Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393600681
Author: Gilbert
Publisher: W. W. Norton & Company
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Chapter 10, Problem 10.70QA
Interpretation Introduction
To find:
The volume of 8.80g of CO2 vapor at 37oC and 0.98 atm.
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Redraw the flowchart
redraw the flowchart with boxes and molecules written in them
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
Chapter 10 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 10 - Prob. 10.1VPCh. 10 - Prob. 10.2VPCh. 10 - Prob. 10.3VPCh. 10 - Prob. 10.4VPCh. 10 - Prob. 10.6VPCh. 10 - Prob. 10.7VPCh. 10 - Prob. 10.8VPCh. 10 - Prob. 10.9VPCh. 10 - Prob. 10.10VPCh. 10 - Prob. 10.11VP
Ch. 10 - Prob. 10.13VPCh. 10 - Prob. 10.14VPCh. 10 - Prob. 10.15VPCh. 10 - Prob. 10.16VPCh. 10 - Prob. 10.17VPCh. 10 - Prob. 10.18VPCh. 10 - Prob. 10.19VPCh. 10 - Prob. 10.20VPCh. 10 - Prob. 10.21QACh. 10 - Prob. 10.22QACh. 10 - Prob. 10.23QACh. 10 - Prob. 10.24QACh. 10 - Prob. 10.25QACh. 10 - Prob. 10.26QACh. 10 - Prob. 10.27QACh. 10 - Prob. 10.28QACh. 10 - Prob. 10.29QACh. 10 - Prob. 10.30QACh. 10 - Prob. 10.31QACh. 10 - Prob. 10.32QACh. 10 - Prob. 10.33QACh. 10 - Prob. 10.34QACh. 10 - Prob. 10.35QACh. 10 - Prob. 10.36QACh. 10 - Prob. 10.37QACh. 10 - Prob. 10.38QACh. 10 - Prob. 10.39QACh. 10 - Prob. 10.40QACh. 10 - Prob. 10.41QACh. 10 - Prob. 10.42QACh. 10 - Prob. 10.43QACh. 10 - Prob. 10.44QACh. 10 - Prob. 10.45QACh. 10 - Prob. 10.46QACh. 10 - Prob. 10.47QACh. 10 - Prob. 10.48QACh. 10 - Prob. 10.49QACh. 10 - Prob. 10.50QACh. 10 - Prob. 10.51QACh. 10 - Prob. 10.52QACh. 10 - Prob. 10.53QACh. 10 - Prob. 10.54QACh. 10 - Prob. 10.55QACh. 10 - Prob. 10.56QACh. 10 - Prob. 10.57QACh. 10 - Prob. 10.58QACh. 10 - Prob. 10.59QACh. 10 - Prob. 10.60QACh. 10 - Prob. 10.61QACh. 10 - Prob. 10.62QACh. 10 - Prob. 10.63QACh. 10 - Prob. 10.64QACh. 10 - Prob. 10.65QACh. 10 - Prob. 10.66QACh. 10 - Prob. 10.67QACh. 10 - Prob. 10.68QACh. 10 - Prob. 10.69QACh. 10 - Prob. 10.70QACh. 10 - Prob. 10.71QACh. 10 - Prob. 10.72QACh. 10 - Prob. 10.73QACh. 10 - Prob. 10.74QACh. 10 - Prob. 10.75QACh. 10 - Prob. 10.76QACh. 10 - Prob. 10.77QACh. 10 - Prob. 10.78QACh. 10 - Prob. 10.79QACh. 10 - Prob. 10.80QACh. 10 - Prob. 10.81QACh. 10 - Prob. 10.82QACh. 10 - Prob. 10.83QACh. 10 - Prob. 10.84QACh. 10 - Prob. 10.85QACh. 10 - Prob. 10.86QACh. 10 - Prob. 10.87QACh. 10 - Prob. 10.88QACh. 10 - Prob. 10.89QACh. 10 - Prob. 10.90QACh. 10 - Prob. 10.91QACh. 10 - Prob. 10.92QACh. 10 - Prob. 10.93QACh. 10 - Prob. 10.94QACh. 10 - Prob. 10.95QACh. 10 - Prob. 10.96QACh. 10 - Prob. 10.97QACh. 10 - Prob. 10.98QACh. 10 - Prob. 10.99QACh. 10 - Prob. 10.100QACh. 10 - Prob. 10.101QACh. 10 - Prob. 10.102QACh. 10 - Prob. 10.103QACh. 10 - Prob. 10.104QACh. 10 - Prob. 10.105QACh. 10 - Prob. 10.106QACh. 10 - Prob. 10.107QACh. 10 - Prob. 10.108QACh. 10 - Prob. 10.109QACh. 10 - Prob. 10.110QACh. 10 - Prob. 10.111QACh. 10 - Prob. 10.112QACh. 10 - Prob. 10.113QACh. 10 - Prob. 10.114QACh. 10 - Prob. 10.115QACh. 10 - Prob. 10.116QACh. 10 - Prob. 10.117QACh. 10 - Prob. 10.118QACh. 10 - Prob. 10.119QACh. 10 - Prob. 10.120QACh. 10 - Prob. 10.121QACh. 10 - Prob. 10.122QACh. 10 - Prob. 10.123QACh. 10 - Prob. 10.124QACh. 10 - Prob. 10.125QACh. 10 - Prob. 10.126QACh. 10 - Prob. 10.127QACh. 10 - Prob. 10.128QACh. 10 - Prob. 10.129QACh. 10 - Prob. 10.130QACh. 10 - Prob. 10.131QACh. 10 - Prob. 10.132QACh. 10 - Prob. 10.133QACh. 10 - Prob. 10.134QACh. 10 - Prob. 10.135QACh. 10 - Prob. 10.136QACh. 10 - Prob. 10.137QACh. 10 - Prob. 10.138QACh. 10 - Prob. 10.139QACh. 10 - Prob. 10.140QACh. 10 - Prob. 10.141QACh. 10 - Prob. 10.142QACh. 10 - Prob. 10.143QACh. 10 - Prob. 10.144QACh. 10 - Prob. 10.145QACh. 10 - Prob. 10.146QACh. 10 - Prob. 10.147QACh. 10 - Prob. 10.148QACh. 10 - Prob. 10.149QACh. 10 - Prob. 10.150QA
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- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
- Draw the curved-arrow mechanism with the drawings of the molecules, not just abbreviations. -NO₂ Sn, HCl (aq) E D H (CH3CO)₂O -NH2 CH3arrow_forwardWhat is/are the product(s) of the following reaction? Select all that apply. * HI A B C OD OH A B OH D Carrow_forwardIn the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forward
- What spectral features allow you to differentiate the product from the starting material? Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR. 2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too. 3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.arrow_forwardQuestion 6 What is the major product of the following Diels-Alder reaction? ? Aldy by day of A. H о B. C. D. E. OB OD Oc OE OAarrow_forwardNonearrow_forward
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