ATKINS' PHYSICAL CHEMISTRY
11th Edition
ISBN: 9780190053956
Author: ATKINS
Publisher: Oxford University Press
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Question
Chapter 11, Problem 11G.2DQ
(a)
Interpretation Introduction
Interpretation:
The evidence for the usual explanation of the mechanism of fluorescence has to be stated.
Concept introduction:
Electronic spectra are formed by the excitation and relaxation process of electrons. The excitation process is due to the transition of an electron from a lower energy level to a higher energy level. The relaxation process is due to the transition of an electron from a higher energy level to lower energy level.
(b)
Interpretation Introduction
Interpretation:
The evidence for the usual explanation of the mechanism of phosphorescence has to be stated.
Concept introduction:
As mentioned in the concept introduction in part (a).
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
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55.0
57.0
100
57.5
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58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
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20
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160
180
200 220
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99.5
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115.0
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77404799
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117.0
12.9
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33.5
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133 0
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157.0
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169.0
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170.0
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171.0
21.6
172.0
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1.3
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784
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2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
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4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 11 Solutions
ATKINS' PHYSICAL CHEMISTRY
Ch. 11 - Prob. 11A.1STCh. 11 - Prob. 11A.2STCh. 11 - Prob. 11B.1STCh. 11 - Prob. 11B.2STCh. 11 - Prob. 11B.3STCh. 11 - Prob. 11B.4STCh. 11 - Prob. 11C.1STCh. 11 - Prob. 11C.2STCh. 11 - Prob. 11D.1STCh. 11 - Prob. 11E.1ST
Ch. 11 - Prob. 11E.2STCh. 11 - Prob. 11F.2STCh. 11 - Prob. 11A.1DQCh. 11 - Prob. 11A.2DQCh. 11 - Prob. 11A.3DQCh. 11 - Prob. 11A.1AECh. 11 - Prob. 11A.1BECh. 11 - Prob. 11A.2AECh. 11 - Prob. 11A.2BECh. 11 - Prob. 11A.3AECh. 11 - Prob. 11A.3BECh. 11 - Prob. 11A.4AECh. 11 - Prob. 11A.4BECh. 11 - Prob. 11A.5AECh. 11 - Prob. 11A.5BECh. 11 - Prob. 11A.6AECh. 11 - Prob. 11A.6BECh. 11 - Prob. 11A.7AECh. 11 - Prob. 11A.7BECh. 11 - Prob. 11A.8AECh. 11 - Prob. 11A.8BECh. 11 - Prob. 11A.9AECh. 11 - Prob. 11A.9BECh. 11 - Prob. 11A.10AECh. 11 - Prob. 11A.10BECh. 11 - Prob. 11A.11AECh. 11 - Prob. 11A.11BECh. 11 - Prob. 11A.12AECh. 11 - Prob. 11A.12BECh. 11 - Prob. 11A.1PCh. 11 - Prob. 11A.2PCh. 11 - Prob. 11A.3PCh. 11 - Prob. 11A.4PCh. 11 - Prob. 11A.5PCh. 11 - Prob. 11A.7PCh. 11 - Prob. 11A.8PCh. 11 - Prob. 11A.9PCh. 11 - Prob. 11A.11PCh. 11 - Prob. 11B.1DQCh. 11 - Prob. 11B.2DQCh. 11 - Prob. 11B.3DQCh. 11 - Prob. 11B.4DQCh. 11 - Prob. 11B.5DQCh. 11 - Prob. 11B.6DQCh. 11 - Prob. 11B.7DQCh. 11 - Prob. 11B.8DQCh. 11 - Prob. 11B.1AECh. 11 - Prob. 11B.1BECh. 11 - Prob. 11B.3AECh. 11 - Prob. 11B.3BECh. 