Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 10, Problem 36E
Interpretation Introduction
Interpretation:
The amount of hydrogen gas required to produce
Concept introduction:
The stoichiometry of a chemical species involved in a
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Identify the missing starting materials/ reagents/ products in the following reactions. Show the stereochemistry clearly in the structures, if any.
If there is a major product, draw the structures of the major product with stereochemistry clearly indicated where applicable. Show only the diastereomers (you do not have to draw the pairs of enantiomers).
If you believe that multiple products are formed in approximately equal amounts (hence neither is the major product), draw the structures of the products, and show the detailed mechanism of these reactions to justify the formation of the multiple products.
If you believe no product is formed, explain why briefly. (6 mark for each, except f and g, which are 10 mark each)
3. What starting material would you use to synthesize 3-hydroxypentanoic acid using a
NaBH4 reduction?
1. Give stereochemical (Fischer projection) formulas for all (but no extras) the
stereoisomers that could theoretically form during the reduction of
a. the carbonyl group of 2-methyl-3--pentanone
b. both carbonyl groups of 2,4-pentanedione (careful!)
2. Predict the products of the reduction of O=CCH2CH2CH2C=O with
a. LiAlH4
b. NaBH4
CH3
OH
Chapter 10 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 10 - The first step in the Ostwald process for...Ch. 10 - When hydrogen sulfide reacts with oxygen, water...Ch. 10 - Magnesium hydroxide is formed from the reaction of...Ch. 10 - In our bodies, sugar is broken down by reacting...Ch. 10 - Prob. 5ECh. 10 - Aqueous solutions of potassium hydrogen sulfate...Ch. 10 - The first step in the Ostwald process for...Ch. 10 - Butane, C4H10 is a common fuel used for heating...Ch. 10 - The explosion of nitroglycerine is described by...Ch. 10 - According to the reaction 2AgNO3+CuCu(NO3)2+2Ag,...
Ch. 10 - Prob. 11ECh. 10 - Prob. 12ECh. 10 - Prob. 13ECh. 10 - Prob. 14ECh. 10 - The hard water scum that forms a ring around the...Ch. 10 - Prob. 16ECh. 10 - Prob. 17ECh. 10 - Prob. 18ECh. 10 - The Solvay process is multistep industrial method...Ch. 10 - Prob. 20ECh. 10 - Prob. 21ECh. 10 - What mass of NaHCO3 must decompose to produce 448g...Ch. 10 - Prob. 23ECh. 10 - Solid ammonium chloride decomposes to form ammonia...Ch. 10 - What mass of magnesium hydroxide will precipitate...Ch. 10 - Prob. 26ECh. 10 - Prob. 27ECh. 10 - Prob. 28ECh. 10 - The reaction of a dry cell battery may be...Ch. 10 - Prob. 30ECh. 10 - Prob. 31ECh. 10 - Prob. 32ECh. 10 - Calcium cyanamide is a common fertilizer. When...Ch. 10 - Prob. 34ECh. 10 - The Haber process for making ammonia from nitrogen...Ch. 10 - Prob. 36ECh. 10 - Prob. 37ECh. 10 - The simplest example of the hydrogenation of a...Ch. 10 - Prob. 39ECh. 10 - Prob. 40ECh. 10 - Ammonia can be formed from a combination reaction...Ch. 10 - Carbon monoxide reacts with oxygen to form carbon...Ch. 10 - An experiment is conducted in which varying...Ch. 10 - The flasks below illustrated three trials of a...Ch. 10 - A solution containing 1.63g of barium chloride is...Ch. 10 - Prob. 46ECh. 10 - Prob. 47ECh. 10 - Prob. 48ECh. 10 - A mixture of tetraphosphorus trisulfide and...Ch. 10 - Sodium carbonate can neutralize nitric acid by the...Ch. 10 - Prob. 51ECh. 10 - Prob. 52ECh. 10 - Prob. 53ECh. 10 - Prob. 54ECh. 10 - Prob. 55ECh. 10 - Prob. 56ECh. 10 - Prob. 57ECh. 10 - Prob. 58ECh. 10 - Prob. 59ECh. 10 - Prob. 60ECh. 10 - Question 57 through 62: Thermochemical equations...Ch. 10 - Prob. 62ECh. 10 - Quicklime, the common name for calcium oxide, CaO,...Ch. 10 - What mass in grams of hydrogen has to react to...Ch. 10 - The quicklime produced in Question 63 is...Ch. 10 - Prob. 66ECh. 10 - What mass in grams of octane, a component of...Ch. 10 - Calculate the quantity of energy (kJ) transferred...Ch. 10 - Prob. 69ECh. 10 - Classify each of the following statements as true...Ch. 10 - Prob. 71ECh. 10 - What mass in grams of calcium phosphate will...Ch. 10 - Prob. 73ECh. 10 - Prob. 74ECh. 10 - A laboratory test of 12.8g of aluminum ore yields...Ch. 10 - How much energy is required to decompose 1.42g of...Ch. 10 - Prob. 77ECh. 10 - Prob. 78ECh. 10 - A sludge containing silver chloride is a water...Ch. 10 - Prob. 80ECh. 10 - Prob. 81ECh. 10 - Prob. 82ECh. 10 - Prob. 83ECh. 10 - Prob. 84ECh. 10 - In 1866, a young chemistry student conceived the...Ch. 10 - Prob. 86ECh. 10 - A student was given a 1.6240-g sample of a mixture...Ch. 10 - A researcher dissolved 1.382g of impure copper in...Ch. 10 - What mass in grams of magnesium nitrate, Mg(NO3)2,...Ch. 10 - Prob. 90ECh. 10 - Prob. 10.1TCCh. 10 - Solutions of zinc bromide and sodium hydroxide are...Ch. 10 - Prob. 2PECh. 10 - Prob. 3PECh. 10 - How mass of fluorine is formed when 3.0grams of...Ch. 10 - Prob. 5PECh. 10 - Prob. 6PECh. 10 - Prob. 7PECh. 10 - Prob. 8PECh. 10 - Prob. 9PECh. 10 - A solution containing 43.5g of calcium nitrate is...Ch. 10 - Prob. 11PECh. 10 - Prob. 12PECh. 10 - Prob. 13PECh. 10 - Prob. 14PECh. 10 - Prob. 15PECh. 10 - Prob. 1PCECh. 10 - Prob. 2PCECh. 10 - Prob. 3PCECh. 10 - Prob. 4PCECh. 10 - Prob. 5PCECh. 10 - Prob. 6PCECh. 10 - Eight problem-classification examples follow. Test...Ch. 10 - Prob. 8PCE
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