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- Phosphorus occurs naturally in the form of fluorapatite, CaF2 3Ca3(PO4)2. The dot indicates 1 part CaF2 to 3 parts Ca3(PO4)2. This mineral is reacted with an aqueous solution of H2SO4 in the preparation of a fertilizer. The products are phosphoric acid, hydrogen fluoride, and gypsum, CaSO4 2H2O. Write the balanced equation describing this process.arrow_forwardThe balanced equation for the reduction of iron ore to the metal using CO is Fe2O3(s) + 3 CO(g) 2 Fe(s) + 3 CO2(g) (a) What is the maximum mass of iron, in grams, that can be obtained from 454 g (1.00 lb) of iron(III) oxide? (b) What mass of CO is required to react with 454 g cot Fe2O3?arrow_forward4.48 Elemental phosphorous is used in the semiconductor industry. It can be obtained from an ore called fluoroapatite via reaction with SiO2 and C: 4Ca5( PO4)3F+18SiO2+30C3P4+30CO+18CaSiO3+2CaF2 Suppose a particular semiconductor production plant requires 1500 kg of P4. If the recovery of P4 from this reaction is 73% efficient, what mass of fluoroapatite is needed?arrow_forward
- A chemist dissolves a 1.497-g sample of a type of metal (an alloy of Sn, Pb, Sb, and Cu) in nitric acid, and metastannic acid, H2SnO3, is precipitated. She heats the precipitate to drive off the water, which leaves 0.4909 g of tin(IV) oxide. What was the percentage of [in in the original sample?arrow_forwardThe presence of arsenic in a sample that may also contain another Group 5A element, antimony, can be confirmed by first precipitating the As3+ and Sb3+ ions as yellow solid As2S3 and orange solid Sb2S3. If aqueous HCI is then added, only Sb2S3 dissolves, leaving behind solid As2S3. The As2S3 can then be dissolved using aqueous HNO3. 3 As2S3(s) + 10 HNO3(aq) + 4 H2O() 6 H3AsO4(aq) + 10 NO(g) + 9 S(s) Finally, the presence of arsenic is confirmed by adding AgNO3 to the solution of H3AsO4 to precipitate a reddish brown solid AgxAsOy The composition of this solid is As, 16.199% and Ag, 69.964%. (a) What are the oxidation numbers of As, S, and N in the reaction of As2S3 with nitric acid? (b) What is the formula of the reddish brown solid AgxAsOy?arrow_forwardIron forms a sulfide with the approximate formula Fe7S8. Assume that the oxidation state of sulfur is 2 and that iron atoms exist in both +2 and +3 oxidation states. What is the ratio of Fe(II) atoms to Fe(III) atoms in this compound?arrow_forward
- A 1.345-g sample of a compound of barium and oxygen was dissolved in hydrochloric acid to give a solution of barium ion, which was then precipitated with an excess of potassium chromate to give 2.012 g of barium chromate, BaCrO4. What is the formula of the compound?arrow_forward1. Calculate the amount (grams) of solid NiSO4·(H2O)6 that is needed to prepare 100 mL of concentrated 0.40 M NiSO4·(H2O)6 solution. 2.Determine the volume of the stock 0.40M nickel (II) sulfate solution that would need to be transferred to a 50.0mL volumetric flask and diluted to achieve the following final concentration: 50.0 mL of a 0.08 M nickel (II) sulfate solution from the original 0.40 M stock solutionarrow_forwardAn iron ore was analyzed by dissolving a 2.9912-g sample in concentrated HCl. The resulting solution was diluted with water, and the iron(III) was precipitated as the hydrous oxide Fe203-xH20 by the addition of NH3. After filtration and washing, the residue was ignited at a high temperature to give 0.8394 g of pure Fe203 (159.69 g/mol). How many grams of Fe;04 (231.54 g/mol) are there in the iron ore sample? A 0.2028 g B 0.4057 g © 0.6085 g 0.8114 garrow_forward
- 1. A sample containing magnetite, Fe;O4, was analyzed by dissolving a 1.5419-g sample in concentrated HCI, giving a mixture of Fe2+ and Fe³+. After adding HNO3 to oxidize any Fe2+ to Fet, the resulting solution was diluted with water and the Fe+ precipitated as Fe(OH)3 by adding NH3. After filtering and rinsing, the residue was ignited, resulting to 0.8525 g of pure Fe2O3. Calculate the: a) % (w/w) Fe b) % (w/w) Fe;O4 in the sample.arrow_forwardAn iron ore was analyzed by dissolving a 2.9912-g sample in concentrated HCl. The resulting solution was diluted with water, and the iron(III) was precipitated as the hydrous oxide Fe203-XH2O by the addition of NH3. After filtration and washing, the residue was ignited at a high temperature to give 0.8394 g of pure Fe203 (159.69 g/mol). If the sample came from an extracted ore that is 50 kg in total, how much iron can be extracted from it? A 9.815 g Fe 9.815 kg Fe 13.94 g Fe 13.94 kg Fearrow_forwardA chemist dissolves a 1.497-g sample of a type of metal (an alloy of Sn, Pb, Sb, and Cu) in nitric acid, and metastannic acid, H2SnO3, is precipitated. She heats the precipitate to drive off the water, which leaves 0.4909 g of tin(IV) oxide. What was the percentage of tin in the original sample?arrow_forward
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