The Lewis structure of the species is to be drawn. Also, the order of the increasing carbon-oxygen bond length and increasing carbon-oxygen bond strength is to be ranked Concept introduction: The Lewis structures are the diagrams that are used to show the bonding between various atoms in a covalent molecule and the number of lone pairs present in that molecule. These are also known as Lewis dot diagrams, electron dot diagrams, Lewis dot structures or Lewis dot formula. These are used to predict the geometry, polarity, and reactivity of covalent compounds. The bond length or bond distance is the average distance between the nuclei of two bonded atoms in a molecule. When two similar atoms are bonded together, half of the bond length is known as the covalent radius. The bond length depends on the number of bonded of two atoms. The unit of bond length is picometer. In single, double and triple bonds, the order of bond length is as follows: Triple bond < Double bond < Single bond The strength with which the two atoms are held together in chemical bonds is called the bond strength. It is measured in terms of energy that is required to break the bonds.
The Lewis structure of the species is to be drawn. Also, the order of the increasing carbon-oxygen bond length and increasing carbon-oxygen bond strength is to be ranked Concept introduction: The Lewis structures are the diagrams that are used to show the bonding between various atoms in a covalent molecule and the number of lone pairs present in that molecule. These are also known as Lewis dot diagrams, electron dot diagrams, Lewis dot structures or Lewis dot formula. These are used to predict the geometry, polarity, and reactivity of covalent compounds. The bond length or bond distance is the average distance between the nuclei of two bonded atoms in a molecule. When two similar atoms are bonded together, half of the bond length is known as the covalent radius. The bond length depends on the number of bonded of two atoms. The unit of bond length is picometer. In single, double and triple bonds, the order of bond length is as follows: Triple bond < Double bond < Single bond The strength with which the two atoms are held together in chemical bonds is called the bond strength. It is measured in terms of energy that is required to break the bonds.
Definition Definition Connection between particles in a compound. Chemical bonds are the forces that hold the particles of a compound together. The stability of a chemical compound greatly depends on the nature and strength of the chemical bonding present in it. As the strength of the chemical bonding increases the stability of the compound also increases.
Chapter 10, Problem 10.72P
Interpretation Introduction
Interpretation:
The Lewis structure of the species is to be drawn. Also, the order of the increasing carbon-oxygen bond length and increasing carbon-oxygen bond strength is to be ranked
Concept introduction:
The Lewis structures are the diagrams that are used to show the bonding between various atoms in a covalent molecule and the number of lone pairs present in that molecule. These are also known as Lewis dot diagrams, electron dot diagrams, Lewis dot structures or Lewis dot formula. These are used to predict the geometry, polarity, and reactivity of covalent compounds.
The bond length or bond distance is the average distance between the nuclei of two bonded atoms in a molecule. When two similar atoms are bonded together, half of the bond length is known as the covalent radius. The bond length depends on the number of bonded of two atoms. The unit of bond length is picometer.
In single, double and triple bonds, the order of bond length is as follows:
Triple bond <Double bond <Single bond
The strength with which the two atoms are held together in chemical bonds is called the bond strength. It is measured in terms of energy that is required to break the bonds.
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
Unlimited attempts
Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
Chapter 10 Solutions
Chemistry: The Molecular Nature of Matter and Change
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