Compounds from the 1 H NMR data and the given molecular formula has to be identified. Concept introduction: The 1 H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule. The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the ( N + 1 ) rule. N is the number of adjacent non-equivalent protons. According to the ( N + 1 ) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into ( N + 1 ) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

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Answer 1

Question

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

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11 1 Which one of the following compounds would show a proton NMR signal at the highest chemical shift? (7pts) cl @amitabh CI CI d) Cl CICI

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Answer 2

Question

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

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Answer 3

Question

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Expert Solution & Answer

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Answer 4

Question

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Expert Solution & Answer

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Answer 5

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 6

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 7

Chapter 10, Problem 69P

(a)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Compounds from the 1H NMR data and the given molecular formula has to be identified.

Concept introduction:

The 1H NMR spectrum of a compound provides some vital information that is required to predict the structure of the compound. The chemical shift values can predict the groups that are present in the molecule.

The splitting of signals predicts the number of hydrogens or protons attached to the adjacent carbon in a carbon chain of a compound. The single signal is split into multiple peaks called the multiplicity of the signal. Splitting of signals is done according to the (N+1) rule. N is the number of adjacent non-equivalent protons.

According to the (N+1) rule, for a proton-coupled with N adjacent non-equivalent protons, the signal split into (N+1) peak. The splitting is mutual. With this information, the structure of the compound can be predicted.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10.1 - Prob. 1P Ch. 10.2 - What would distinguish the mass spectrum of...Ch. 10.2 - Prob. 3P Ch. 10.3 - Prob. 5P Ch. 10.3 - Suggest possible molecular formulas for a compound...Ch. 10.3 - Prob. 7P Ch. 10.4 - Prob. 8P Ch. 10.4 - Prob. 9P Ch. 10.5 - Prob. 10P Ch. 10.5 - Prob. 11P

Solution Summary: The author explains that the 1H NMR spectrum of a compound provides vital information that is required to predict the structure of the compound.

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