The formula of product obtained by reducing 2-butanone to 2-butanol has to be written and its chirality has to be predicted. Concept introduction: Chirality: The presence of four different atoms (or groups) at carbon is known as asymmetric carbon and is known as chiral center of the compound. Lithium aluminum hydride: Used as strong reducing agent, hydride (weaker Al-H bond) act as strong nucleophile that attack the electrophilic carbon of carbonyl group forming metal alkoxide intermediate complex; acid workup is the final step involving protonation of alkoxide oxygen results the alcohol as aproduct.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 11, Problem 11.75SP

(a)

Interpretation Introduction

Interpretation:

The formula of product obtained by reducing 2-butanone to 2-butanol has to be written and its chirality has to be predicted.

Concept introduction:

Chirality: The presence of four different atoms (or groups) at carbon is known as asymmetric carbon and is known as chiral center of the compound.

Lithium aluminum hydride: Used as strong reducing agent, hydride (weaker Al-H bond) act as strong nucleophile that attack the electrophilic carbon of carbonyl group forming metal alkoxide intermediate complex; acid workup is the final step involving protonation of alkoxide oxygen results the alcohol as aproduct.

(b)

Interpretation Introduction

Interpretation:

The product does not exhibit optical activity; the reason has to be explained.

Concept introduction:

Chirality: The presence of four different atoms (or groups) at carbon is known as asymmetric carbon and is known as chiral center of the compound.

Optical activity: The ability of a chiral molecule to rotate the plane of plane-polarized light, using polarimeter.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Q5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R H

Calculate the proton and carbon chemical shifts for this structure

A. B. b. Now consider the two bicyclic molecules A. and B. Note that A. is a dianion and B. is a neutral molecule. One of these molecules is a highly reactive compound first characterized in frozen noble gas matrices, that self-reacts rapidly at temperatures above liquid nitrogen temperature. The other compound was isolated at room temperature in the early 1960s, and is a stable ligand used in organometallic chemistry. Which molecule is the more stable molecule, and why?

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 11, Problem 11.75SP

(a)

Interpretation Introduction

Interpretation:

The formula of product obtained by reducing 2-butanone to 2-butanol has to be written and its chirality has to be predicted.

Concept introduction:

Chirality: The presence of four different atoms (or groups) at carbon is known as asymmetric carbon and is known as chiral center of the compound.

Lithium aluminum hydride: Used as strong reducing agent, hydride (weaker Al-H bond) act as strong nucleophile that attack the electrophilic carbon of carbonyl group forming metal alkoxide intermediate complex; acid workup is the final step involving protonation of alkoxide oxygen results the alcohol as aproduct.

(b)

Interpretation Introduction

Interpretation:

The product does not exhibit optical activity; the reason has to be explained.

Concept introduction:

Chirality: The presence of four different atoms (or groups) at carbon is known as asymmetric carbon and is known as chiral center of the compound.

Optical activity: The ability of a chiral molecule to rotate the plane of plane-polarized light, using polarimeter.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 11, Problem 11.75SP

(a)

Interpretation Introduction

Interpretation:

The formula of product obtained by reducing 2-butanone to 2-butanol has to be written and its chirality has to be predicted.

Concept introduction:

Chirality: The presence of four different atoms (or groups) at carbon is known as asymmetric carbon and is known as chiral center of the compound.

Lithium aluminum hydride: Used as strong reducing agent, hydride (weaker Al-H bond) act as strong nucleophile that attack the electrophilic carbon of carbonyl group forming metal alkoxide intermediate complex; acid workup is the final step involving protonation of alkoxide oxygen results the alcohol as aproduct.

(b)

Interpretation Introduction

Interpretation:

The product does not exhibit optical activity; the reason has to be explained.

Concept introduction:

Chirality: The presence of four different atoms (or groups) at carbon is known as asymmetric carbon and is known as chiral center of the compound.

Optical activity: The ability of a chiral molecule to rotate the plane of plane-polarized light, using polarimeter.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 11, Problem 11.75SP

(a)

Interpretation Introduction