Using KF as an example, write equations that refer to ∆ H soln and ∆ H hyd · Lattice energy was defined in Chapter 3 as ∆ H for the reaction K + ( g ) + F − ( g ) → KF( s ). Show how you would utilize Hess’s law to calculate ∆ H so1n from ∆ H hyd and ∆ H LE for KF, where ∆ H LE = lattice energy. ∆ H soln for KF, as for other soluble ionic compounds, is a relatively small number. How can this be since ∆ H hyd and ∆ H LE are relatively large negative numbers?
Using KF as an example, write equations that refer to ∆ H soln and ∆ H hyd · Lattice energy was defined in Chapter 3 as ∆ H for the reaction K + ( g ) + F − ( g ) → KF( s ). Show how you would utilize Hess’s law to calculate ∆ H so1n from ∆ H hyd and ∆ H LE for KF, where ∆ H LE = lattice energy. ∆ H soln for KF, as for other soluble ionic compounds, is a relatively small number. How can this be since ∆ H hyd and ∆ H LE are relatively large negative numbers?
Solution Summary: The author explains how Hess's law calculates the enthalpy change for reactants to products, whether the process takes place in single or sequence of steps.
Using KF as an example, write equations that refer to ∆Hsoln and ∆Hhyd· Lattice energy was defined in Chapter 3 as ∆H for the reaction K+(g) + F− (g) → KF(s). Show how you would utilize Hess’s law to calculate ∆Hso1n from ∆Hhyd and ∆HLE for KF, where ∆HLE = lattice energy. ∆Hsoln for KF, as for other soluble ionic compounds, is a relatively small number. How can this be since ∆Hhyd and ∆HLE are relatively large negative numbers?
6. Match each of the lettered items in the column on
the left with the most appropriate numbered
item(s) in the column on the right. Some of the
numbered items may be used more than once
and some not at all.
a.
Z = 37
1.
b.
Mn
2.
C.
Pr
element in period 5 and group
14
element in period 5 and group
15
d. S
e. [Rn] 7s¹
f.
d block
metal
3. highest metallic character of all
the elements
4. paramagnetic with 5 unpaired
electrons
5. 4f36s2
6. isoelectronic with Ca²+ cation
7.
an alkaline metal
8. an f-block element
Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.
Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
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