ATKINS' PHYSICAL CHEMISTRY
11th Edition
ISBN: 9780190053956
Author: ATKINS
Publisher: Oxford University Press
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Question
Chapter 11, Problem 11B.5DQ
Interpretation Introduction
Interpretation:
The physical origins of gross selection rule for the Raman spectroscopy have to be stated.
Concept introduction:
Raman scattering is a result of rotational transitions. The selection rule for rotational Raman spectrum is that it should be polarizable. The molecules must acquire an induced dipole moment even if it has a permanent dipole moment.
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Directions: Given the following reaction and the stress applied in each
reaction, answer the question below.
A. H2(g) + Cl2(g) 2 HCl(g)
Stress applied: Decreasing the pressure
1. What is the Keq expression?
2. What will be the effect in the number of moles of HCl(g)?
3. What will be the Equilibrium Shift or the reaction?
B.
Fe3O4(s) + 4 H2(g) + heat 53 Fe(s) + 4 H₂O(g)
Stress applied: Increasing the temperature
1. What is the Keq expression?.
2. What will be the effect in the volume of water vapor collected?
3. What will be the Equilibrium Shift or the reaction?
C. 4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g) + heat
Stress applied: Increasing the volume of the container
1. What is the Keq expression?.
2. What will be the effect in the amount of H₂O?
3. What will be the Equilibrium Shift or the reaction?
Chapter 11 Solutions
ATKINS' PHYSICAL CHEMISTRY
Ch. 11 - Prob. 11A.1STCh. 11 - Prob. 11A.2STCh. 11 - Prob. 11B.1STCh. 11 - Prob. 11B.2STCh. 11 - Prob. 11B.3STCh. 11 - Prob. 11B.4STCh. 11 - Prob. 11C.1STCh. 11 - Prob. 11C.2STCh. 11 - Prob. 11D.1STCh. 11 - Prob. 11E.1ST
Ch. 11 - Prob. 11E.2STCh. 11 - Prob. 11F.2STCh. 11 - Prob. 11A.1DQCh. 11 - Prob. 11A.2DQCh. 11 - Prob. 11A.3DQCh. 11 - Prob. 11A.1AECh. 11 - Prob. 11A.1BECh. 11 - Prob. 11A.2AECh. 11 - Prob. 11A.2BECh. 11 - Prob. 11A.3AECh. 11 - Prob. 11A.3BECh. 11 - Prob. 11A.4AECh. 11 - Prob. 11A.4BECh. 11 - Prob. 11A.5AECh. 11 - Prob. 11A.5BECh. 11 - Prob. 11A.6AECh. 11 - Prob. 11A.6BECh. 11 - Prob. 11A.7AECh. 11 - Prob. 11A.7BECh. 11 - Prob. 11A.8AECh. 11 - Prob. 11A.8BECh. 11 - Prob. 11A.9AECh. 11 - Prob. 11A.9BECh. 11 - Prob. 11A.10AECh. 11 - Prob. 11A.10BECh. 11 - Prob. 11A.11AECh. 11 - Prob. 11A.11BECh. 11 - Prob. 11A.12AECh. 11 - Prob. 11A.12BECh. 11 - Prob. 11A.1PCh. 11 - Prob. 11A.2PCh. 11 - Prob. 11A.3PCh. 11 - Prob. 11A.4PCh. 11 - Prob. 11A.5PCh. 11 - Prob. 11A.7PCh. 11 - Prob. 11A.8PCh. 11 - Prob. 11A.9PCh. 11 - Prob. 11A.11PCh. 11 - Prob. 11B.1DQCh. 11 - Prob. 11B.2DQCh. 11 - Prob. 11B.3DQCh. 11 - Prob. 11B.4DQCh. 11 - Prob. 11B.5DQCh. 11 - Prob. 11B.6DQCh. 11 - Prob. 11B.7DQCh. 11 - Prob. 11B.8DQCh. 11 - Prob. 11B.1AECh. 11 - Prob. 11B.1BECh. 11 - Prob. 11B.3AECh. 11 - Prob. 11B.3BECh. 11 - Prob. 11B.4BECh. 11 - Prob. 11B.5AECh. 11 - Prob. 11B.5BECh. 11 - Prob. 11B.6AECh. 11 - Prob. 11B.6BECh. 11 - Prob. 11B.7AECh. 11 - Prob. 11B.7BECh. 11 - Prob. 11B.8AECh. 11 - Prob. 11B.8BECh. 11 - Prob. 11B.9AECh. 11 - Prob. 11B.9BECh. 11 - Prob. 11B.10AECh. 11 - Prob. 11B.10BECh. 11 - Prob. 11B.11AECh. 11 - Prob. 11B.11BECh. 11 - Prob. 11B.12AECh. 