(a)
Interpretation:
For a binary system, the given equations are to be shown.
Concept Introduction:
For a binary system, equation
For a binary system, equation
(a)
Explanation of Solution
Given information:
Given equations to be shown are:
Here,
Rearrange and write the given equation as:
Now, take derivative of this equation with respect to
In terms of both
For excess property relation, equation (1) can be written as:
Substitute the values from equations (3) and (4) in the above equation and simplify as:
Similarly, for excess property relation, equation (2) can be written as:
Substitute the values from equations (3) and (4) in the above equation and simplify as:
Hence, the given equations are proved.
(b)
Interpretation:
The plot of
Concept Introduction:
For mixing process, equation for enthalpy is:
In terms of a third-degree polynomial equation in
Here,
(b)
Answer to Problem 11.33P
The plot of
From the plot of
Explanation of Solution
Given information:
The heat of mixing data for the
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Here,
From the equation (5), the given heat of mixing for the values of
Now, plot the graph of
Now, calculate the derivative of equation (7) as:
Now, calculate the value of
Now, plot the graph for
From the plot of
Want to see more full solutions like this?
Chapter 11 Solutions
Introduction to Chemical Engineering Thermodynamics
- Q2/ An adsorption study is set up in laboratory by adding a known amount of activated carbon to six which contain 200 mL of an industrial waste. An additional flask containing 200 mL of waste but no c is run as a blank. Plot the Langmuir isotherm and determine the values of the constants. Flask No. Mass of C (mg) Volume in Final COD Flask (mL) (mg C/L) 1 804 200 4.7 2 668 200 7.0 3 512 200 9.31 4 393 200 16.6 C 5 313 200 32.5 6 238 200 62.8 7 0 200 250arrow_forwardمشر on ۲/۱ Two rods (fins) having same dimensions, one made of brass(k=85 m K) and the other of copper (k = 375 W/m K), having one of their ends inserted into a furnace. At a section 10.5 cm a way from the furnace, the temperature brass rod 120°C. Find the distance at which the same temperature would be reached in the copper rod ? both ends are exposed to the same environment. 22.05 ofthearrow_forward4.59 Using the unilateral z-transform, solve the following difference equations with the given initial conditions. (a) y[n]-3y[n-1] = x[n], with x[n] = 4u[n], y[− 1] = 1 (b) y[n]-5y[n-1]+6y[n-2]= x[n], with x[n] = u[n], y[-1] = 3, y[-2]= 2 Ans. (a) y[n] = -2+9(3)", n ≥ -1 (b) y[n]=+8(2)" - (3)", n ≥ -2arrow_forward
- (30) 6. In a process design, the following process streams must be cooled or heated: Stream No mCp Temperature In Temperature Out °C °C kW/°C 1 5 350 270 2 9 270 120 3 3 100 320 4 5 120 288 Use the MUMNE algorithm for heat exchanger networks with a minimum approach temperature of 20°C. (5) a. Determine the temperature interval diagram. (3) (2) (10) (10) b. Determine the cascade diagram, the pinch temperatures, and the minimum hot and cold utilities. c. Determine the minimum number of heat exchangers above and below the pinch. d. Determine a valid heat exchange network above the pinch. e. Determine a valid heat exchange network below the pinch.arrow_forwardUse this equation to solve it.arrow_forwardQ1: Consider the following transfer function G(s) 5e-s 15s +1 1. What is the study state gain 2. What is the time constant 3. What is the value of the output at the end if the input is a unit step 4. What is the output value if the input is an impulse function with amplitude equals to 3, at t=7 5. When the output will be 3.5 if the input is a unit steparrow_forward
- Introduction to Chemical Engineering Thermodynami...Chemical EngineeringISBN:9781259696527Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark SwihartPublisher:McGraw-Hill EducationElementary Principles of Chemical Processes, Bind...Chemical EngineeringISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEYElements of Chemical Reaction Engineering (5th Ed...Chemical EngineeringISBN:9780133887518Author:H. Scott FoglerPublisher:Prentice Hall
- Industrial Plastics: Theory and ApplicationsChemical EngineeringISBN:9781285061238Author:Lokensgard, ErikPublisher:Delmar Cengage LearningUnit Operations of Chemical EngineeringChemical EngineeringISBN:9780072848236Author:Warren McCabe, Julian C. Smith, Peter HarriottPublisher:McGraw-Hill Companies, The