Calculate the pH of the cathode compartment for the following reaction given when
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Chemical Principles
- An aqueous solution of an unknown salt of vanadium is electrolyzed by a current of 2.50 amps for 1.90 hours. The electroplating is carried out with an efficiency of 95.0%, resulting in a deposit of 2.850 g of vanadium. a How many faradays are required to deposit the vanadium? b What is the charge on the vanadium ions (based on your calculations)?arrow_forwardAn aqueous solution of an unknown salt of gold is electrolyzed by a current of 2.75 amps for 3.39 hours. The electroplating is carried out with an efficiency of 93.0%, resulting in a deposit of 21.221 g of gold. a How many faradays are required to deposit the gold? b What is the charge on the gold ions (based on your calculations)?arrow_forwardChlorine, Cl2, is produced commercially by the electrolysis of aqueous sodium chloride. The anode reaction is 2Cl(aq)Cl2(g)+2e How long will it take to produce 2.00 kg of chlorine if the current is 5.00 102 A?arrow_forward
- Hydrazine, N2H4, has been proposed as the fuel in a fuel cell in which oxygen is the oxidizing agent. The reactions are N2H4(aq) + 4 OH(aq) N2(g) + 4 H2O() + 4e O2(g) + 2 H2O() + 4e 4 OH(aq) (a) Which reaction occurs at the anode and which at thecathode? (b) What is the overall cell reaction? (c) If the cell is to produce 0.50 A of current for 50.0 h, calculate what mass in grams of hydrazine must be present. (d) Calculate what mass (g) of O2 must be available to reactwith the mass of N2H4 determined in part (c).arrow_forwardAn electrode is prepared by dipping a silver strip into a solution saturated with silver thiocyanate, AgSCN, and containing 0.10 M SCN . The cell potential of the voltaic cell constructed by connecting this electrode as the cathode to the standard hydrogen half-cell as the anode is 0.45 V. What is the solubility product of silver thiocyanate?arrow_forwardElectrolysis of a solution of CuSO4(aq) to give copper metal is carried out using a current of 0.66 A. How long should electrolysis continue to produce 0.50 g of copper?arrow_forward
- In the commercial preparation of aluminum, aluminum oxide, Al2O3, is electrolyzed at 1000C. (The mineral cryolite is added as a solvent.) Assume that the cathode reaction is Al3+3eAl How many coulombs of electricity are required to give 3.9 kg of aluminum?arrow_forwardOrder the following oxidizing agents by increasing strength under standard-state conditions: Mg2+(aq), Hg2+(aq), Pb2+(aq).arrow_forwardAnswer the following questions by referring to standard electrode potentials at 25C. a Will oxygen, O2, oxidize iron(II) ion in solution under standard conditions? b Will copper metal reduce 1.0 M Ni2(aq) to metallic nickel?arrow_forward
- Assume the following electrochemical cell simulates the galvanic cell formed by copper and zinc in seawater at pH 7.90 and 25 C. Zn | Zn(OH)2(s) | OH(aq) || Cu(OH)2(s) | Cu(s) a. Write a balanced equation for the reaction that occurs at the cathode. b. Write a balanced equation for the reaction that occurs at the anode. c. Write a balanced chemical equation for the overall reaction. d. Determine the potential (in volts) of the cell.arrow_forwardUse electrode potentials to answer the following questions, assuming standard conditions. a Do you expect permanganate ion (MnO4 ) to oxidize chloride ion to chlorine gas in acidic solution? b Will dichromate ion (Cr2O72) oxidize chloride ion to chlorine gas in acidic solution?arrow_forwardCalcium metal can be obtained by the direct electrolysis of molten CaCl2, at a voltage of 3.2 V. (a) How many joules of electrical energy are required to obtain 12.0 1b of calcium? (b) What is the cost of the electrical energy obtained in (a) if electrical energy is sold at the rate of nine cents per kilowatt hour?arrow_forward
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