(a) Interpretation: The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated. Concept introduction: The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

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Answer 1

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

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Answer 2

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

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Answer 5

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

Answer 6

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Answer 7

Chapter 10, Problem 10.41AP

Interpretation Introduction

(a)

Interpretation:

The structure of seven-carbon tertiary alcohol which yields a single alkene after acid-catalyzed dehydration is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of alcohol that, after acid-catalyzed dehydration yields an alkene and after the ozonolysis followed with (CH3)2S, gives only benzaldehyde is to be stated.

Concept introduction:

The dehydration of alcohol in the presence of acid catalyst results in the formation of an alkene with the removal of one molecule of water. Dehydration of alcohol is a type of β- elimination reaction, in which beta hydrogen is eliminated from the alcohol molecule. If all beta hydrogen in alcohol is equivalent, then only single alkene will be the major product.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of alcohol that gives the same product when it reacts with KMnO4 as it obtained from the ozonolysis of trans−3,6−dimethyl−4−octene followed by treatment with H2O2 is to be stated.

Concept introduction:

Potassium permanganate (KMnO4) is a useful oxidizing agent, which can oxidize primary alcohol to carboxylic acid in the presence of basic solution but not used in secondary alcohol to ketones because ketones react further with alkaline permanganate solution. The oxidative ozonolysis of alkene also produces a carboxylic acid.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

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