11 - Prob. 11B.12BECh. 11 - Prob. 11B.13AECh. 11 - Prob. 11B.13BECh. 11 - Prob. 11B.14AECh. 11 - Prob. 11B.14BECh. 11 - Prob. 11B.1PCh. 11 - Prob. 11B.2PCh. 11 - Prob. 11B.3PCh. 11 - Prob. 11B.4PCh. 11 - Prob. 11B.5PCh. 11 - Prob. 11B.6PCh. 11 - Prob. 11B.7PCh. 11 - Prob. 11B.8PCh. 11 - Prob. 11B.9PCh. 11 - Prob. 11B.10PCh. 11 - Prob. 11B.11PCh. 11 - Prob. 11B.12PCh. 11 - Prob. 11B.13PCh. 11 - Prob. 11B.14PCh. 11 - Prob. 11C.1DQCh. 11 - Prob. 11C.2DQCh. 11 - Prob. 11C.3DQCh. 11 - Prob. 11C.4DQCh. 11 - Prob. 11C.1AECh. 11 - Prob. 11C.1BECh. 11 - Prob. 11C.2AECh. 11 - Prob. 11C.2BECh. 11 - Prob. 11C.3AECh. 11 - Prob. 11C.3BECh. 11 - Prob. 11C.4AECh. 11 - Prob. 11C.4BECh. 11 - Prob. 11C.5AECh. 11 - Prob. 11C.5BECh. 11 - Prob. 11C.6AECh. 11 - Prob. 11C.6BECh. 11 - Prob. 11C.7AECh. 11 - Prob. 11C.7BECh. 11 - Prob. 11C.8AECh. 11 - Prob. 11C.8BECh. 11 - Prob. 11C.2PCh. 11 - Prob. 11C.3PCh. 11 - Prob. 11C.4PCh. 11 - Prob. 11C.5PCh. 11 - Prob. 11C.6PCh. 11 - Prob. 11C.7PCh. 11 - Prob. 11C.8PCh. 11 - Prob. 11C.9PCh. 11 - Prob. 11C.10PCh. 11 - Prob. 11C.11PCh. 11 - Prob. 11C.12PCh. 11 - Prob. 11C.13PCh. 11 - Prob. 11C.15PCh. 11 - Prob. 11C.17PCh. 11 - Prob. 11C.18PCh. 11 - Prob. 11C.19PCh. 11 - Prob. 11D.1DQCh. 11 - Prob. 11D.2DQCh. 11 - Prob. 11D.3DQCh. 11 - Prob. 11D.1AECh. 11 - Prob. 11D.1BECh. 11 - Prob. 11D.2AECh. 11 - Prob. 11D.2BECh. 11 - Prob. 11D.3AECh. 11 - Prob. 11D.3BECh. 11 - Prob. 11D.4AECh. 11 - Prob. 11D.4BECh. 11 - Prob. 11D.5AECh. 11 - Prob. 11D.5BECh. 11 - Prob. 11D.6AECh. 11 - Prob. 11D.6BECh. 11 - Prob. 11D.7AECh. 11 - Prob. 11D.7BECh. 11 - Prob. 11D.2PCh. 11 - Prob. 11E.1DQCh. 11 - Prob. 11E.1AECh. 11 - Prob. 11E.1BECh. 11 - Prob. 11E.2AECh. 11 - Prob. 11E.2BECh. 11 - Prob. 11E.3AECh. 11 - Prob. 11E.3BECh. 11 - Prob. 11E.1PCh. 11 - Prob. 11E.2PCh. 11 - Prob. 11F.1DQCh. 11 - Prob. 11F.2DQCh. 11 - Prob. 11F.3DQCh. 11 - Prob. 11F.4DQCh. 11 - Prob. 11F.5DQCh. 11 - Prob. 11F.6DQCh. 11 - Prob. 11F.1AECh. 11 - Prob. 11F.1BECh. 11 - Prob. 11F.2AECh. 11 - Prob. 11F.2BECh. 11 - Prob. 11F.3AECh. 11 - Prob. 11F.3BECh. 11 - Prob. 11F.4AECh. 11 - Prob. 11F.4BECh. 11 - Prob. 11F.5AECh. 11 - Prob. 11F.5BECh. 11 - Prob. 11F.6AECh. 11 - Prob. 11F.6BECh. 11 - Prob. 11F.7AECh. 11 - Prob. 11F.7BECh. 11 - Prob. 11F.8AECh. 11 - Prob. 11F.8BECh. 11 - Prob. 11F.9AECh. 11 - Prob. 11F.9BECh. 11 - Prob. 11F.10AECh. 11 - Prob. 11F.10BECh. 11 - Prob. 11F.11AECh. 11 - Prob. 11F.11BECh. 11 - Prob. 11F.12AECh. 11 - Prob. 11F.12BECh. 11 - Prob. 11F.13AECh. 11 - Prob. 11F.13BECh. 11 - Prob. 11F.1PCh. 11 - Prob. 11F.2PCh. 11 - Prob. 11F.3PCh. 11 - Prob. 11F.4PCh. 11 - Prob. 11F.5PCh. 11 - Prob. 11F.6PCh. 11 - Prob. 11F.7PCh. 11 - Prob. 11F.8PCh. 11 - Prob. 11F.9PCh. 11 - Prob. 11F.10PCh. 11 - Prob. 11F.11PCh. 11 - Prob. 11F.12PCh. 11 - Prob. 11G.1DQCh. 11 - Prob. 11G.2DQCh. 11 - Prob. 11G.3DQCh. 11 - Prob. 11G.4DQCh. 11 - Prob. 11G.5DQCh. 11 - Prob. 11G.1AECh. 11 - Prob. 11G.1BECh. 11 - Prob. 11G.2AECh. 11 - Prob. 11G.2BECh. 11 - Prob. 11G.1PCh. 11 - Prob. 11G.2PCh. 11 - Prob. 11G.3PCh. 11 - Prob. 11G.4PCh. 11 - Prob. 11G.5PCh. 11 - Prob. 11G.6PCh. 11 - Prob. 11.1IACh. 11 - Prob. 11.5IACh. 11 - Prob. 11.8IA
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