Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 11, Problem 11.25P
Interpretation Introduction

Interpretation:

To find the heat of mixing at 300 K in KJ/kg

Concept Introduction:

We find the Excess enthalpy of H2SO4of pure and 35-wt-% from the H-x diagram of H2SO4

Then we find the enthalpy of Pure water.

The heat of mixing is as given below,

  Q=H3x2H2x1H1

Where,

Mass fraction of H2O= x1

Mass fraction of H2SO4= x2

Enthalpy of Pure H2O = H1 Enthalpy of Pure H2SO4 (100-wt-%) = H2 Enthalpy of 35-wt-% aqueous solution of H2SO4 = H3

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