Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces. Concept Introduction: The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.

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Answer 1

Question

Chapter 10, Problem 10.49QP

(a)

Interpretation Introduction

Interpretation:

Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.

(b)

Interpretation Introduction

Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).

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1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)

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Answer 2

Question

Chapter 10, Problem 10.49QP

(a)

Interpretation Introduction

Interpretation:

Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.

(b)

Interpretation Introduction

Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).

Expert Solution & Answer

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Answer 3

Question

Chapter 10, Problem 10.49QP

(a)

Interpretation Introduction

Interpretation:

Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.

(b)

Interpretation Introduction

Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).

Expert Solution & Answer

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Answer 4

Question

Chapter 10, Problem 10.49QP

(a)

Interpretation Introduction

Interpretation:

Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.

(b)

Interpretation Introduction

Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).

Expert Solution & Answer

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Answer 5

Chapter 10, Problem 10.49QP

(a)

Interpretation Introduction

Interpretation:

Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.

(b)

Interpretation Introduction

Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 10, Problem 10.49QP

(a)

Interpretation Introduction

Interpretation:

Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.

Answer 7

Chapter 10, Problem 10.49QP

(a)

Interpretation Introduction

Interpretation:

Heptane, butane, hexane, and ethane has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

The force of attraction between two molecules that experience a short-lived dipole is known as London Dispersion force. Length of the carbon chain has a direct relationship with the melting point of the molecule. This is because as the length of carbon chain increases, the number of electrons increases and there will be stronger force of attraction between the molecules resulting in strong London Dispersion forces. As the London dispersion force increases, the melting point and boiling point also increases. This implies that as the length of hydrocarbon chain increases, the melting point and boiling point also increases.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 10.1 - Prob. 10.1Q Ch. 10.1 - Prob. 10.2Q Ch. 10.2 - Prob. 10.1PP Ch. 10.2 - Prob. 10.3Q Ch. 10.2 - Prob. 10.4Q Ch. 10.2 - Prob. 10.2PP Ch. 10.2 - Prob. 10.3PP Ch. 10.2 - Heptane is a very poor fuel and is given a zero on...Ch. 10.3 - Name each of the following cycloalkanes using...Ch. 10.3 - Prob. 10.6PP

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Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).

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Chapter 10 Solutions

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Interpretation: Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces. Concept Introduction: Refer part (a).

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Chapter 10 Solutions

Interpretation:

Given compounds has to be ranked in order of highest to lowest boiling point based on intermolecular forces.

Concept Introduction:

Refer part (a).