Concept explainers
(a)
Interpretation:
IUPAC name has to be determined for the given compound.
Concept Introduction:
A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.
IUPAC rules for naming
There are about five rules that has to be followed for naming an alkane and they are,
- The longest continuous carbon chain in the compound has to be identified. This is known as parent compound. From this the parent name is obtained. Suffix “–ane” (for alkane) is added at the end of the prefix which gives information about the number of carbon atoms.
- Numbering has to be done so that the lowest number is given to the first group that is encountered in the parent chain.
- Naming and numbering has to be given for each atom or group that is attached to the parent chain. Numbering has to be done in a way that substituents get the least numbering.
- If the same substitution is present in the parent chain more than once, a separate prefix is added which tells about the number of times the substituent occurs. Prefixes used are di-, tri-, tetra-, penta- etc.
- Name of the substituents has to be placed in an alphabetical order before the parent compound name.
(b)
Interpretation:
IUPAC name has to be determined for the given compound.
Concept Introduction:
Refer part (a).
(c)
Interpretation:
IUPAC name has to be determined for the given compound.
Concept Introduction:
Refer part (a).
(d)
Interpretation:
IUPAC name has to be determined for the given compound.
Concept Introduction:
Refer part (a).
Want to see the full answer?
Check out a sample textbook solutionChapter 10 Solutions
Connect 2-Year Online Access for General, Organic, and Biochemistry
- Technetium is the first element in the periodic chart that does not have any stable isotopes. Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half life ideally suited for medical tests. It would seem that the decay of technetium should fit the treatment above with the result In(c/c) = -kt. The table below includes data from the two sites: http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130 http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab). a. b. C. Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also graph In(c/c.) on the vertical axis versus time on the horizontal axis. When half of the original amount of starting material has hours fraction remaining disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the material to decay away). Determine the slope of your In(c/c.) vs t graph and…arrow_forwardPlease correct answer and don't use hand ratingarrow_forward1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)arrow_forward
- What is the pH of the Tris buffer after the addition of 10 mL of 0.01M NaOH? How would I calculate this?arrow_forwardWhy do isopolianions form polymeric species with a defined molecular weight? What does it depend on?arrow_forwardWhat are isopolianions? Describe the structural unit of isopolianions.arrow_forward
- Justify the polymerization of vanadates VO43-, as a function of concentration and pH.arrow_forwardWhat is the preparation of 500 mL of 100mM MOPS buffer (pH=7.5) starting with 1 M MOPS and 1 M NaOH? How would I calculate the math?arrow_forwardIndicate the correct option.a) Isopolianions are formed around metallic atoms in a low oxidation state.b) Non-metals such as N, S, C, Cl, ... give rise to polyacids (oxygenated).c) Both are incorrect.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY