Chemistry with Access Code, Hybrid Edition

9th Edition

ISBN: 9781285188492

Author: Steven S. Zumdahl

Publisher: CENGAGE L

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Textbook Question

Chapter 10, Problem 136CP

Rationalize the differences in physical properties in terms of intermolecular forces for the following organic compounds. Compare the first three substances with each other, compare the last three with each other, and then compare all six. Can you account for any anomalies?

	bp (°C)	mp (°C)	∆H_vap (kJ/mol)
Benzene, C₆H₆	80	6	33.9
Naphthalene, C₁₀H₈	218	80	51.5
Carbon tetrachloride	76	-23	31.8
Acetone, CH₃COCH₃	56	-95	3.18
Acetic acid, CH₃CO₂H	118	17	39.7
Benzoic acid, C₆H₅CO₂H	249	122	68.2

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Chapter 10 Solutions

Chemistry with Access Code, Hybrid Edition

Ch. 10 - What are intermolecular forces? How do they differ...Ch. 10 - Define the following terms and describe how each...Ch. 10 - Compare and contrast solids, liquids, and gases.Ch. 10 - Prob. 4RQ Ch. 10 - What is a lattice? What is a unit cell? Describe a...Ch. 10 - What is closest packing? What is the difference...Ch. 10 - Describe, in general, the structures of ionic...Ch. 10 - Prob. 9RQ Ch. 10 - Prob. 10RQ Ch. 10 - Compare and contrast the phase diagrams of water...

