Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Chapter 11, Problem 11.35QA
Interpretation Introduction
To explain:
Why theoretical and experimental van’t Hoff factors of electrolytes are different sometimes.
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2. Histamine (below structure) is a signal molecule involved in immune response and is
a neurotransmitter. Histamine features imidazole ring which is an aromatic heterocycle.
Please answer the following questions regarding Histamine.
b
a
HN
=N
C
NH2
a. Determine hybridization of each N atom (s, p, sp, sp², sp³, etc.) in histamine
N-a hybridization:
N-b hybridization:
N-c hybridization:
b. Determine what atomic orbitals (s, p, sp, sp², sp³, etc.) of the lone pair of each N
atom resided in
N-a hybridization:
N-b hybridization:
N-c hybridization:
None
29. Use frontier orbital analysis (HOMO-LUMO interactions) to decide whether the following
dimerization is 1) thermally allowed or forbidden and 2) photochemically allowed or
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+
Chapter 11 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 11 - Prob. 11.1VPCh. 11 - Prob. 11.2VPCh. 11 - Prob. 11.3VPCh. 11 - Prob. 11.4VPCh. 11 - Prob. 11.6VPCh. 11 - Prob. 11.7VPCh. 11 - Prob. 11.8VPCh. 11 - Prob. 11.9VPCh. 11 - Prob. 11.10VPCh. 11 - Prob. 11.11QA
Ch. 11 - Prob. 11.12QACh. 11 - Prob. 11.13QACh. 11 - Prob. 11.14QACh. 11 - Prob. 11.15QACh. 11 - Prob. 11.16QACh. 11 - Prob. 11.17QACh. 11 - Prob. 11.18QACh. 11 - Prob. 11.19QACh. 11 - Prob. 11.20QACh. 11 - Prob. 11.21QACh. 11 - Prob. 11.22QACh. 11 - Prob. 11.23QACh. 11 - Prob. 11.24QACh. 11 - Prob. 11.25QACh. 11 - Prob. 11.26QACh. 11 - Prob. 11.27QACh. 11 - Prob. 11.28QACh. 11 - Prob. 11.29QACh. 11 - Prob. 11.30QACh. 11 - Prob. 11.31QACh. 11 - Prob. 11.32QACh. 11 - Prob. 11.33QACh. 11 - Prob. 11.34QACh. 11 - Prob. 11.35QACh. 11 - Prob. 11.36QACh. 11 - Prob. 11.37QACh. 11 - Prob. 11.38QACh. 11 - Prob. 11.39QACh. 11 - Prob. 11.40QACh. 11 - Prob. 11.41QACh. 11 - Prob. 11.42QACh. 11 - Prob. 11.43QACh. 11 - Prob. 11.44QACh. 11 - Prob. 11.45QACh. 11 - Prob. 11.46QACh. 11 - Prob. 11.47QACh. 11 - Prob. 11.48QACh. 11 - Prob. 11.49QACh. 11 - Prob. 11.50QACh. 11 - Prob. 11.51QACh. 11 - Prob. 11.52QACh. 11 - Prob. 11.53QACh. 11 - Prob. 11.54QACh. 11 - Prob. 11.55QACh. 11 - Prob. 11.56QACh. 11 - Prob. 11.57QACh. 11 - Prob. 11.58QACh. 11 - Prob. 11.59QACh. 11 - Prob. 11.60QACh. 11 - Prob. 11.61QACh. 11 - Prob. 11.62QACh. 11 - Prob. 11.63QACh. 11 - Prob. 11.64QACh. 11 - Prob. 11.65QACh. 11 - Prob. 11.66QACh. 11 - Prob. 11.67QACh. 11 - Prob. 11.68QACh. 11 - Prob. 11.69QACh. 11 - Prob. 11.70QACh. 11 - Prob. 11.71QACh. 11 - Prob. 11.72QACh. 11 - Prob. 11.73QACh. 11 - Prob. 11.74QACh. 11 - Prob. 11.75QACh. 11 - Prob. 11.76QACh. 11 - Prob. 11.77QACh. 11 - Prob. 11.78QACh. 11 - Prob. 11.79QACh. 11 - Prob. 11.80QACh. 11 - Prob. 11.81QACh. 11 - Prob. 11.82QACh. 11 - Prob. 11.83QACh. 11 - Prob. 11.84QA
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