Chapter 10, Problem 10.23P

Interpretation Introduction

(a)

Interpretation:

Calculate the initial concentrations of both reactants and derive relations for the concentrations of CO, Cl₂.

Concept introduction:

Number of moles produced can be calculated using the equation,

$N=\left(\frac{V}{V_{STR}}\right)\left(\frac{T_{STP}}{T}\right)\left(\frac{P}{P_{STP}}\right)\left(1mol\right)$

Where, $V_{STR}$ = volume of 1 mol substance at STP, $T_{STP}$ = temperature of 1 mol at STP, $P_{STP}$ = pressure of 1 mol substance at STP

Interpretation Introduction

(b)

Interpretation:

Derive the given relationship.

Concept introduction:

Number of moles produced can be calculated using the equation,

$N=\left(\frac{V}{V_{STR}}\right)\left(\frac{T_{STP}}{T}\right)\left(\frac{P}{P_{STP}}\right)\left(1mol\right)$

Where, $V_{STR}$ = volume of 1 mol substance at STP, $T_{STP}$ = temperature of 1 mol at STP, $P_{STP}$ = pressure of 1 mol substance at STP

Interpretation Introduction

(c)

Interpretation:

Sketch the plot of Cp versus t and explain the graph and determine the maximum value.

Concept introduction:

Number of moles produced can be calculated using the equation,

$N=\left(\frac{V}{V_{STR}}\right)\left(\frac{T_{STP}}{T}\right)\left(\frac{P}{P_{STP}}\right)\left(1mol\right)$

Where, $V_{STR}$ = volume of 1 mol substance at STP, $T_{STP}$ = temperature of 1 mol at STP, $P_{STP}$ = pressure of 1 mol substance at STP

Interpretation Introduction

(d)

Interpretation:

Derive an expression for the time required to achieve a 75% conversion of the limiting reactant.

Concept introduction:

Number of moles produced can be calculated using the equation,

$N=\left(\frac{V}{V_{STR}}\right)\left(\frac{T_{STP}}{T}\right)\left(\frac{P}{P_{STP}}\right)\left(1mol\right)$

Where, $V_{STR}$ = volume of 1 mol substance at STP, $T_{STP}$ = temperature of 1 mol at STP, $P_{STP}$ = pressure of 1 mol substance at STP

Interpretation Introduction

(e)

Interpretation:

Use Simpson’s rule to integrate the given expression.

Concept introduction:

Number of moles produced can be calculated using the equation,

$N=\left(\frac{V}{V_{STR}}\right)\left(\frac{T_{STP}}{T}\right)\left(\frac{P}{P_{STP}}\right)\left(1mol\right)$

Where, $V_{STR}$ = volume of 1 mol substance at STP, $T_{STP}$ = temperature of 1 mol at STP, $P_{STP}$ = pressure of 1 mol substance at STP