Decreasing order of F − A − F bond angle in the given AF n species is to be determined. Concept introduction: The following steps are used to determine the molecular shape of the given molecule. Step 1: Write the Lewis structure of the given formula and place the atoms. Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement. Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR. Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly. The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In clear words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is more or the bond angle is less as the number of lone pair increases on the central atom.

Question

Want to see the full answer?

Answer 1

Question

Chapter 10, Problem 10.47P

Interpretation Introduction

Interpretation:

Decreasing order of F−A−F bond angle in the given AFn species is to be determined.

Concept introduction:

The following steps are used to determine the molecular shape of the given molecule.

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In clear words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is more or the bond angle is less as the number of lone pair increases on the central atom.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Complete the spectroscopy with structure

Write the calculate the reaction quotient for the following system, if the partial pressure of all reactantsand products is 0.15 atm: NOCl (g) ⇌ NO (g) + Cl2 (g) H = 20.5 kcal

Answer 2

Question

Chapter 10, Problem 10.47P

Interpretation Introduction

Interpretation:

Decreasing order of F−A−F bond angle in the given AFn species is to be determined.

Concept introduction:

The following steps are used to determine the molecular shape of the given molecule.

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In clear words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is more or the bond angle is less as the number of lone pair increases on the central atom.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 10, Problem 10.47P

Interpretation Introduction

Interpretation:

Decreasing order of F−A−F bond angle in the given AFn species is to be determined.

Concept introduction:

The following steps are used to determine the molecular shape of the given molecule.

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In clear words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is more or the bond angle is less as the number of lone pair increases on the central atom.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 10, Problem 10.47P

Interpretation Introduction

Interpretation:

Decreasing order of F−A−F bond angle in the given AFn species is to be determined.

Concept introduction:

The following steps are used to determine the molecular shape of the given molecule.

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In clear words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is more or the bond angle is less as the number of lone pair increases on the central atom.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 10, Problem 10.47P

Interpretation Introduction

Interpretation:

Decreasing order of F−A−F bond angle in the given AFn species is to be determined.

Concept introduction:

The following steps are used to determine the molecular shape of the given molecule.

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In clear words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is more or the bond angle is less as the number of lone pair increases on the central atom.

Answer 6

Chapter 10, Problem 10.47P

Interpretation Introduction

Interpretation:

Decreasing order of F−A−F bond angle in the given AFn species is to be determined.

Concept introduction:

The following steps are used to determine the molecular shape of the given molecule.

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In clear words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is more or the bond angle is less as the number of lone pair increases on the central atom.

Answer 7

Chapter 10, Problem 10.47P

Interpretation Introduction

Interpretation:

Decreasing order of F−A−F bond angle in the given AFn species is to be determined.

Concept introduction:

The following steps are used to determine the molecular shape of the given molecule.

Step 1: Write the Lewis structure of the given formula and place the atoms.

Step 2: Count all electron groups including bonding and non-bonding pairs around the central atom and use it to assign one of the five electron-group arrangement.

Step 3: Write the ideal bond angle related to the electron-group arrangement and the effect of any deviation can be predicted by using VSEPR.

Step 4: Count the bonding and non-bonding electron groups and draw the molecular shape accordingly.

The deviation in the value of ideal angles is directly proportional to the number of lone pair present on the central atom because its presence causes more repulsion between itself and bond pair. In clear words, bond pair-bond pair has less repulsion than lone pair-bond pair repulsion and lone pair-lone pair has the most repulsion. Hence deviation from the ideal angle is more or the bond angle is less as the number of lone pair increases on the central atom.

Answer 8

Expert Solution & Answer

Answer 9

Expert Solution & Answer

Answer 10

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 11

Ch. 10.1 - Write a Lewis structure for H2S; ; SOCl2. Ch. 10.1 - Prob. 10.1BFP Ch. 10.1 - Prob. 10.2AFP Ch. 10.1 - Prob. 10.2BFP Ch. 10.1 - Prob. 10.3AFP Ch. 10.1 - Prob. 10.3BFP Ch. 10.1 - Prob. 10.4AFP Ch. 10.1 - Prob. 10.4BFP Ch. 10.1 - Write a Lewis structure with minimal formal...Ch. 10.1 - Prob. 10.5BFP

Concept explainers

Videos

Want to see the full answer?

Chapter 10 Solutions