Chemistry For Changing Times (14th Edition)
14th Edition
ISBN: 9780321972026
Author: John W. Hill, Terry W. McCreary
Publisher: PEARSON
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Chapter 1, Problem 71AP
Interpretation Introduction
Interpretation: To determine if the given statement is scientific hypothesis, law, observation or theory.
Concept Introduction: A given statement can be scientific hypothesis, law, observation or theory based upon its stage in scientific process.
Correct answer: The given statement is a scientific law.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 1 Solutions
Chemistry For Changing Times (14th Edition)
Ch. 1 - Prob. 1RQCh. 1 - Why do experiments have to be done to support a...Ch. 1 - Why can't scientific methods always be used to...Ch. 1 - How does technology differ from science?Ch. 1 - Prob. 5RQCh. 1 - Prob. 6RQCh. 1 - What is a DQ? What does a large DQ mean? Why is it...Ch. 1 - What derived units of (a) mass and (b) length are...Ch. 1 - What is the Sl-derived unit for volume? What...Ch. 1 - Prefix Symbol Definition tera- T 1012 - M - centi-...
Ch. 1 - Prob. 11RQCh. 1 - Identify the following work as either applied...Ch. 1 - Penicillin kills bacteria, thus saving the lives...Ch. 1 - Prob. 14PCh. 1 - Prob. 15PCh. 1 - X-rays are widely used in medicine and dentistry....Ch. 1 - Prob. 17PCh. 1 - The virus called HIV causes AIDS, a devastating...Ch. 1 - Which are realistic masses for a cellular...Ch. 1 - In Europe, A2 sized paper measures 594 mm 420 mm,...Ch. 1 - Which one(s) of the following are likely to be...Ch. 1 - Sample X on the moon has exactly the same mass as...Ch. 1 - Which of the following is a reasonable volume for...Ch. 1 - Which of the following is a reasonable...Ch. 1 - Earth's oceans contain 3.501 0 8 mi3 of water and...Ch. 1 - What is the area of Earth's oceans in square...Ch. 1 - Consider the two tubes shown below. The aluminum...Ch. 1 - Which one(s) of the following could be the inside...Ch. 1 - Identify the following as physical or chemical...Ch. 1 - Identify the following as physical or chemical...Ch. 1 - Identify the following changes as physical or...Ch. 1 - Identify the following changes as physical or...Ch. 1 - Identify each of the following as a substance or a...Ch. 1 - Identify each of the following as a substance or a...Ch. 1 - Which of the following mixtures are homogeneous,...Ch. 1 - Which of the following mixtures are homogeneous,...Ch. 1 - Every sample of the sugar glucose (no matter where...Ch. 1 - An advertisement for shampoo says, "Pure shampoo,...Ch. 1 - Which of the following represent elements, and...Ch. 1 - Prob. 40PCh. 1 - Prob. 41PCh. 1 - Without consulting tables, write a symbol for each...Ch. 1 - In his 1739 textbook, Traite elementaire de...Ch. 1 - In 1774 Joseph Priestley isolated a gas that he...Ch. 1 - Change the unit for each of the following...Ch. 1 - Convert each of the following measurements to the...Ch. 1 - Carry out the following conversions. a. 5.52104 mL...Ch. 1 - Carry out the following conversions. a. 546 mm to...Ch. 1 - Indicate which is the larger unit in each pair. a....Ch. 1 - There are about...Ch. 1 - Express the length of a 31 -cm ruler in (a) mm,...Ch. 1 - What is the volume in liters of (a) a 352-mL soft...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - Prob. 61PCh. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - (You may need data from Table 1.6 for some of...Ch. 1 - Liquid nitrogen, used for freezing sperm samples,...Ch. 1 - Normal body temperature is about 37 °C. What is...Ch. 1 - Prob. 67PCh. 1 - Prob. 68PCh. 1 - A certain chemistry class is 1.00 microcentury ( ...Ch. 1 - 70. A unit of beauty, a helen, thought to have...Ch. 1 - 71. English chemist William Henry studied the...Ch. 1 - Prob. 72APCh. 1 - Prob. 73APCh. 1 - For Problems 74 and 75t, classify each of the...Ch. 1 - For Problems 74 and 75, classify each of the...Ch. 1 - Prob. 76APCh. 1 - Prob. 77APCh. 1 - Prob. 78APCh. 1 - Prob. 79APCh. 1 - Prob. 80APCh. 1 - Prob. 81APCh. 1 - Prob. 82APCh. 1 - Prob. 83APCh. 1 - Prob. 84APCh. 1 - Prob. 85APCh. 1 - Prob. 86APCh. 1 - The density of a planet can be approximated from...Ch. 1 - The extrasolar planet HAT-P-i orbits a star 450...Ch. 1 - Prob. 89APCh. 1 - Prob. 90APCh. 1 - Prob. 91APCh. 1 - Prob. 92APCh. 1 - Prob. 1.1CTECh. 1 - Prob. 1.2CTECh. 1 - Prob. 1.3CTECh. 1 - Prob. 1.4CTECh. 1 - Prob. 1.5CTECh. 1 - Prob. 1.6CTECh. 1 - Prob. 1CGPCh. 1 - Prob. 2CGPCh. 1 - Prob. 3CGPCh. 1 - Materials Needed: • 1/4 cup dark corn syrup • 1/4...Ch. 1 - Materials Needed: • 1/4 cup dark corn syrup • 1/4...Ch. 1 - Prob. 3CHQCh. 1 - Prob. 4CHQCh. 1 - Materials Needed: • 1/4 cup dark corn syrup • 1/4...
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY