(a) Interpretation: Interpret the following statement is true or false. ‘Boiling point of alkane increases with number of carbon’. Concept Introduction: Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C n H 2 n + 2 where, n is number of carbon atom. Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane. Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Question

Want to see more full solutions like this?

Answer 1

Question

Chapter 11, Problem 31P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘Boiling point of alkane increases with number of carbon’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point.

Conclusion

Hence, boiling point of alkane increases with number of carbon.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘Alkane having more density than water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Majorly alkane mostly having density lower than water or less than 1 g /cc. Thus, alkane having less density than water.

Conclusion

Hence, alkane having less density than water.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘Cis and trans isomer have same physical properties with same molecular formula’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Cis and trans isomer belongs to same molecular formula but having different physical properties such as different color or different odor.

Conclusion

Hence, Cis and trans isomer having different physical properties.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘Least branched isomer has lowest boiling point’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

More branched isomer having lowest boiling point due to the decrease in surface area and thus less bonding between the molecules appear which result in decrease in boiling point.

Conclusion

Hence, least branched isomer has lowest boiling point.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes and cycloalkane are not soluble in water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Alkane and cycloalkane are non polar in nature and thus not be able to create hydrogen bonds water which results in insolubility in water.

Conclusion

Hence, Alkane and cycloalkane having insolubility in water.

Interpretation Introduction

(f)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes are soluble in each other’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Liquid alkane are soluble in each other and in other organic solvent due to similar nature.

Conclusion

Hence, liquid alkane are soluble in each other.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Students have asked these similar questions

Indicate whether each statement is true or false. Alkanes do not have any carbon-carbon multiple bonds. Cyclobutane contains a four-membered ring. Alkenes contain carbon-carbon triple bonds. Alkynes contain carbon-carbon double bonds. Pentene is a saturated hydrocarbon. 1-pentene is an unsaturated hydrocarbon. Cyclohexane is an aromatic hydrocarbon. The methyl group contains one less hydrogen atom than methane.

Alkanes are hydrocarbons containing only single bonds. Acyclic alkanes have carbon atoms arranged in chains, whereas cycloalkanes have carbon atoms arranged in one or more rings. How many hydrogen atoms are in an acyclic alkane with 6 carbon atoms?

What is cis-trans isomerism in alkenes? cis-trans isomerism in alkenes involves having the major groups in an alkene on the same or opposite side of the double bond cis-trans isomerism in alkenes involves having different or identical substituents at the both ends of the double bond cis-trans isomerism in alkenes involves having the major groups in an alkene in staggered or eclipsed conformations cis-trans isomerism in alkenes involves different location of double bond along the carbon chain

Answer 2

Question

Chapter 11, Problem 31P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘Boiling point of alkane increases with number of carbon’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point.

Conclusion

Hence, boiling point of alkane increases with number of carbon.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘Alkane having more density than water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Majorly alkane mostly having density lower than water or less than 1 g /cc. Thus, alkane having less density than water.

Conclusion

Hence, alkane having less density than water.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘Cis and trans isomer have same physical properties with same molecular formula’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Cis and trans isomer belongs to same molecular formula but having different physical properties such as different color or different odor.

Conclusion

Hence, Cis and trans isomer having different physical properties.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘Least branched isomer has lowest boiling point’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

More branched isomer having lowest boiling point due to the decrease in surface area and thus less bonding between the molecules appear which result in decrease in boiling point.

Conclusion

Hence, least branched isomer has lowest boiling point.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes and cycloalkane are not soluble in water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Alkane and cycloalkane are non polar in nature and thus not be able to create hydrogen bonds water which results in insolubility in water.

Conclusion

Hence, Alkane and cycloalkane having insolubility in water.

Interpretation Introduction

(f)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes are soluble in each other’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Liquid alkane are soluble in each other and in other organic solvent due to similar nature.

Conclusion

Hence, liquid alkane are soluble in each other.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 3

Question

Chapter 11, Problem 31P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘Boiling point of alkane increases with number of carbon’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point.

Conclusion

Hence, boiling point of alkane increases with number of carbon.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘Alkane having more density than water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Majorly alkane mostly having density lower than water or less than 1 g /cc. Thus, alkane having less density than water.

Conclusion

Hence, alkane having less density than water.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘Cis and trans isomer have same physical properties with same molecular formula’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Cis and trans isomer belongs to same molecular formula but having different physical properties such as different color or different odor.

Conclusion

Hence, Cis and trans isomer having different physical properties.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘Least branched isomer has lowest boiling point’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

More branched isomer having lowest boiling point due to the decrease in surface area and thus less bonding between the molecules appear which result in decrease in boiling point.

Conclusion

Hence, least branched isomer has lowest boiling point.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes and cycloalkane are not soluble in water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Alkane and cycloalkane are non polar in nature and thus not be able to create hydrogen bonds water which results in insolubility in water.

Conclusion

Hence, Alkane and cycloalkane having insolubility in water.

Interpretation Introduction

(f)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes are soluble in each other’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Liquid alkane are soluble in each other and in other organic solvent due to similar nature.

Conclusion

Hence, liquid alkane are soluble in each other.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Chapter 11, Problem 31P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘Boiling point of alkane increases with number of carbon’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point.

Conclusion

Hence, boiling point of alkane increases with number of carbon.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘Alkane having more density than water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Majorly alkane mostly having density lower than water or less than 1 g /cc. Thus, alkane having less density than water.

Conclusion

Hence, alkane having less density than water.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘Cis and trans isomer have same physical properties with same molecular formula’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Cis and trans isomer belongs to same molecular formula but having different physical properties such as different color or different odor.

Conclusion

Hence, Cis and trans isomer having different physical properties.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘Least branched isomer has lowest boiling point’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

More branched isomer having lowest boiling point due to the decrease in surface area and thus less bonding between the molecules appear which result in decrease in boiling point.

Conclusion

Hence, least branched isomer has lowest boiling point.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes and cycloalkane are not soluble in water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Alkane and cycloalkane are non polar in nature and thus not be able to create hydrogen bonds water which results in insolubility in water.

Conclusion

Hence, Alkane and cycloalkane having insolubility in water.

Interpretation Introduction

(f)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes are soluble in each other’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Liquid alkane are soluble in each other and in other organic solvent due to similar nature.

Conclusion

Hence, liquid alkane are soluble in each other.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 11, Problem 31P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘Boiling point of alkane increases with number of carbon’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point.

Conclusion

Hence, boiling point of alkane increases with number of carbon.

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘Alkane having more density than water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Majorly alkane mostly having density lower than water or less than 1 g /cc. Thus, alkane having less density than water.

Conclusion

Hence, alkane having less density than water.

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘Cis and trans isomer have same physical properties with same molecular formula’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Cis and trans isomer belongs to same molecular formula but having different physical properties such as different color or different odor.

Conclusion

Hence, Cis and trans isomer having different physical properties.

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘Least branched isomer has lowest boiling point’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

More branched isomer having lowest boiling point due to the decrease in surface area and thus less bonding between the molecules appear which result in decrease in boiling point.

Conclusion

Hence, least branched isomer has lowest boiling point.

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes and cycloalkane are not soluble in water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Alkane and cycloalkane are non polar in nature and thus not be able to create hydrogen bonds water which results in insolubility in water.

Conclusion

Hence, Alkane and cycloalkane having insolubility in water.

Interpretation Introduction

(f)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes are soluble in each other’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Liquid alkane are soluble in each other and in other organic solvent due to similar nature.

Conclusion

Hence, liquid alkane are soluble in each other.

Answer 6

Chapter 11, Problem 31P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘Boiling point of alkane increases with number of carbon’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point.

Conclusion

Hence, boiling point of alkane increases with number of carbon.

Answer 7

Chapter 11, Problem 31P

Interpretation Introduction

(a)

Interpretation:

Interpret the following statement is true or false.

‘Boiling point of alkane increases with number of carbon’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Answer 8

Expert Solution

Answer to Problem 31P

The given statement is true.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point.

Answer 13

Conclusion

Hence, boiling point of alkane increases with number of carbon.

Answer 14

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘Alkane having more density than water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Majorly alkane mostly having density lower than water or less than 1 g /cc. Thus, alkane having less density than water.

Conclusion

Hence, alkane having less density than water.

Answer 15

Interpretation Introduction

(b)

Interpretation:

Interpret the following statement is true or false.

‘Alkane having more density than water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Answer 16

Expert Solution

Answer to Problem 31P

The given statement is false.

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

Majorly alkane mostly having density lower than water or less than 1 g /cc. Thus, alkane having less density than water.

Answer 21

Conclusion

Hence, alkane having less density than water.

Answer 22

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘Cis and trans isomer have same physical properties with same molecular formula’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is false.

Explanation of Solution

Cis and trans isomer belongs to same molecular formula but having different physical properties such as different color or different odor.

Conclusion

Hence, Cis and trans isomer having different physical properties.

Answer 23

Interpretation Introduction

(c)

Interpretation:

Interpret the following statement is true or false.

‘Cis and trans isomer have same physical properties with same molecular formula’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Answer 24

Expert Solution

Answer to Problem 31P

The given statement is false.

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

Cis and trans isomer belongs to same molecular formula but having different physical properties such as different color or different odor.

Answer 29

Conclusion

Hence, Cis and trans isomer having different physical properties.

Answer 30

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘Least branched isomer has lowest boiling point’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

More branched isomer having lowest boiling point due to the decrease in surface area and thus less bonding between the molecules appear which result in decrease in boiling point.

Conclusion

Hence, least branched isomer has lowest boiling point.

Answer 31

Interpretation Introduction

(d)

Interpretation:

Interpret the following statement is true or false.

‘Least branched isomer has lowest boiling point’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Answer 32

Expert Solution

Answer to Problem 31P

The given statement is true.

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

The compound containing longest parent chain of carbon having high boiling point due to the bulkiness of the structure while the compound containing shortest parent chain of carbon having low boiling point.

More branched isomer having lowest boiling point due to the decrease in surface area and thus less bonding between the molecules appear which result in decrease in boiling point.

Answer 37

Conclusion

Hence, least branched isomer has lowest boiling point.

Answer 38

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes and cycloalkane are not soluble in water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Alkane and cycloalkane are non polar in nature and thus not be able to create hydrogen bonds water which results in insolubility in water.

Conclusion

Hence, Alkane and cycloalkane having insolubility in water.

Answer 39

Interpretation Introduction

(e)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes and cycloalkane are not soluble in water’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Answer 40

Expert Solution

Answer to Problem 31P

The given statement is true.

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

Alkane and cycloalkane are non polar in nature and thus not be able to create hydrogen bonds water which results in insolubility in water.

Answer 45

Conclusion

Hence, Alkane and cycloalkane having insolubility in water.

Answer 46

Interpretation Introduction

(f)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes are soluble in each other’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Expert Solution

Answer to Problem 31P

The given statement is true.

Explanation of Solution

Liquid alkane are soluble in each other and in other organic solvent due to similar nature.

Conclusion

Hence, liquid alkane are soluble in each other.

Answer 47

Interpretation Introduction

(f)

Interpretation:

Interpret the following statement is true or false.

‘Alkanes are soluble in each other’.

Concept Introduction:

Alkane is a long chain of carbon linked with only single bond between each carbon. Its general formula is C_n H₂_n₊₂ where, n is number of carbon atom.

Moreover, straight chain have large surface area which increases the possibility of area of contact with other chain which results in higher vander waal forces between them and thus increases the boiling point. Change in the position of substituent attached on alkane may result in either constitutional isomerism or geometrical isomerism if present below or above the plane.

Alkanes not having any charge separation due to the absence of atoms of different electronegativity and thus they are non polar.

Answer 48

Expert Solution

Answer to Problem 31P

The given statement is true.

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

Liquid alkane are soluble in each other and in other organic solvent due to similar nature.

Answer 53

Conclusion

Hence, liquid alkane are soluble in each other.

Answer 54

Ch. 11.2 - Prob. 11.1QC Ch. 11.3 - Prob. 11.2QC Ch. 11.3 - Prob. 11.3QC Ch. 11.4 - Problem 11-4 Write the molecular formula and IUPAC...Ch. 11.6 - Problem 11-5 Write the molecular formula and IUPAC...Ch. 11.7 - Prob. 11.6QC Ch. 11.8 - Prob. 11.7QC Ch. 11.9 - Prob. 11.8QC Ch. 11.10 - Prob. 11.9QC Ch. 11 - 11-11 Define: Hydrocarbon Alkane Saturated...

Concept explainers

Answer to Problem 31P

Explanation of Solution

Answer to Problem 31P

Explanation of Solution

Answer to Problem 31P

Explanation of Solution

Answer to Problem 31P

Explanation of Solution

Answer to Problem 31P

Explanation of Solution

Answer to Problem 31P

Explanation of Solution

Want to see more full solutions like this?

Chapter 11 Solutions