(a)
Interpretation: The strongest oxidizing agent from the given species needs to be identified.
Concept Introduction: The substance that can easily reduce is oxidizing agent. They are on left side of reduction half reactions.
The substances that get easily oxidized are reducing agent. They are on right side of the reduction half reactions.
(b)
Interpretation: The strongest reducing agent from the given species needs to be identified.
Concept Introduction: The substances that get easily oxidized are reducing agent. They are on right side of the reduction half reactions. More negative standard reduction potential is better is reducing agent.
(c)
Interpretation: The species that can be oxidized by
Concept Introduction: The substance that can easily reduce is oxidizing agent. They are on left side of reduction half reactions. More positive standard reduction potential is better is reducing agent.
(d)
Interpretation: The species that can be reduced by Al (s) needs to be determined.
Concept Introduction: The substance that can easily reduce is oxidizing agent. They are on left side of reduction half reactions. More positive standard reduction potential is better is reducing agent.
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Chemical Principles
- Consider the following cell running under standard conditions: Fe(s)Fe2+(aq)Al3+(aq)Al(s) a Is this a voltaic cell? b Which species is being reduced during the chemical reaction? c Which species is the oxidizing agent? d What happens to the concentration of Fe3+(aq) as the reaction proceeds? e How does the mass of Al(s) change as the reaction proceeds?arrow_forwardConsider the following galvanic cell: Calculate the concentrations of Ag+(aq) and Ni2+(aq) once the cell is dead.arrow_forwardFour metals, A, B, C, and D, exhibit the following properties: (a) Only A and C react with 1.0 M hydrochloric acid to give H2(g). (b) When C is added to solutions of the ions of the other metals, metallic B, D, and A are formed. (c) Metal D reduces Bn+ to give metallic B and Dn+. Based on this information, arrange the four metals in order of increasing ability to act as reducing agents.arrow_forward
- For the following half-reactions, answer these questions. Ce4+(aq)+eCe3+(aq)E=+1.61VAg+(aq)+eAg(s)E=+0.80VHg22+(aq)+2e2Hg(l)E=+0.80VSn2+(aq)+2eSn(s)E=0.14VNi2+(aq)+2eNi(s)E=0.24VAl3+(aq)+3eAl(s)E=1.68V (a) Which is the weakest oxidizing agent? (b) Which is the strongest oxidizing agent? (c) Which is the strongest reducing agent? (d) Which is the weakest reducing agent? (e) Will Sn(s) reduce Ag+(aq) to Ag(s)? (f) Will Hg(l) reduce Sn2+(aq) to Sn(s)? (g) Which ion(s) can be reduced by Sn(s)? (h) Which metal(s) can be oxidized by Ag+(aq)?arrow_forwardDescribe what you expect to happen when the following solutions are electrolyzed: a aqueous Na2SO4; b aqueous KBr. That is, what are the electrode reactions? What is the overall reaction?arrow_forward(a) Rank the following metals in their ability to function as reducing agents: Hg, Sn, and Pb. (b) Which halogens will oxidize mercury to mercury(II)?arrow_forward
- Answer the following questions using data from Table 17-1 (all under standard conditions). a. Is H+(aq) capable of oxidizing Cu(s) to Cu2+(aq)? b. Is Fe3+ (aq) capable of oxidizing I (aq)? c. Is H2(g) capable of reducing Ag+(aq)?arrow_forwardConsider only the species (at standard conditions) Na+, Cl, Ag+, Ag, Zn2+, Zn, Pb in answering the following questions. Give reasons for your answers. (Use data from Table 17-1.) a. Which is the strongest oxidizing agent? b. Which is the strongest reducing agent? c. Which species can be oxidized by SO42 (aq) in acid? d. Which species can be reduced by Al(s)?arrow_forwardUse Table 17.1 to arrange the following oxidizing agents in order of increasing strength: Mn2+ S Co3+ Cl2 K+arrow_forward
- A solution contains the ions H+, Ag+, Pb2+, and Ba2+, each at a concentration of 1.0 M. (a) Which of these ions would be reduced first at the cathode during an electrolysis? (b) After the first ion has been completely removed by electrolysis, which is the second ion to be reduced? (c) Which, if any, of these ions cannot be reduced by the electrolysis of the aqueous solution?arrow_forwardAn electrolytic cell is set up with Cd(s) in Cd(NO3)2(aq) and Zn(s) in Zn(NO3)2(aq). Initially both electrodesweigh 5.00 g. After running the cell for several hours theelectrode in the left compartment weighs 4.75 g. (a) Which electrode is in the left compartment? (b) Does the mass of the electrode in the right compartmentincrease, decrease, or stay the same? If the masschanges, what is the new mass? (c) Does the volume of the electrode in the right compartment increase, decrease, or stay the same? If the volumechanges, what is the new volume? (The density of Cd is8.65 g/cm3.)arrow_forwardAs the voltaic cell shown here runs, the blue solution gradually gets lighter in color and the gray solution gets darker. (a) What species is oxidized and what is reduced? (b) Which electrode is the anode and which is the cathode? (C) Which metal electrode gains mass? (d) In which direction do electrons flow through the external circuit?arrow_forward
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