Introductory Chemistry (5th Edition) (Standalone Book)
5th Edition
ISBN: 9780321910295
Author: Nivaldo J. Tro
Publisher: PEARSON
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Textbook Question
Chapter 10, Problem 65E
Determine the molecular geometry of each molecule.
a.
b.
c.
d.
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each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that:
1. the rate of substitution doesn't depend on nucleophile concentration and
2. the products are a roughly 50/50 mixture of enantiomers.
Substrate A
Substrate B
Faster Rate
X
Ś
CI
(Choose one)
(Choose one)
CI
Br
Explanation
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Br
(Choose one)
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
The
H
O
HỌC—C—0—CH, CH,
2
A
ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
Check
OA
B
OC
ch
B
C
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
Chapter 10 Solutions
Introductory Chemistry (5th Edition) (Standalone Book)
Ch. 10 - Q1. Which pair of elements has the most similar...Ch. 10 - What is the Lewis structure for the compound that...Ch. 10 - Prob. 3SAQCh. 10 - Q4. What is the correct Lewis structure for?
a....Ch. 10 - Q5. How many electron dots are in the Lewis...Ch. 10 - Prob. 6SAQCh. 10 - What is the molecular geometry of PBr3 ? a. Bent...Ch. 10 - What is the molecular geometry of N2O ? (Nitrogen...Ch. 10 - Prob. 9SAQCh. 10 - Q10. Which molecular is polar?
a.
b.
c.
d.
Ch. 10 - Prob. 1ECh. 10 - Write the election configuration for Ne and Ar....Ch. 10 - In the Lewis model, what is an octet? What is a...Ch. 10 - 4. What is the different between ionic bonding and...Ch. 10 - Prob. 5ECh. 10 - Prob. 6ECh. 10 - 7. How are double and triple bonds physically...Ch. 10 - What is the procedure for writing a covalent Lewis...Ch. 10 - 9. How do you determine the number of electrons...Ch. 10 - How do you determine the number of electrons that...Ch. 10 - Prob. 11ECh. 10 - What are resonance structures? Why are they...Ch. 10 - Prob. 13ECh. 10 - Use the VSEPR theory to predict the bond angle...Ch. 10 - Prob. 15ECh. 10 - What is the difference between electron geometry...Ch. 10 - Prob. 17ECh. 10 - 18. What is the most electronegative element on...Ch. 10 - Prob. 19ECh. 10 - What is a dipole moment?Ch. 10 - 21. Is the H-Cl bond in HCl polar? Do HCl...Ch. 10 - Prob. 22ECh. 10 - Write an electron configuration for each element...Ch. 10 - 24. Write an electron configuration for each...Ch. 10 - Prob. 25ECh. 10 - Write the Lewis structure for each element. a. Kr...Ch. 10 - Write a generic Lewis structure for the halogens....Ch. 10 - Write a generic Lewis structure for the alkali...Ch. 10 - Prob. 29ECh. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Indicate the noble gas that has the same Lewis...Ch. 10 - Prob. 34ECh. 10 - Lewis structure for lonic compounds
35. Is each...Ch. 10 - Prob. 36ECh. 10 - Write the Lewis structure for each ionic compound....Ch. 10 - 38. Write the Lewis structure for each ionic...Ch. 10 - Use the Lewis model to determine the formula for...Ch. 10 - 40. Use the Lewis model to determine the formula...Ch. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Prob. 43ECh. 10 - 44. Determine the general formula of the ionic...Ch. 10 - Use the Lewis model to explain why each element...Ch. 10 - Use the Lewis model to explain why the compound...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - Prob. 48ECh. 10 - 49. Write the Lewis structure for each...Ch. 10 - 50. Write the Lewis structure for each...Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - Write the Lewis structure for each molecule. a....Ch. 10 - 53. Determine what is wrong with each Lewis...Ch. 10 - 54. Determine what is wrong with each Lewis...Ch. 10 - 55. Write the Lewis structure for each molecule or...Ch. 10 - Prob. 56ECh. 10 - 57. Write the Lewis structure for each ion....Ch. 10 - Prob. 58ECh. 10 - 59. Write the Lewis structure for each molecule....Ch. 10 - Write the Lewis structure for each molecule. These...Ch. 10 - 61. Determine the number of electron groups around...Ch. 10 - 62. Determine the number of electron groups around...Ch. 10 - 63. Determine the number of bonding groups and the...Ch. 10 - Determine the number of bonding groups and the...Ch. 10 - 65. Determine the molecular geometry of each...Ch. 10 - Prob. 66ECh. 10 - ...Ch. 10 - 66. Determine the molecular geometry of each...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - 71. Determine the bond angles for each molecule in...Ch. 10 - 72. Determine the bond angles for each molecule in...Ch. 10 - Determine the electron and molecular geometry of...Ch. 10 - Determine the electron and molecular geometries of...Ch. 10 - Determine the molecular geometry of each...Ch. 10 - Prob. 76ECh. 10 - Refer to Figure10.2 to determine the...Ch. 10 - Refer to figure 10.2 to determine the...Ch. 10 - List these elements in order of decreasing...Ch. 10 - 80. List these elements in order of increasing...Ch. 10 - 81. Refer to figure10.2 to find the...Ch. 10 - Refer to figure 10.2 to find the electronegativity...Ch. 10 - Prob. 83ECh. 10 - Arrange these diatomic molecules in order of...Ch. 10 - Classify each diatomic molecule as polar or...Ch. 10 - Prob. 86ECh. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Classify each molecule as polar nonpolar. a. CS2...Ch. 10 - Prob. 90ECh. 10 - 91. Classify each molecule as polar nonpolar.
a....Ch. 10 -
Ch. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - 95. Determine whether each compound is ionic or...Ch. 10 - Determine whether each compound is ionic or...Ch. 10 - Write the Lewis structure for OCCI2 (carbon is...Ch. 10 - Prob. 98ECh. 10 - Prob. 99ECh. 10 - Prob. 100ECh. 10 - Prob. 101ECh. 10 - 102. Consider the precipitation reaction.
Write...Ch. 10 - Prob. 103ECh. 10 - Prob. 104ECh. 10 - 105. Each compound listed contains both ionic and...Ch. 10 - Prob. 106ECh. 10 - 107. Each molecule listed contains an expanded...Ch. 10 - Prob. 108ECh. 10 - Formic acid is responsible for the sting you feel...Ch. 10 - Sodium azide has the formula of NaNx with a high...Ch. 10 - Free radicals are molecules that contain an odd...Ch. 10 - Prob. 112ECh. 10 - Prob. 113ECh. 10 - Prob. 114ECh. 10 - Prob. 115ECh. 10 - Prob. 116ECh. 10 - Draft a list stepbystep instructions for writing a...Ch. 10 - for each of the following molecules:...
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- in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstantarrow_forwardtrue or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forward
- calculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forwardtrue or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forward
- true or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forwardtrue or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forward
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