Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 11, Problem 11.19P
Interpretation Introduction

Interpretation:

The general appearance of the curve for the titration of weak diprotic acid with NaOH has to be sketched.  The chemistry involves in governing the pH in each of the four distinct regions of the curve has to be explained.

Concept introduction:

Acid-base titration is titration between acid and base. It is also known as neutralization reaction.

There are primarily four types of acid-base titrations –

  • Strong base vs strong acid
  • Strong base vs weak acid
  • Weak base vs strong acid
  • Weak base vs weak acid

Equivalence point ensures the titration reaction becomes completed and at this point the number of moles of titrant and the number of moles of analyte becomes equal.

Titration involving diprotic acids show two equivalence points as there are two protons and the protons are abstracted by base at different rates of reaction.

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The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism:  1) NO + NO ⇄ N2O2 (fast);   2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
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Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.

Chapter 11 Solutions

Quantitative Chemical Analysis

Ch. 11 - Prob. 11.HECh. 11 - Prob. 11.IECh. 11 - Prob. 11.JECh. 11 - Prob. 11.KECh. 11 - Prob. 11.1PCh. 11 - Prob. 11.2PCh. 11 - Prob. 11.3PCh. 11 - Prob. 11.4PCh. 11 - Prob. 11.5PCh. 11 - Prob. 11.6PCh. 11 - Prob. 11.7PCh. 11 - Prob. 11.8PCh. 11 - Prob. 11.9PCh. 11 - Prob. 11.10PCh. 11 - Prob. 11.11PCh. 11 - Prob. 11.12PCh. 11 - Prob. 11.13PCh. 11 - Prob. 11.14PCh. 11 - Prob. 11.15PCh. 11 - Prob. 11.16PCh. 11 - Prob. 11.17PCh. 11 - Prob. 11.18PCh. 11 - Prob. 11.19PCh. 11 - Prob. 11.20PCh. 11 - Prob. 11.21PCh. 11 - Prob. 11.22PCh. 11 - Prob. 11.23PCh. 11 - Prob. 11.24PCh. 11 - Prob. 11.25PCh. 11 - Prob. 11.26PCh. 11 - Prob. 11.27PCh. 11 - Prob. 11.28PCh. 11 - Prob. 11.29PCh. 11 - Prob. 11.30PCh. 11 - Prob. 11.31PCh. 11 - Prob. 11.32PCh. 11 - Prob. 11.33PCh. 11 - Prob. 11.34PCh. 11 - Prob. 11.35PCh. 11 - Prob. 11.36PCh. 11 - Prob. 11.37PCh. 11 - Prob. 11.38PCh. 11 - Prob. 11.39PCh. 11 - Prob. 11.40PCh. 11 - Prob. 11.41PCh. 11 - Prob. 11.42PCh. 11 - Prob. 11.43PCh. 11 - Prob. 11.44PCh. 11 - Prob. 11.45PCh. 11 - Prob. 11.46PCh. 11 - Prob. 11.47PCh. 11 - Prob. 11.48PCh. 11 - Prob. 11.49PCh. 11 - Prob. 11.50PCh. 11 - Prob. 11.51PCh. 11 - Prob. 11.52PCh. 11 - Prob. 11.53PCh. 11 - Prob. 11.54PCh. 11 - Prob. 11.55PCh. 11 - Prob. 11.56PCh. 11 - Prob. 11.57PCh. 11 - Prob. 11.58PCh. 11 - Prob. 11.60PCh. 11 - Prob. 11.61PCh. 11 - Prob. 11.62PCh. 11 - Prob. 11.63PCh. 11 - Prob. 11.64PCh. 11 - Prob. 11.65PCh. 11 - Prob. 11.66PCh. 11 - Prob. 11.67PCh. 11 - Prob. 11.68PCh. 11 - Prob. 11.69PCh. 11 - Prob. 11.70PCh. 11 - Prob. 11.71PCh. 11 - Prob. 11.72PCh. 11 - Prob. 11.73PCh. 11 - Prob. 11.74PCh. 11 - Prob. 11.75P
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Acid-Base Titration | Acids, Bases & Alkalis | Chemistry | FuseSchool; Author: FuseSchool - Global Education;https://www.youtube.com/watch?v=yFqx6_Y6c2M;License: Standard YouTube License, CC-BY