(a) Interpretation: The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified. Concept introduction: The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

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Answer 1

Question

Chapter 10, Problem 10.43AP

Interpretation Introduction

(a)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(b)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(c)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

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Answer 2

Question

Chapter 10, Problem 10.43AP

Interpretation Introduction

(a)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(b)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(c)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

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Answer 3

Question

Chapter 10, Problem 10.43AP

Interpretation Introduction

(a)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(b)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(c)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

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Answer 4

Question

Chapter 10, Problem 10.43AP

Interpretation Introduction

(a)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(b)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(c)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

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Answer 5

Chapter 10, Problem 10.43AP

Interpretation Introduction

(a)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(b)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Interpretation Introduction

(c)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Answer 6

Chapter 10, Problem 10.43AP

Interpretation Introduction

(a)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Answer 7

Chapter 10, Problem 10.43AP

Interpretation Introduction

(a)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The fluorine atoms in the given compound which are the diastereotopic fluorines, the enantiotopic fluorines, the homotopic fluorines, and the constitutionally nonequivalent fluorines are to be identified.

Concept introduction:

The groups which are chemically nondistinguishable are termed as constitutionally equivalent. The groups which are chemically distinguishable are termed as constitutionally nonequivalent. The constitutionally equivalent groups can be further divided into three categories homotopic, enantiotopic, and diastereotopic.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

Solution Summary: The author explains that the given compound has the enantiotopic and homotopic fluorines, which are chemically nondistinguishable and constitutionally nonequivalent.

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