The molecule CH 4 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments. Concept introduction: The rigid rotators can be classified spherical, symmetric, linear, or asymmetric rotor depending on the moment of inertia. The spherical rotator has either O h or T d point group. The symmetric rotator has point group with atleast one threefold axis, whereas the asymmetric rotator does not has any point group with threefold axis or higher. The linear rotators are linear molecules.

Question

Want to see the full answer?

Answer 1

Question

Chapter 11, Problem 11.1IA

(a)

Interpretation Introduction

Interpretation:

The molecule CH4 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

The rigid rotators can be classified spherical, symmetric, linear, or asymmetric rotor depending on the moment of inertia. The spherical rotator has either Oh or Td point group. The symmetric rotator has point group with atleast one threefold axis, whereas the asymmetric rotator does not has any point group with threefold axis or higher. The linear rotators are linear molecules.

(b)

Interpretation Introduction

Interpretation:

The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(c)

Interpretation Introduction

Interpretation:

The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(d)

Interpretation Introduction

Interpretation:

The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(e)

Interpretation Introduction

Interpretation:

The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(f)

Interpretation Introduction

Interpretation:

The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

help

Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Answer 2

Question

Chapter 11, Problem 11.1IA

(a)

Interpretation Introduction

Interpretation:

The molecule CH4 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

The rigid rotators can be classified spherical, symmetric, linear, or asymmetric rotor depending on the moment of inertia. The spherical rotator has either Oh or Td point group. The symmetric rotator has point group with atleast one threefold axis, whereas the asymmetric rotator does not has any point group with threefold axis or higher. The linear rotators are linear molecules.

(b)

Interpretation Introduction

Interpretation:

The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(c)

Interpretation Introduction

Interpretation:

The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(d)

Interpretation Introduction

Interpretation:

The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(e)

Interpretation Introduction

Interpretation:

The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(f)

Interpretation Introduction

Interpretation:

The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 11, Problem 11.1IA

(a)

Interpretation Introduction

Interpretation:

The molecule CH4 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

The rigid rotators can be classified spherical, symmetric, linear, or asymmetric rotor depending on the moment of inertia. The spherical rotator has either Oh or Td point group. The symmetric rotator has point group with atleast one threefold axis, whereas the asymmetric rotator does not has any point group with threefold axis or higher. The linear rotators are linear molecules.

(b)

Interpretation Introduction

Interpretation:

The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(c)

Interpretation Introduction

Interpretation:

The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(d)

Interpretation Introduction

Interpretation:

The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(e)

Interpretation Introduction

Interpretation:

The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(f)

Interpretation Introduction

Interpretation:

The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 11, Problem 11.1IA

(a)

Interpretation Introduction

Interpretation:

The molecule CH4 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

The rigid rotators can be classified spherical, symmetric, linear, or asymmetric rotor depending on the moment of inertia. The spherical rotator has either Oh or Td point group. The symmetric rotator has point group with atleast one threefold axis, whereas the asymmetric rotator does not has any point group with threefold axis or higher. The linear rotators are linear molecules.

(b)

Interpretation Introduction

Interpretation:

The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(c)

Interpretation Introduction

Interpretation:

The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(d)

Interpretation Introduction

Interpretation:

The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(e)

Interpretation Introduction

Interpretation:

The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(f)

Interpretation Introduction

Interpretation:

The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 11, Problem 11.1IA

(a)

Interpretation Introduction

Interpretation:

The molecule CH4 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

The rigid rotators can be classified spherical, symmetric, linear, or asymmetric rotor depending on the moment of inertia. The spherical rotator has either Oh or Td point group. The symmetric rotator has point group with atleast one threefold axis, whereas the asymmetric rotator does not has any point group with threefold axis or higher. The linear rotators are linear molecules.

(b)

Interpretation Introduction

Interpretation:

The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(c)

Interpretation Introduction

Interpretation:

The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(d)

Interpretation Introduction

Interpretation:

The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(e)

Interpretation Introduction

Interpretation:

The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

(f)

Interpretation Introduction

Interpretation:

The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 6

Chapter 11, Problem 11.1IA

(a)

Interpretation Introduction

Interpretation:

The molecule CH4 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

The rigid rotators can be classified spherical, symmetric, linear, or asymmetric rotor depending on the moment of inertia. The spherical rotator has either Oh or Td point group. The symmetric rotator has point group with atleast one threefold axis, whereas the asymmetric rotator does not has any point group with threefold axis or higher. The linear rotators are linear molecules.

Answer 7

Chapter 11, Problem 11.1IA

(a)

Interpretation Introduction

Interpretation:

The molecule CH4 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

The rigid rotators can be classified spherical, symmetric, linear, or asymmetric rotor depending on the moment of inertia. The spherical rotator has either Oh or Td point group. The symmetric rotator has point group with atleast one threefold axis, whereas the asymmetric rotator does not has any point group with threefold axis or higher. The linear rotators are linear molecules.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 14

(e)

Interpretation Introduction

Interpretation:

The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 15

(e)

Interpretation Introduction

Interpretation:

The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 16

(f)

Interpretation Introduction

Interpretation:

The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 17

(f)

Interpretation Introduction

Interpretation:

The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 21

Ch. 11 - Prob. 11A.1ST Ch. 11 - Prob. 11A.2ST Ch. 11 - Prob. 11B.1ST Ch. 11 - Prob. 11B.2ST Ch. 11 - Prob. 11B.3ST Ch. 11 - Prob. 11B.4ST Ch. 11 - Prob. 11C.1ST Ch. 11 - Prob. 11C.2ST Ch. 11 - Prob. 11D.1ST Ch. 11 - Prob. 11E.1ST

Interpretation: The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments. Concept introduction: As mentioned in the concept introduction in part (a).

Interpretation: The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments. Concept introduction: As mentioned in the concept introduction in part (a).

Interpretation: The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments. Concept introduction: As mentioned in the concept introduction in part (a).

Interpretation: The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments. Concept introduction: As mentioned in the concept introduction in part (a).

Interpretation: The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments. Concept introduction: As mentioned in the concept introduction in part (a).

Want to see the full answer?

Chapter 11 Solutions

Interpretation:

The molecule CH3CN has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Interpretation:

The molecule CO2 has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Interpretation:

The molecule CH3OH has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Interpretation:

The molecule benzene has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).

Interpretation:

The molecule pyridine has to be classified as spherical, symmetric, linear, or asymmetric rotor. The corresponding has to be validated with group theoretical arguments.

Concept introduction:

As mentioned in the concept introduction in part (a).