11 - Prob. 11B.4BECh. 11 - Prob. 11B.5AECh. 11 - Prob. 11B.5BECh. 11 - Prob. 11B.6AECh. 11 - Prob. 11B.6BECh. 11 - Prob. 11B.7AECh. 11 - Prob. 11B.7BECh. 11 - Prob. 11B.8AECh. 11 - Prob. 11B.8BECh. 11 - Prob. 11B.9AECh. 11 - Prob. 11B.9BECh. 11 - Prob. 11B.10AECh. 11 - Prob. 11B.10BECh. 11 - Prob. 11B.11AECh. 11 - Prob. 11B.11BECh. 11 - Prob. 11B.12AECh. 11 - Prob. 11B.12BECh. 11 - Prob. 11B.13AECh. 11 - Prob. 11B.13BECh. 11 - Prob. 11B.14AECh. 11 - Prob. 11B.14BECh. 11 - Prob. 11B.1PCh. 11 - Prob. 11B.2PCh. 11 - Prob. 11B.3PCh. 11 - Prob. 11B.4PCh. 11 - Prob. 11B.5PCh. 11 - Prob. 11B.6PCh. 11 - Prob. 11B.7PCh. 11 - Prob. 11B.8PCh. 11 - Prob. 11B.9PCh. 11 - Prob. 11B.10PCh. 11 - Prob. 11B.11PCh. 11 - Prob. 11B.12PCh. 11 - Prob. 11B.13PCh. 11 - Prob. 11B.14PCh. 11 - Prob. 11C.1DQCh. 11 - Prob. 11C.2DQCh. 11 - Prob. 11C.3DQCh. 11 - Prob. 11C.4DQCh. 11 - Prob. 11C.1AECh. 11 - Prob. 11C.1BECh. 11 - Prob. 11C.2AECh. 11 - Prob. 11C.2BECh. 11 - Prob. 11C.3AECh. 11 - Prob. 11C.3BECh. 11 - Prob. 11C.4AECh. 11 - Prob. 11C.4BECh. 11 - Prob. 11C.5AECh. 11 - Prob. 11C.5BECh. 11 - Prob. 11C.6AECh. 11 - Prob. 11C.6BECh. 11 - Prob. 11C.7AECh. 11 - Prob. 11C.7BECh. 11 - Prob. 11C.8AECh. 11 - Prob. 11C.8BECh. 11 - Prob. 11C.2PCh. 11 - Prob. 11C.3PCh. 11 - Prob. 11C.4PCh. 11 - Prob. 11C.5PCh. 11 - Prob. 11C.6PCh. 11 - Prob. 11C.7PCh. 11 - Prob. 11C.8PCh. 11 - Prob. 11C.9PCh. 11 - Prob. 11C.10PCh. 11 - Prob. 11C.11PCh. 11 - Prob. 11C.12PCh. 11 - Prob. 11C.13PCh. 11 - Prob. 11C.15PCh. 11 - Prob. 11C.17PCh. 11 - Prob. 11C.18PCh. 11 - Prob. 11C.19PCh. 11 - Prob. 11D.1DQCh. 11 - Prob. 11D.2DQCh. 11 - Prob. 11D.3DQCh. 11 - Prob. 11D.1AECh. 11 - Prob. 11D.1BECh. 11 - Prob. 11D.2AECh. 11 - Prob. 11D.2BECh. 11 - Prob. 11D.3AECh. 11 - Prob. 11D.3BECh. 11 - Prob. 11D.4AECh. 11 - Prob. 11D.4BECh. 11 - Prob. 11D.5AECh. 11 - Prob. 11D.5BECh. 11 - Prob. 11D.6AECh. 11 - Prob. 11D.6BECh. 11 - Prob. 11D.7AECh. 11 - Prob. 11D.7BECh. 11 - Prob. 11D.2PCh. 11 - Prob. 11E.1DQCh. 11 - Prob. 11E.1AECh. 11 - Prob. 11E.1BECh. 11 - Prob. 11E.2AECh. 11 - Prob. 11E.2BECh. 11 - Prob. 11E.3AECh. 11 - Prob. 11E.3BECh. 11 - Prob. 11E.1PCh. 11 - Prob. 11E.2PCh. 11 - Prob. 11F.1DQCh. 11 - Prob. 11F.2DQCh. 11 - Prob. 11F.3DQCh. 11 - Prob. 11F.4DQCh. 11 - Prob. 11F.5DQCh. 11 - Prob. 11F.6DQCh. 11 - Prob. 11F.1AECh. 11 - Prob. 11F.1BECh. 11 - Prob. 11F.2AECh. 11 - Prob. 11F.2BECh. 11 - Prob. 11F.3AECh. 11 - Prob. 11F.3BECh. 11 - Prob. 11F.4AECh. 11 - Prob. 11F.4BECh. 11 - Prob. 11F.5AECh. 11 - Prob. 11F.5BECh. 11 - Prob. 11F.6AECh. 11 - Prob. 11F.6BECh. 11 - Prob. 11F.7AECh. 11 - Prob. 11F.7BECh. 11 - Prob. 11F.8AECh. 11 - Prob. 11F.8BECh. 11 - Prob. 11F.9AECh. 11 - Prob. 11F.9BECh. 11 - Prob. 11F.10AECh. 11 - Prob. 11F.10BECh. 11 - Prob. 11F.11AECh. 11 - Prob. 11F.11BECh. 11 - Prob. 11F.12AECh. 11 - Prob. 11F.12BECh. 11 - Prob. 11F.13AECh. 11 - Prob. 11F.13BECh. 11 - Prob. 11F.1PCh. 11 - Prob. 11F.2PCh. 11 - Prob. 11F.3PCh. 11 - Prob. 11F.4PCh. 11 - Prob. 11F.5PCh. 11 - Prob. 11F.6PCh. 11 - Prob. 11F.7PCh. 11 - Prob. 11F.8PCh. 11 - Prob. 11F.9PCh. 11 - Prob. 11F.10PCh. 11 - Prob. 11F.11PCh. 11 - Prob. 11F.12PCh. 11 - Prob. 11G.1DQCh. 11 - Prob. 11G.2DQCh. 11 - Prob. 11G.3DQCh. 11 - Prob. 11G.4DQCh. 11 - Prob. 11G.5DQCh. 11 - Prob. 11G.1AECh. 11 - Prob. 11G.1BECh. 11 - Prob. 11G.2AECh. 11 - Prob. 11G.2BECh. 11 - Prob. 11G.1PCh. 11 - Prob. 11G.2PCh. 11 - Prob. 11G.3PCh. 11 - Prob. 11G.4PCh. 11 - Prob. 11G.5PCh. 11 - Prob. 11G.6PCh. 11 - Prob. 11.1IACh. 11 - Prob. 11.5IACh. 11 - Prob. 11.8IA
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