Ch. 10 - It is possible to balance a paper clip on the...Ch. 10 - Consider a sealed container half-filled with...Ch. 10 - Explain the following: You add 100 mL water to a...Ch. 10 - Prob. 4ALQ Ch. 10 - Prob. 5ALQ Ch. 10 - Why do liquids have a vapor pressure? Do all...Ch. 10 - Prob. 7ALQ Ch. 10 - What is the vapor pressure of water at 100C? How...Ch. 10 - Prob. 9ALQ Ch. 10 - Prob. 10ALQ Ch. 10 - Prob. 11ALQ Ch. 10 - In the diagram below, which lines represent the...Ch. 10 - Prob. 14Q Ch. 10 - Atoms are assumed to touch in closest packed...Ch. 10 - Define critical temperature and critical pressure....Ch. 10 - Use the kinetic molecular theory to explain why a...Ch. 10 - Prob. 18Q Ch. 10 - Prob. 19Q Ch. 10 - Describe what is meant by a dynamic equilibrium in...Ch. 10 - Prob. 21Q Ch. 10 - Prob. 22Q Ch. 10 - Prob. 23Q Ch. 10 - Prob. 24Q Ch. 10 - When wet laundry is hung on a clothesline on a...Ch. 10 - You have three covalent compounds with three very...Ch. 10 - Prob. 28Q Ch. 10 - Compare and contrast the structures of the...Ch. 10 - Silicon carbide (SiC) is an extremely hard...Ch. 10 - How could you tell experimentally if TiO2 is an...Ch. 10 - A common prank on college campuses is to switch...Ch. 10 - A plot of In (Pvap) versus 1/T (K) is linear with...Ch. 10 - Prob. 34Q Ch. 10 - Identify the most important types of interparticle...Ch. 10 - Prob. 36E Ch. 10 - Predict which substance in each of the following...Ch. 10 - Consider the compounds CI2, HCI. F2, NaF, and HF....Ch. 10 - Prob. 39E Ch. 10 - Consider the following electrostatic potential...Ch. 10 - In each of the following groups of substances,...Ch. 10 - Prob. 42E Ch. 10 - The shape of the meniscus of water in a glass tube...Ch. 10 - Prob. 44E Ch. 10 - Hydrogen peroxide (H2O2) is a syrupy liquid with a...Ch. 10 - Carbon diselenide (CSe2) is a liquid at room...Ch. 10 - X rays from a copper X-ray tube ( = 154 pm) were...Ch. 10 - The second-order diffraction (n = 2) for a gold...Ch. 10 - A topaz crystal has an interplanar spacing (d) of...Ch. 10 - X rays of wavelength 2.63 were used to analyze a...Ch. 10 - Calcium has a cubic closest packed structure as a...Ch. 10 - Nickel has a face-centered cubic unit cell. The...Ch. 10 - A certain form of lead has a cubic closest packed...Ch. 10 - Prob. 54E Ch. 10 - You are given a small bar of an unknown metal X....Ch. 10 - A metallic solid with atoms in a face-centered...Ch. 10 - Titanium metal has a body-centered cubic unit...Ch. 10 - Barium has a body-centered cubic structure. If the...Ch. 10 - The radius of gold is 144 pm, and the density is...Ch. 10 - The radius of tungsten is 137 pm and the density...Ch. 10 - What fraction of the total volume of a cubic...Ch. 10 - Iron has a density of 7.86 g/cm3 and crystallizes...Ch. 10 - Prob. 63E Ch. 10 - Prob. 64E Ch. 10 - Selenium is a semiconductor used in photocopying...Ch. 10 - Prob. 66E Ch. 10 - Prob. 67E Ch. 10 - Prob. 68E Ch. 10 - The structures of some common crystalline...Ch. 10 - The unit cell for nickel arsenide is shown below....Ch. 10 - Cobalt fluoride crystallizes in a closest packed...Ch. 10 - The compounds Na2O, CdS, and ZrI4. all can be...Ch. 10 - What is the formula for the compound that...Ch. 10 - Prob. 74E Ch. 10 - A certain metal fluoride crystallizes in such a...Ch. 10 - Prob. 76E Ch. 10 - The unit cell of MgO is shown below l Does MgO...Ch. 10 - In solid KCl the smallest distance between the...Ch. 10 - The CsCl structure is a simple cubic array of...Ch. 10 - MnO has either the NaCI type structure or the CsCI...Ch. 10 - What type of solid will each of the following...Ch. 10 - What type of solid will each of the following...Ch. 10 - The memory metal, nitinol, is an alloy of nickel...Ch. 10 - Superalloys have been made of nickel and aluminum....Ch. 10 - Perovskite is a mineral containing calcium,...Ch. 10 - A mineral crystallizes in a cubic closest packed...Ch. 10 - Materials containing the elements Y, Ba, Cu, and O...Ch. 10 - The structures of another class of ceramic,...Ch. 10 - Plot the following data and determine Hvap for...Ch. 10 - From the following data for liquid nitric acid,...Ch. 10 - In Breckenridge, Colorado, the typical atmospheric...Ch. 10 - The temperature inside a pressure cooker is 115C....Ch. 10 - Carbon tetrachloride, CCl4, has a vapor pressure...Ch. 10 - Diethyl ether (CH3CH2OCH2CH3) was one of the first...Ch. 10 - A substance, X, has the following properties:...Ch. 10 - Use the heating-cooling curve below to answer the...Ch. 10 - The molar heat of fusion of sodium metal is 2.60...Ch. 10 - Prob. 98E Ch. 10 - What quantity of energy does it take to convert...Ch. 10 - Consider a 75.0-g sample of H2O(g) at 125C. What...Ch. 10 - An ice cube tray contains enough water at 22.0C to...Ch. 10 - A 0.250-g chunk of sodium metal is cautiously...Ch. 10 - Prob. 103E Ch. 10 - Prob. 104E Ch. 10 - Prob. 105E Ch. 10 - Prob. 106E Ch. 10 - Prob. 107E Ch. 10 - Consider the following data for xenon: Triple...Ch. 10 - Some of the physical properties of H2O and D2O are...Ch. 10 - Rationalize the following boiling points:Ch. 10 - Consider the following vapor pressure versus...Ch. 10 - Consider the following enthalpy changes:...Ch. 10 - Prob. 113AE Ch. 10 - Boron nitride (BN) exists in two forms. The first...Ch. 10 - Prob. 115AE Ch. 10 - Argon has a cubic closest packed structure as a...Ch. 10 - Prob. 117AE Ch. 10 - A 20.0-g sample of ice at 10.0C is mixed with...Ch. 10 - In regions with dry climates, evaporative coolers...Ch. 10 - Which of the following compound(s) exhibit only...Ch. 10 - Which of the following statements about...Ch. 10 - Prob. 123CWP Ch. 10 - Aluminum has an atomic radius of 143 pm and forms...Ch. 10 - Pyrolusite is a mineral containing manganese ions...Ch. 10 - The structure of the compound K2O is best...Ch. 10 - Prob. 127CWP Ch. 10 - Some ice cubes at 0c with a total mass of 403 g...Ch. 10 - The enthalpy of vaporization for acetone is 32.0...Ch. 10 - Prob. 130CWP Ch. 10 - When I mole of benzene is vaporized at a constant...Ch. 10 - You and a friend each synthesize a compound with...Ch. 10 - Prob. 133CP Ch. 10 - Prob. 134CP Ch. 10 - Consider two different organic compounds, each...Ch. 10 - Rationalize the differences in physical properties...Ch. 10 - Prob. 137CP Ch. 10 - Some ionic compounds contain a mixture of...Ch. 10 - Some ionic compounds contain a mixture of...Ch. 10 - Spinel is a mineral that contains 37.9% aluminum,...Ch. 10 - Mn crystallizes in the same type of cubic unit...Ch. 10 - You are asked to help set up a historical display...Ch. 10 - Some water is placed in a sealed glass container...Ch. 10 - The molar enthalpy of vaporization of water at 373...Ch. 10 - Prob. 145CP Ch. 10 - Rubidium chloride has the sodium chloride...Ch. 10 - Prob. 147IP Ch. 10 - A metal burns in air at 600c under high pressure...Ch. 10 - Prob. 149IP Ch. 10 - General Zod has sold Lex Luthor what Zod claims to...

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Solution Summary: The author explains the order of intermolecular forces and increasing boiling, melting points and enthalpy of vaporization of given compounds.

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