EP CHEMISTRY:CENTRAL..-MOD.MASTERING
14th Edition
ISBN: 9780136781509
Author: Brown
Publisher: PEARSON CO
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Textbook Question
Chapter 10, Problem 64E
A deep-sea diver uses a gas cylinder with a volume of 10.0L and a content of 51.2 g of O2
And 32.6 g He. Calculate the partial pressure of each gas and the total pressure if the temperature
Of the gas is 19°C.
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Complete the following table. The only density needed is already given. Show your
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should be included and significant figures should be given close attention. Be sure to notice
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mass of the product should in milligrams rather than grams.
LOCH 3
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Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 10 Solutions
EP CHEMISTRY:CENTRAL..-MOD.MASTERING
Ch. 10.2 - Prob. 10.1.1PECh. 10.2 -
Gallium melts just above room temperature...Ch. 10.2 - Prob. 10.2.1PECh. 10.2 - Prob. 10.2.2PECh. 10.3 - Prob. 10.3.1PECh. 10.3 - Prob. 10.3.2PECh. 10.4 - Prob. 10.4.1PECh. 10.4 - Prob. 10.4.2PECh. 10.4 - Prob. 10.5.1PECh. 10.4 - Prob. 10.5.2PE
Ch. 10.4 - Prob. 10.6.1PECh. 10.4 - Prob. 10.6.2PECh. 10.5 - Prob. 10.7.1PECh. 10.5 - Prob. 10.7.2PECh. 10.5 - Prob. 10.8.1PECh. 10.5 - Prob. 10.8.2PECh. 10.5 - Prob. 10.9.1PECh. 10.5 - Prob. 10.9.2PECh. 10.6 - Prob. 10.10.1PECh. 10.6 - Prob. 10.10.2PECh. 10.6 - Prob. 10.11.1PECh. 10.6 - Prob. 10.11.2PECh. 10.7 - Prob. 10.12.1PECh. 10.7 - Prob. 10.12.2PECh. 10.8 - Fill in the blanks for the following statement:...Ch. 10.8 - Prob. 10.13.2PECh. 10.8 - Prob. 10.14.1PECh. 10.8 - Prob. 10.14.2PECh. 10.9 - Calculate the pressure of a 2975-mol sample of N2...Ch. 10.9 - Prob. 10.15.2PECh. 10 - Prob. 1DECh. 10 - Prob. 1ECh. 10 - Prob. 2ECh. 10 - Consider the sample of gas depicted here_ What...Ch. 10 - Imagine that the reaction 2CO(g)+O2(g)2CO(g)...Ch. 10 - Suppose you have a fixed amount of an ideal gas at...Ch. 10 - Prob. 6ECh. 10 - Prob. 7ECh. 10 - Prob. 8ECh. 10 - Prob. 9ECh. 10 - Prob. 10ECh. 10 -
10.11 A thin glass tube 1 m long is filled with...Ch. 10 -
10.12 The graph below shows the change in...Ch. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - Prob. 15ECh. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - a. The compound 1-iodododecane is a nonvolatile...Ch. 10 - Prob. 19ECh. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - Prob. 22ECh. 10 - Prob. 23ECh. 10 - Prob. 24ECh. 10 - You have a gas at 25C confined to a cylinder with...Ch. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Nitrogen and hydrogen gases react to form ammonia...Ch. 10 -
10.29
a. What conditions are represented by the...Ch. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Prob. 33ECh. 10 - Prob. 34ECh. 10 - Prob. 35ECh. 10 - Prob. 36ECh. 10 - Calculate the number of molecules in deep breath...Ch. 10 - If the pressure exerted by ozone, O3, in the...Ch. 10 - A scuba diver’s tank contain 0.29 kg of O2...Ch. 10 - Prob. 40ECh. 10 - Prob. 41ECh. 10 - Prob. 42ECh. 10 - Chlorine is widely used to purify municipal water...Ch. 10 - Many gases are shipped in high-pressure...Ch. 10 - Prob. 45ECh. 10 - Prob. 46ECh. 10 - Rank the following gases from least to denser at...Ch. 10 - Prob. 48ECh. 10 - Prob. 49ECh. 10 - Prob. 50ECh. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Magnesium can be used as a ‘getter” in evacuated...Ch. 10 - Prob. 56ECh. 10 - The metabolic oxidation of glucose, C6H12O6, in...Ch. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Consider the apparatus shown in the following...Ch. 10 - Prob. 62ECh. 10 - A mixture containing 0.75 mol He(g), 0.330 mol...Ch. 10 - A deep-sea diver uses a gas cylinder with a volume...Ch. 10 - Prob. 65ECh. 10 - Prob. 66ECh. 10 - Prob. 67ECh. 10 - Prob. 68ECh. 10 - Prob. 69ECh. 10 - Prob. 70ECh. 10 - Prob. 71ECh. 10 - Prob. 72ECh. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - Prob. 75ECh. 10 - Indicate which of the following statement...Ch. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - Prob. 79ECh. 10 - Suppose you have two 1-L flasks, one containing N2...Ch. 10 - Prob. 81ECh. 10 -
10.8
Place the following gases in order of...Ch. 10 - Prob. 83ECh. 10 - Prob. 84ECh. 10 - Prob. 85ECh. 10 - Prob. 86ECh. 10 - Prob. 87ECh. 10 - Prob. 88ECh. 10 - Prob. 89ECh. 10 - Prob. 90ECh. 10 - Prob. 91ECh. 10 - Prob. 92ECh. 10 - Prob. 93ECh. 10 - Prob. 94ECh. 10 - Prob. 95ECh. 10 - Prob. 96ECh. 10 - Prob. 97AECh. 10 - A gas bubble with a volume of 1.0 mm3 originates...Ch. 10 - A 15.0-L tank is filled with helium gas at a...Ch. 10 - Prob. 100AECh. 10 - Prob. 101AECh. 10 - Prob. 102AECh. 10 - Prob. 103AECh. 10 - Prob. 104AECh. 10 - Prob. 105AECh. 10 - Prob. 106AECh. 10 - Prob. 107AECh. 10 - Prob. 108AECh. 10 - Prob. 109AECh. 10 - The density of gas of unknown molar mass was...Ch. 10 - A glass vessel fitted with a stopcock valve has a...Ch. 10 - Prob. 112AECh. 10 -
10.113 consider the following gases. All at STP:...Ch. 10 - Prob. 114AECh. 10 - Prob. 115AECh. 10 - Prob. 116AECh. 10 - Prob. 117AECh. 10 - Prob. 118IECh. 10 - Prob. 119IECh. 10 - Prob. 120IECh. 10 -
10.121 A 4.00-g sample of a mixture of CaO and...Ch. 10 - Prob. 122IECh. 10 - Prob. 123IECh. 10 - Chlorine dioxide gas (CIO2) is used as a...Ch. 10 - Natural gas is very abundant in many Middle...Ch. 10 - Prob. 126IECh. 10 - Prob. 127IE
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