(a) Interpretation: The structure corresponding to ( 1 E , 4 R ) − 1 , 4 − dimethylcyclodecene is to be drawn. Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name. The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

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Answer 1

Question

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Li+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiCl

Answer 2

Question

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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Answer 3

Question

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

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Answer 4

Question

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Expert Solution & Answer

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Answer 5

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 6

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer 7

Chapter 10, Problem 41P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to (1E,4R)−1,4−dimethylcyclodecene is to be drawn.

Concept introduction: The systematic naming of organic compound is given by IUPAC. The naming of organic compound is done such that the structure of organic compound is correctly interpreted from the name.

The prefix E and Z depends upon the location of the higher priority groups. When two higher priority groups are present on the opposite side then it is an E isomer, whereas when two higher priority groups are present on the same side then it is Z isomer.

Answer 8

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Answer 9

Interpretation Introduction

(b)

Interpretation: The enantiomer of (1E,4R)−1,4−dimethylcyclodecene including its E or Z and R or S is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. Two compounds which are non-superimposable mirror images of each other are known as enantiomers.

Answer 10

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 11

Interpretation Introduction

(c)

Interpretation: The two possible diasteromers of given compound is to be drawn.

Concept introduction: Stereochemistry is defined as the arrangement of molecule in three dimensional and its impact on chemical reactions. A pair of diastereomers exists when two substituents attached to each of the double bonded carbon atoms are different.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10.1 - Prob. 1P Ch. 10.2 - Problem 10.2 How many degrees of unsaturation are...Ch. 10.3 - Give the IUPAC name for each alkene. abcde Ch. 10.3 - Give the IUPAC name for each polyfunctional...Ch. 10.3 - Prob. 9P Ch. 10.6 - Linolenic acidTable 10.2 and stearidonic acid are...Ch. 10.7 - Prob. 12P Ch. 10.9 - Problem 10.13 What product is formed when each...Ch. 10.9 - Prob. 14P Ch. 10.10 - Problem 10.15 Draw the products formed when each...

Solution Summary: The author explains the systematic naming of organic compound by IUPAC. The prefix E and Z depends upon the location of the higher priority groups.

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Chapter 10 Solutions