The product should be identified. Concept introduction: The pinacol–pinacolone rearrangement: Pinacol–pinacolone rearrangement is a conversion of 1,2- diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 10, Problem 93P

(a)

Interpretation Introduction

Interpretation:

The product should be identified.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

(b)

Interpretation Introduction

Interpretation:

The reason should be explained for the only one product in the given reaction.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Predict the major products of the following organic reaction: NC Δ ? Some important Notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to draw bonds carefully to show important geometric relationships between substituents. Note: if your answer contains a complicated ring structure, you must use one of the molecular fragment stamps (available in the menu at right) to enter the ring structure. You can add any substituents using the pencil tool in the usual way. Click and drag to start drawing a structure. Х а

Predict the major products of this organic reaction. Be sure you use dash and wedge bonds to show stereochemistry where it's important. + ☑ OH 1. TsCl, py .... 文 P 2. t-BuO K Click and drag to start drawing a structure.

Consider this organic reaction: ( Draw the major products of the reaction in the drawing area below. If there won't be any major products, because this reaction won't happen at a significant rate, check the box under the drawing area instead. Click and drag to start drawing a structure. Х : а ค 1

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 10, Problem 93P

(a)

Interpretation Introduction

Interpretation:

The product should be identified.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

(b)

Interpretation Introduction

Interpretation:

The reason should be explained for the only one product in the given reaction.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 10, Problem 93P

(a)

Interpretation Introduction

Interpretation:

The product should be identified.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

(b)

Interpretation Introduction

Interpretation:

The reason should be explained for the only one product in the given reaction.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 10, Problem 93P

(a)

Interpretation Introduction

Interpretation:

The product should be identified.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

(b)

Interpretation Introduction

Interpretation:

The reason should be explained for the only one product in the given reaction.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 10, Problem 93P

(a)

Interpretation Introduction

Interpretation:

The product should be identified.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

(b)

Interpretation Introduction

Interpretation:

The reason should be explained for the only one product in the given reaction.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Answer 6

Chapter 10, Problem 93P

(a)

Interpretation Introduction

Interpretation:

The product should be identified.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Answer 7

Chapter 10, Problem 93P

(a)

Interpretation Introduction

Interpretation:

The product should be identified.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reason should be explained for the only one product in the given reaction.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reason should be explained for the only one product in the given reaction.

Concept introduction:

The pinacol–pinacolone rearrangement:

Pinacol–pinacolone rearrangement is a conversion of 1,2-diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 10.1 - Why are NH3 and CH3NH2 no longer nucleophiles when...Ch. 10.1 - Explain the difference in reactivity between...Ch. 10.1 - Prob. 5P Ch. 10.1 - Prob. 6P Ch. 10.1 - Prob. 8P Ch. 10.2 - Prob. 9P Ch. 10.3 - Prob. 11P Ch. 10.3 - Show how 1-propanol can be converted into the...Ch. 10.4 - Which of the following alcohols dehydrates the...Ch. 10.4 - Prob. 14P

The product should be identified. Concept introduction: The pinacol–pinacolone rearrangement: Pinacol–pinacolone rearrangement is a conversion of 1,2- diol to a carbonyl compound in the presence of acid via 1,2- shift is called rearrangement is called Pinacol–pinacolone rearrangement.

Solution Summary: The author explains the pinacol–pinacola rearrangement, which is a conversion of 1,2-diol to carbonyl compound in the presence of acid. Dehydration of primary alcohol does not occur.

Concept explainers

Want to see the full answer?

Chapter 10 Solutions