Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 1, Problem 4RQ
What evidence led to the conclusion that cathode rays had a negative charge?
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Use the References to access important values if needed for this question.
What is the IUPAC name of each of the the following?
0
CH3CHCNH₂
CH3
CH3CHCNHCH2CH3
CH3
You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Chapter 1 Solutions
Chemistry: An Atoms First Approach
Ch. 1 - Define and e xplain the differences between the...Ch. 1 - Is the scientific method suitable for solving...Ch. 1 - Use Daltons atomic theory to account for each of...Ch. 1 - What evidence led to the conclusion that cathode...Ch. 1 - What discoveries were made by J. J. Thomson, Henri...Ch. 1 - Consider Ernest Rutherfords -particle bombardment...Ch. 1 - Do the proton and the neutron have exactly the...Ch. 1 - What is the distinction between atomic number and...Ch. 1 - Paracelsus, a sixteenth-century alchemist and...Ch. 1 - What is wrong with the following statement? The...
Ch. 1 - Which of the following is true about an individual...Ch. 1 - These questions concern the work of J. J. Thomson....Ch. 1 - Which of the following explain how an ion is...Ch. 1 - You have a chemical in a sealed glass container...Ch. 1 - You may have noticed that when water boils, you...Ch. 1 - One of the best indications of a useful theory is...Ch. 1 - Prob. 9ALQCh. 1 - Which (if any) of the following can be determined...Ch. 1 - The difference between a law and a theory is the...Ch. 1 - As part of a science project, you study traffic...Ch. 1 - Explain the fundamental steps of the scientific...Ch. 1 - When hydrogen is burned in oxygen to form water,...Ch. 1 - Explain the law of conservation of mass, the law...Ch. 1 - Chlorine has two natural isotopes: C1737I and...Ch. 1 - The vitamin niacin (nicotinic acid, C6H5NO2) can...Ch. 1 - Section 1-5 describes the postulates of Daltons...Ch. 1 - The contributions of J. J. Thomson and Ernest...Ch. 1 - What is the modern view of the structure of the...Ch. 1 - The number of protons in an atom determines the...Ch. 1 - If the volume of a proton is similar to the volume...Ch. 1 - Prob. 23QCh. 1 - What refinements had to be made in Daltons atomic...Ch. 1 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 1 - Observations of the reaction between nitrogen gas...Ch. 1 - A sample of chloroform is found to contain 12.0 g...Ch. 1 - A sample of H2SO4 contains 2.02 g of hydrogen,...Ch. 1 - Hydrazine, ammonia, and hydrogen azide al1 contain...Ch. 1 - Consider 100.0-g samples of two different...Ch. 1 - The three most stable oxides of carbon are carbon...Ch. 1 - Two elements, R and Q, combine to form two binary...Ch. 1 - Prob. 33ECh. 1 - In a combustion reaction, 46.0 g of ethanol reacts...Ch. 1 - Early tables of atomic weights (masses) were...Ch. 1 - Indium oxide contains 4.784 g of indium for every...Ch. 1 - Prob. 37ECh. 1 - If you wanted to make an accurate scale model of...Ch. 1 - In an experiment it was found that the total...Ch. 1 - A chemist in a galaxy far, far away performed the...Ch. 1 - Write the symbol of each atom using the ZAX...Ch. 1 - For carbon-14 and carbon-12, how many protons and...Ch. 1 - How many protons and neutrons are in the nucleus...Ch. 1 - What number of protons and neutrons is contained...Ch. 1 - Prob. 45ECh. 1 - Write the atomic symbol (ZAX) for each of the...Ch. 1 - For each of the following ions, indicate the...Ch. 1 - How many protons, neutrons, and electrons are in...Ch. 1 - Prob. 49ECh. 1 - What is the symbol of an ion with 16 protons, 18...Ch. 1 - Complete the following table:Ch. 1 - Complete the following table:Ch. 1 - Four Fe2+ ions are key components of hemoglobin,...Ch. 1 - Which of the following statements is/are true? For...Ch. 1 - Identify each of the following elements. Give the...Ch. 1 - The isotope of an unknown element, X, has a mass...Ch. 1 - Prob. 57AECh. 1 - The early alchemists used to do an experiment in...Ch. 1 - In a reaction, 34.0 g of chromium(III) oxide...Ch. 1 - Prob. 60CWPCh. 1 - Complete the following table. Atmos Number of...Ch. 1 - Complete the following table.Ch. 1 - Which of the following is( are) correct? a. C40a2+...Ch. 1 - Prob. 64CPCh. 1 - Each of the following statements is true, but...Ch. 1 - Reaction of 2.0 L of hydrogen gas with 1.0 L of...Ch. 1 - A combustion reaction involves the reaction of a...Ch. 1 - A chemistry instructor makes the following claim:...Ch. 1 - You have two distinct gaseous compounds made from...Ch. 1 - Using the information in Table 1-1, answer the...Ch. 1 - A single molecule has a mass of 7.31 1023 g....Ch. 1 - You have gone back in time and are working with...
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- Part I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forward
- In the image, the light blue sphere represents a mole of hydrogen atoms, the purple or teal spheres represent a mole of a conjugate base. A light blue sphere by itself is H+. Assuming there is 2.00 L of solution, answer the following: The Ka of the left & right solution is? The pH of the left & right solution is? The acid on the left & right is what kind of acid?arrow_forwardNonearrow_forwardNonearrow_forward
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