) should be given. Concept introduction: Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt. These quaternary ammonium salt under goes an elimination reaction easily. Hofmann elimination: Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

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Answer 1

Question

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

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Answer 2

Question

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

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Answer 3

Question

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

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Answer 4

Question

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

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Answer 5

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 6

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 7

Chapter 11, Problem 65P

(a)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination. Proton abstraction is takes place in β- carbon atom which is having more number of hydrogen.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The respective reactant (methyl substituted piperidine) and respective product (diene) should be given.

Concept introduction:

Generally amines can’t undergo elimination reaction, therefore amines can be converted in to quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate, and this ammonium halide is treating with silver oxide to give ammonium hydroxide salt.

These quaternary ammonium salt under goes an elimination reaction easily.

Hofmann elimination:

Quaternary ammonium ion undergoes elimination when using strong base like hydroxide ion this reaction is called as Hofmann elimination.

In the Hofmann elimination, abstraction of proton form β- carbon atom which is having more number of hydrogen to result the elimination product.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 11.1 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 11.1 - Prob. 2P Ch. 11.1 - Prob. 5P Ch. 11.2 - Prob. 7P Ch. 11.3 - Prob. 9P Ch. 11.3 - Show how 1-propanol can be converted into the...Ch. 11.4 - Which of the following alcohols dehydrates the...Ch. 11.4 - Prob. 12P Ch. 11.4 - Prob. 13P Ch. 11.4 - Propose a mechanism for each of the following...

Solution Summary: The author explains how amines can be converted into quaternary ammonium halide by treating with ethyl iodide in basic solution of potassium carbonate.

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